zhpsЖурнал прикладной спектроскопииZhurnal Prikladnoii Spektroskopii0514-7506B. I. Stepanov Institute of Physics of the National Academy of Scienceszhps-1069Research ArticleАННОТАЦИИ АНГЛОЯЗЫЧНЫХ СТАТЕЙABSTRACTS ENGLISH-LANGUAGE ARTICLESИспользование ультразвуковой дисперсионной микротвердофазной экстракции для концентрирования следов кобальта и никеля и их прецизионного определения в образцах окружающей среды с помощью пламенной атомно-абсорбционной спектрометрииUltrasound-Assisted Dispersive Microsolid-Phase Extraction for Preconcentration of Trace Cobalt and Nickel in Environmental Samples Prior to Their Determination by Flame Atomic Absorption SpectrometryGoudaA. A.GoudaA. A.

Загазиг

Zagazig

aymangouda77@gmail.comEl SheikhR.El SheikhR.

Zagazig

El SayedH. M.El SayedH. M.

Загазиг

Zagazig

KhedrA. M.KhedrA. M.

Танта

Tanta

Abo Al EzzSh.Abo Al EzzSh.

Загазиг

Zagazig

GamilW.GamilW.

Загазиг

Zagazig

HamdyM.HamdyM.

Порт-Саид

Port Said

Университет ЗагазигаZagazig UniversityУниверситет ТантыTanta UniversityУниверситет Порт-СаидаPort Said University202226052022893433433Copyright © Gouda A.A., El Sheikh R., El Sayed H.M., Khedr A.M., Abo Al Ezz S., Gamil W., Hamdy M., 20222022Gouda A.A., El Sheikh R., El Sayed H.M., Khedr A.M., Abo Al Ezz S., Gamil W., Hamdy M.Gouda A.A., El Sheikh R., El Sayed H.M., Khedr A.M., Abo Al Ezz S., Gamil W., Hamdy M.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://zhps.ejournal.by/jour/article/view/1069

Разработан простой и экологичный подход к ультразвуковой дисперсионной микротвердофазной экстракции с использованием новых модифицированных адсорбентом многостенных углеродных нанотрубок (MWCNTs) для разделения и предварительной концентрации ионов кобальта Co(II) и никеля Ni(II) в различных образцах окружающей среды перед определением методом пламенной атомно-абсорбционной спектрометрии. Предлагаемый метод основан на модификации MWCNTs комплексообразователем 3-(2,4-дигидроксифен-1-илазо)-1,2,4-триазолом, который образует комплекс с ионами Co(II) или Ni(II) в качестве селективного и эффективного сорбента при рН 8.0. Исследовано и оптимизировано влияние различных параметров. Калибровочные кривые линейные в пределах 1.0–200 и 2.0–300 мкг/л; пределы обнаружения при оптимальных условиях 0.30 и 0.60 мкг/л для ионов Co(II) и Ni(II). Коэффициент предварительной концентрации 200. Максимальная сорбционная способность Co(II) и Ni(II) ~300 и 380 мг/г. Показатели извлечения анализируемых веществ 96.0—102 %. Относительное стандартное отклонение (RSD%) для внутрисуточной и межсуточной повторяемостей 1.30, 1.70 % и 1.750, 1.95% для Co(II) и Ni(II) соответственно. Сертифицированные справочные материалы (листья шпината SRM 1570A и обогащенная вода TMDA-52.3) использованы для проверки точности предлагаемого протокола предварительной концентрации. Метод успешно применен для определения содержания ионов Co(II) и Ni(II) в образцах воды, соков и пищевых продуктов.

A new, green, simple, and validated ultrasound-assisted dispersive microsolid-phase extraction method applying unprecedented adsorbent-modified multiwalled carbon nanotubes was achieved for preconcentration and separation of trace cobalt (Co(II)) and nickel (Ni(II)) ions in diverse ecological samples before determination by flame atomic absorption spectrometry. The suggested approach uses a novel chelating agent named 3-(2,4-dihydroxyphen-1-ylazo)-1,2,4-triazole, which is chelated with Co(II) or Ni(II) ions as efficient and selective sorbent at pH 8.0. The impact of many parameters has been studied and optimized. Under ideal conditions, the calibration curves were linear within 1.0–200 and 2.0–300 μg/L ranges, with limits of detection equaling 0.30 and 0.60 μg/L for Co(II) and Ni(II) ions, respectively. The preconcentration factor attained 200, while the highest sorption capacities of Co(II) and Ni(II) are around 300 and 380 mg/g, respectively. The relative standard deviation (%RSD) regarding repeatability for Co(II) and Ni(II) upon calculation was 1.30 and 1.70% for intraday, and 1.750 and 1.95% for interday. To ensure the correctness of the suggested preconcentration approach, certified reference materials (SRM 1570A spinach leaves and TMDA-52.3 enriched water) were employed. The proposed approach was applied to determine the concentration of Co(II) and Ni(II) ions in a range of genuine water, juice, and food samples, and the findings were excellent.

