zhpsЖурнал прикладной спектроскопииZhurnal Prikladnoii Spektroskopii0514-7506B. I. Stepanov Institute of Physics of the National Academy of Scienceszhps-1020Research ArticleАННОТАЦИИ АНГЛОЯЗЫЧНЫХ СТАТЕЙABSTRACTS ENGLISH-LANGUAGE ARTICLESКонтролируемый синтез, спектральные исследования и каталитическая активность наночастиц серебра и золота, синтезированных с использованием экстракта листьев Ficus sycomorusControlled Synthesis, Spectral Studies, and Catalytic Activity of Silver and Gold Nanoparticles Biosynthesized Using Ficus sycomorus Leaf ExtractZayedM. F.ZayedM. F.

 Эль-Менуфия 

mervat.zayed@yahoo.comShalbyO. M.ShalbyO. M.

 Эль-Менуфия 

EisaW. H.EisaW. H.El-KousyS. M.El-KousyS. M.

 Эль-Менуфия 

EltorgomanA М.EltorgomanA. M.

 Эль-Менуфия 

Университет МенуфияChemistry Department, Faculty of Science, Menoufia UniversityНациональный исследовательский центр (NRC)Spectroscopy Department, Physics Division, National Research Centre (NRC)202225032022892290290Copyright © Zayed M.F., Shalby O.M., Eisa W.H., El-Kousy S.M., Eltorgoman A.М., 20222022Zayed M.F., Shalby O.M., Eisa W.H., El-Kousy S.M., Eltorgoman A.М.Zayed M.F., Shalby O.M., Eisa W.H., El-Kousy S.M., Eltorgoman A.M.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://zhps.ejournal.by/jour/article/view/1020

Наночастицы серебра (AgNPs) и золота (AuNPs) синтезированы экологически чистым методом с использованием экстракта Ficus sycomorus. Настройка экспериментальных параметров (количества извлеченного, концентрации ионов металлов и значения pH) позволяет контролировать размер, форму и распределение наночастиц по размерам. С помощью УФ-видимой спектроскопии выявлены изменения спектрального профиля поверхностного плазмонного резонанса наночастиц в различных условиях. Получение монодисперсных сферических AgNPs (4 нм) и AuNPs (11 нм) подтверждено методом просвечивающей электронной микроскопии. По данным ИК-Фурье-спектроскопии, флавоноидные гликозиды играют главную роль в восстановлении и стабилизации ионов металлов. Свежеприготовленные AgNP и AuNP использованы в качестве экологичных катализаторов для эффективного разложения метиленового синего в присутствии боргидрида натрия.

Plant-mediated synthesis of nanoparticles (NPs) is an efficient and safe alternative to the conventional synthetic route. In this study, silver and gold NPs (AgNPs and AuNPs, respectively) were synthesized via a green route using Ficus sycomorus extract. Tuning the experimental parameters (namely, extract quantity, metal ion concentration, and pH value) allowed control over the size, shape, and size distribution of the NPs. UV-visible spectroscopy has been utilized to monitor the spectral profile changes of the surface plasmon resonance of the NPs under various conditions. The successful preparation of monodispersed spherical AgNPs (4 nm) and AuNPs (11 nm) was confirmed by transmission electron microscopic analysis. Fourier transform infrared spectroscopic data indicated that flavonoid glycosides played a major role in the reduction and stabilization of metal ions. The as-prepared AgNPs and AuNPs were then used as green catalysts for efficient degradation of methylene blue in the presence of sodium borohydride.

экстракт Ficus sycomorusнаночастицы золотананочастицы серебраконтролируемый синтезкаталитическая активностьFicus sycomorusgold nanoparticlessilver nanoparticlescontrolled synthesiscatalytic activityReferencesA. V. Kalenskii, A. A. Zvekov, A. P. Nikitin, J. Appl. Spectrosc., 83, 1020–1025 (2017).A. V. Kalenskii, A. A. Zvekov, A. P. Nikitin, J. Appl. Spectrosc., 83, 1020–1025 (2017).P. Slepička, N. Slepičková Kasálková, J. Siegel, Z. Kolská, V. Švorčík, Materials, 13, 1 (2019).P. Slepička, N. Slepičková Kasálková, J. Siegel, Z. Kolská, V. Švorčík, Materials, 13, 1 (2019).S. He, Z. Guo, Y. Zhang, S. Zhang, J. Wang, N. Gu, Mater. Lett., 61, 3984–3987 (2007).S. He, Z. Guo, Y. Zhang, S. Zhang, J. Wang, N. Gu, Mater. Lett., 61, 3984–3987 (2007).A. Zuorro, A. Iannone, S. Natali, R. Lavecchia, Processes, 7, 193 (2019).A. Zuorro, A. Iannone, S. Natali, R. Lavecchia, Processes, 7, 193 (2019).S. Wang, K. Qian, X. Bi, W. Huang, J. Phys. Chem. C, 113, 6505–6510 (2009).S. Wang, K. Qian, X. Bi, W. Huang, J. Phys. Chem. C, 113, 6505–6510 (2009).M. F. Zayed, W. H. Eisa, S. M. El-Kousy, W. K. Mleha, N. Kamal, Spectrochim. Acta A, Mol. Biomol. Spectrosc., 214, 496–512 (2019).M. F. Zayed, W. H. Eisa, S. M. El-Kousy, W. K. Mleha, N. Kamal, Spectrochim. Acta A, Mol. Biomol. Spectrosc., 214, 496–512 (2019).Y. Foo, V. Periasamy, L. Kiew, G. Kumar, S. Malek, Nanomaterials, 7, 123 (2017).Y. Foo, V. Periasamy, L. Kiew, G. Kumar, S. Malek, Nanomaterials, 7, 123 (2017).S. Phukan, P. Bharali, A. K. Das, M. H. Rashid, RSC Adv., 6, 49307–49316 (2016).S. Phukan, P. Bharali, A. K. Das, M. H. Rashid, RSC Adv., 6, 49307–49316 (2016).M. Amin, F. Anwar, M. R. S. A. Janjua, M. A. Iqbal, U. Rashid, Int. J. Mol. Sci., 13, 9923–9941 (2012).M. Amin, F. Anwar, M. R. S. A. Janjua, M. A. Iqbal, U. Rashid, Int. J. Mol. Sci., 13, 9923–9941 (2012).S. Iravani, Green Chem., 13, 2638 (2011).S. Iravani, Green Chem., 13, 2638 (2011).M. F. Zayed, R. A. Mahfoze, S. M. El-kousy, E. A. Al-Ashkar, Colloids Surf. A: Physicochem. Eng. Aspects, 585, 124167 (2020).M. F. Zayed, R. A. Mahfoze, S. M. El-kousy, E. A. Al-Ashkar, Colloids Surf. A: Physicochem. Eng. Aspects, 585, 124167 (2020).C. Shi, N. Zhu, Y. Cao, P. Wu, Nanoscale Res. Lett., 10 (2015).C. Shi, N. Zhu, Y. Cao, P. Wu, Nanoscale Res. Lett., 10 (2015).N. Konai, D. Raidandi, A. Pizzi, L. Meva’a, Eur. J. Wood and Wood Prod., 75, 807–815 (2017).N. Konai, D. Raidandi, A. Pizzi, L. Meva’a, Eur. J. Wood and Wood Prod., 75, 807–815 (2017).O. Mousa, P. Vuorela, J. Kiviranta, S. A. Wahab, R. Hiltunen, H. Vuorela, J. Ethnopharmacol., 41, 71–76 (1994).O. Mousa, P. Vuorela, J. Kiviranta, S. A. Wahab, R. Hiltunen, H. Vuorela, J. Ethnopharmacol., 41, 71–76 (1994).H. S. Foyet, S. Tchinda Deffo, P. Koagne Yewo, I. Antioch, S. Zingue, E. A. Asongalem, P. Kamtchouing, A. Ciobica, BMC Complementary Altern. Med., 17 (2017).H. S. Foyet, S. Tchinda Deffo, P. Koagne Yewo, I. Antioch, S. Zingue, E. A. Asongalem, P. Kamtchouing, A. Ciobica, BMC Complementary Altern. Med., 17 (2017).E.-S. S. Abdel-Hameed, Food Chem., 114, 1271–1277 (2009).E.-S. S. Abdel-Hameed, Food Chem., 114, 1271–1277 (2009).M. Amjadi, T. Sodouri, J. Appl. Spectrosc., 81, 232–237 (2014).M. Amjadi, T. Sodouri, J. Appl. Spectrosc., 81, 232–237 (2014).R. A. Boitor, I. S. Tódor, L. F. Leopold, N. Leopold, J. Appl. Spectrosc., 82, 415–419 (2015).R. A. Boitor, I. S. Tódor, L. F. Leopold, N. Leopold, J. Appl. Spectrosc., 82, 415–419 (2015).N. Esmaile, M. R. Sohrabi, F. Motiee, J. Appl. Spectrosc., 87, 372–377 (2020).N. Esmaile, M. R. Sohrabi, F. Motiee, J. Appl. Spectrosc., 87, 372–377 (2020).R. R. Shamilov, V. I. Nuzhdin, V. F. Valeev, Y. G. Galyametdinov, A. L. Stepanov, J. Appl. Spectrosc., 82, 773–778 (2015).R. R. Shamilov, V. I. Nuzhdin, V. F. Valeev, Y. G. Galyametdinov, A. L. Stepanov, J. Appl. Spectrosc., 82, 773–778 (2015).E. Seo, S.-J. Ko, S. H. Min, J. Y. Kim, B.-S. Kim, Chem. Mater., 27, 4789–4798 (2015).E. Seo, S.-J. Ko, S. H. Min, J. Y. Kim, B.-S. Kim, Chem. Mater., 27, 4789–4798 (2015).A. D. Dwivedi, K. Gopal, Colloids Surf. A: Physicochem. Eng. Aspects, 369, 27–33 (2010).A. D. Dwivedi, K. Gopal, Colloids Surf. A: Physicochem. Eng. Aspects, 369, 27–33 (2010).P. Galinetto, A. Taglietti, L. Pasotti, P. Pallavicini, G. Dacarro, E. Giulotto, M. S. Grandi, J. Appl. Spectrosc., 82, 1052–1059 (2016).P. Galinetto, A. Taglietti, L. Pasotti, P. Pallavicini, G. Dacarro, E. Giulotto, M. S. Grandi, J. Appl. Spectrosc., 82, 1052–1059 (2016).K. R. Aadil, A. Barapatre, A. S. Meena, H. Jha, Int. J. Biol. Macromol., 82, 39–47 (2016).K. R. Aadil, A. Barapatre, A. S. Meena, H. Jha, Int. J. Biol. Macromol., 82, 39–47 (2016).M. F. Zayed, W. H. Eisa, A. M. Hezma, J. Appl. Spectrosc., 83, 1046–1050 (2017).M. F. Zayed, W. H. Eisa, A. M. Hezma, J. Appl. Spectrosc., 83, 1046–1050 (2017).N. Yang, W.-H. Li, Ind. Crops Prod., 48, 81–88 (2013).N. Yang, W.-H. Li, Ind. Crops Prod., 48, 81–88 (2013).M. M. H. Khalil, E. H. Ismail, K. Z. El-Baghdady, D. Mohamed, Arab. J. Chem., 7, 1131–1139 (2014).M. M. H. Khalil, E. H. Ismail, K. Z. El-Baghdady, D. Mohamed, Arab. J. Chem., 7, 1131–1139 (2014).C. Krishnaraj, R. Ramachandran, K. Mohan, P. T. Kalaichelvan, Spectrochim. Acta A: Mol. Biomol. Spectrosc., 93, 95–99 (2012).C. Krishnaraj, R. Ramachandran, K. Mohan, P. T. Kalaichelvan, Spectrochim. Acta A: Mol. Biomol. Spectrosc., 93, 95–99 (2012).Y. Li, Y. Li, Q. Li, X. Fan, J. Gao, Y. Luo, J. Chem., 2016, 1–7 (2016).Y. Li, Y. Li, Q. Li, X. Fan, J. Gao, Y. Luo, J. Chem., 2016, 1–7 (2016).M. F. Zayed, W. H. Eisa, Spectrochim. Acta A: Mol. Biomol. Spectrosc., 121, 238–244 (2014).M. F. Zayed, W. H. Eisa, Spectrochim. Acta A: Mol. Biomol. Spectrosc., 121, 238–244 (2014).G. Tondi, A. Petutschnigg, Ind. Crops Prod., 65, 422–428 (2015).G. Tondi, A. Petutschnigg, Ind. Crops Prod., 65, 422–428 (2015).M. M. M. El-Sayed, M. A.-A. El-Nahas, H. A.-K. El-Sayed, W. El-Eman, Ghareeb Mosad, Pharmacologyonline, 3, 317–332 (2010).M. M. M. El-Sayed, M. A.-A. El-Nahas, H. A.-K. El-Sayed, W. El-Eman, Ghareeb Mosad, Pharmacologyonline, 3, 317–332 (2010).F. Tasca, R. Antiochia, Nanomaterials, 10, 909 (2020).F. Tasca, R. Antiochia, Nanomaterials, 10, 909 (2020).M. S. Coutinho, E. Latocheski, J. M. Neri, A. C. O. Neves, J. B. Domingos, L. N. Cavalcanti, L. H. S. Gasparotto, E. P. Moraes, F. G. Menezes, RSC Adv., 9, 30007–30011 (2019).M. S. Coutinho, E. Latocheski, J. M. Neri, A. C. O. Neves, J. B. Domingos, L. N. Cavalcanti, L. H. S. Gasparotto, E. P. Moraes, F. G. Menezes, RSC Adv., 9, 30007–30011 (2019).Z. D. Ozdal, E. Sahmetlioglu, I. Narin, A. Cumaoglu, Biotech., 9 (2019).Z. D. Ozdal, E. Sahmetlioglu, I. Narin, A. Cumaoglu, Biotech., 9 (2019).N. Sahu, D. Soni, B. Chandrashekhar, D. B. Satpute, S. Saravanadevi, B. K. Sarangi, R. A. Pandey, Int. Nano Lett., 6, 173–181 (2016).N. Sahu, D. Soni, B. Chandrashekhar, D. B. Satpute, S. Saravanadevi, B. K. Sarangi, R. A. Pandey, Int. Nano Lett., 6, 173–181 (2016).A. M. Atta, Y. M. Moustafa, H. A. Al-Lohedan, A. O. Ezzat, A. I. Hashem, ACS Omega, 5, 2829–2842 (2020).A. M. Atta, Y. M. Moustafa, H. A. Al-Lohedan, A. O. Ezzat, A. I. Hashem, ACS Omega, 5, 2829–2842 (2020).N. G. Bastús, F. Merkoçi, J. Piella, V. Puntes, Chem. Mater., 26, 2836–2846 (2014).N. G. Bastús, F. Merkoçi, J. Piella, V. Puntes, Chem. Mater., 26, 2836–2846 (2014).A. Bhargava, N. Jain, M. A. Khan, V. Pareek, R. V. Dilip, J. Panwar, J. Environ. Manag., 183, 22–32 (2016).A. Bhargava, N. Jain, M. A. Khan, V. Pareek, R. V. Dilip, J. Panwar, J. Environ. Manag., 183, 22–32 (2016).G. A. Molina, R. Esparza, J. L. López-Miranda, A. R. Hernández-Martínez, B. L. España-Sánchez,G. A. Molina, R. Esparza, J. L. López-Miranda, A. R. Hernández-Martínez, B. L. España-Sánchez,E. A. Elizalde-Peña, M. Estevez, Colloids Surf. B: Biointerfaces, 180, 141–149 (2019).E. A. Elizalde-Peña, M. Estevez, Colloids Surf. B: Biointerfaces, 180, 141–149 (2019).M. Rafique, I. Sadaf, M. B. Tahir, M. S. Rafique, G. Nabi, T. Iqbal, K. Sughra, Mater. Sci. Eng. C, 99, 1313–1324 (2019).M. Rafique, I. Sadaf, M. B. Tahir, M. S. Rafique, G. Nabi, T. Iqbal, K. Sughra, Mater. Sci. Eng. C, 99, 1313–1324 (2019).B. Kumar, K. Smita, L. Cumbal, J. Sol-Gel Sci. Technol., 78, 285–292 (2015).B. Kumar, K. Smita, L. Cumbal, J. Sol-Gel Sci. Technol., 78, 285–292 (2015).S. Francis, K. M. Nair, N. Paul, E. P. Koshy, B. Mathew, Mater. Today: Proc., 9, 97–104 (2019).S. Francis, K. M. Nair, N. Paul, E. P. Koshy, B. Mathew, Mater. Today: Proc., 9, 97–104 (2019).L. Sherin, A. Sohail, U.-e.-S. Amjad, M. Mustafa, R. Jabeen, A. Ul-Hamid, Colloid Interface Sci. Commun., 37, 100276 (2020).L. Sherin, A. Sohail, U.-e.-S. Amjad, M. Mustafa, R. Jabeen, A. Ul-Hamid, Colloid Interface Sci. Commun., 37, 100276 (2020).A. Rajan, V. Vilas, D. Philip, J. Mol. Liquids, 207, 231–236 (2015).A. Rajan, V. Vilas, D. Philip, J. Mol. Liquids, 207, 231–236 (2015).V. S. Suvith, D. Philip, Spectrochim. Acta A: Mol. Biomol. Spectrosc., 118, 526–532 (2014).V. S. Suvith, D. Philip, Spectrochim. Acta A: Mol. Biomol. Spectrosc., 118, 526–532 (2014).A. Nouri, M. Tavakkoli Yaraki, A. Lajevardi, Z. Rezaei, M. Ghorbanpour, M. Tanzifi, Colloid Interface Sci. Commun., 35, 100252 (2020).A. Nouri, M. Tavakkoli Yaraki, A. Lajevardi, Z. Rezaei, M. Ghorbanpour, M. Tanzifi, Colloid Interface Sci. Commun., 35, 100252 (2020).S. Hamedi, S. A. Shojaosadati, Polyhedron, 171, 172–180 (2019).S. Hamedi, S. A. Shojaosadati, Polyhedron, 171, 172–180 (2019).B. C. Choudhary, D. Paul, T. Gupta, S. R. Tetgure, V. J. Garole, A. U. Borse, D. J. Garole, J. Environ. Sci., 55, 236–246 (2017).B. C. Choudhary, D. Paul, T. Gupta, S. R. Tetgure, V. J. Garole, A. U. Borse, D. J. Garole, J. Environ. Sci., 55, 236–246 (2017).J. Das, P. Velusamy, J. Taiwan Inst. Chem. Eng., 45, 2280–2285 (2014).J. Das, P. Velusamy, J. Taiwan Inst. Chem. Eng., 45, 2280–2285 (2014).N. K. R. Bogireddy, K. K. Hoskote Anand, B. K. Mandal, J. Mol. Liq., 211, 868–875 (2015).N. K. R. Bogireddy, K. K. Hoskote Anand, B. K. Mandal, J. Mol. Liq., 211, 868–875 (2015).B. Kumar, K. Smita, L. Cumbal, A. Debut, J. Photochem. Photobiol. B: Biol., 158, 55–60 (2016).B. Kumar, K. Smita, L. Cumbal, A. Debut, J. Photochem. Photobiol. B: Biol., 158, 55–60 (2016).B. Paul, B. Bhuyan, D. D. Purkayastha, S. Vadivel, S. S. Dhar, Mater. Lett., 185, 143–147 (2016).B. Paul, B. Bhuyan, D. D. Purkayastha, S. Vadivel, S. S. Dhar, Mater. Lett., 185, 143–147 (2016).B. Paul, B. Bhuyan, D. D. Purkayastha, S. S. Dhar, J. Photochem. Photobiol. B: Biol., 154, 1–7 (2016).B. Paul, B. Bhuyan, D. D. Purkayastha, S. S. Dhar, J. Photochem. Photobiol. B: Biol., 154, 1–7 (2016).

The authors declare that there are no conflicts of interest present.