ультразвуковая дисперсионная микротвердофазная экстракциямногостенные углеродные нанотрубкикобальтникельобразцы окружающей средыпламенная атомноабсорбционная спектрометрияultrasound-assisted dispersive microsolid-phase extractionmultiwalled carbon nanotubescobaltnickelenvironmental samplesflame atomic absorption spectrometryReferencesATSDR, Toxicological Profile for Cobalt, U. S. Department of Health and Human Services, Atlanta (2001).ATSDR, Toxicological Profile for Cobalt, U. S. Department of Health and Human Services, Atlanta (2001).A. A. Gouda, R. El Sheikh, A. M. Khedr, S. Abo Al Ezz, W. Gamil, M. M. El-Gabry, E. H. Youssef, Int. J. Environ. Anal. Chem. (2021), doi: 10.1080/03067319.2021.1928106.A. A. Gouda, R. El Sheikh, A. M. Khedr, S. Abo Al Ezz, W. Gamil, M. M. El-Gabry, E. H. Youssef, Int. J. Environ. Anal. Chem. (2021), doi: 10.1080/03067319.2021.1928106.S. Dahiya, R. Karpe, A. G. Hegde, R. M. Sharma, J. Food Compos. Anal., 18, 517–522 (2005).S. Dahiya, R. Karpe, A. G. Hegde, R. M. Sharma, J. Food Compos. Anal., 18, 517–522 (2005).Y. Şahan, F. Basoglu, S. Gücer, Food. Chem., 105, 395–399 (2007).Y. Şahan, F. Basoglu, S. Gücer, Food. Chem., 105, 395–399 (2007).W. J. Barreto, S. R. G. Barreto, I. S. Scarminio, D. N. Ishikawa, M. F. Soares, M. V. B. de Proença, Quim. Nova, 33, 109–113 (2010).W. J. Barreto, S. R. G. Barreto, I. S. Scarminio, D. N. Ishikawa, M. F. Soares, M. V. B. de Proença, Quim. Nova, 33, 109–113 (2010).N. Baghban, A. M. H. Shabani, S. Dadfarnia, A. A. Jafari, J. Braz. Chem. Soc., 20, 832–838 (2009).N. Baghban, A. M. H. Shabani, S. Dadfarnia, A. A. Jafari, J. Braz. Chem. Soc., 20, 832–838 (2009).J. E. O’Sullivan, R. J. Watson, E. C. V. Butler, Talanta, 115, 999–1010 (2013).J. E. O’Sullivan, R. J. Watson, E. C. V. Butler, Talanta, 115, 999–1010 (2013).F. Nekouei, S. Nekouei, Indian J. Sci. Res., 8, 138–145 (2014).F. Nekouei, S. Nekouei, Indian J. Sci. Res., 8, 138–145 (2014).M. A. Akl, S. A. Ahmad, Egypt. J. Chem., 62, 1917–1931 (2019).M. A. Akl, S. A. Ahmad, Egypt. J. Chem., 62, 1917–1931 (2019).M. Sadia, M. R. Jan, J. Shah, G. M. Greenway, Int. J. Environ. Anal. Chem., 93, 1537–1556 (2013).M. Sadia, M. R. Jan, J. Shah, G. M. Greenway, Int. J. Environ. Anal. Chem., 93, 1537–1556 (2013).B. Feist, B. Mikula, Food Chem., 147, 302–306 (2014).B. Feist, B. Mikula, Food Chem., 147, 302–306 (2014).S. V. Smirnova, D. V. Ilin, I. V. Pletnev, Talanta, 221, 121485 (2021).S. V. Smirnova, D. V. Ilin, I. V. Pletnev, Talanta, 221, 121485 (2021).Z. A. Alothman, Y. E., Unsal M. Habila, M. Tuzen, M. Soylak, Desalin. Water Treat., 53, 3457–3465 (2015).Z. A. Alothman, Y. E., Unsal M. Habila, M. Tuzen, M. Soylak, Desalin. Water Treat., 53, 3457–3465 (2015).M. Ghaedi, A. Shokrollahi, F. Ahmadi, H. R. Rajabi, M. Soylak, J. Hazard Mater., 150, 533–540 (2008).M. Ghaedi, A. Shokrollahi, F. Ahmadi, H. R. Rajabi, M. Soylak, J. Hazard Mater., 150, 533–540 (2008).D. Citak, M. Tuzen, M. Soylak, Food Chem. Toxic., 47, 2302–2307 (2009).D. Citak, M. Tuzen, M. Soylak, Food Chem. Toxic., 47, 2302–2307 (2009).S. Saracoglu, M. Soylak, D. Çabuk, Z. Topalak, Y. Karagozlu, J. AOAC Int., 95, 892–896 (2012).S. Saracoglu, M. Soylak, D. Çabuk, Z. Topalak, Y. Karagozlu, J. AOAC Int., 95, 892–896 (2012).L. S. Moreira, Í. P. Sá, R. C. Machado, A. R. A. Nogueira, E. G. P. da Silva, C. D. B. Amaral, Spectrochim. Acta B, At. Spectrosc., 169, 105899 (2020).L. S. Moreira, Í. P. Sá, R. C. Machado, A. R. A. Nogueira, E. G. P. da Silva, C. D. B. Amaral, Spectrochim. Acta B, At. Spectrosc., 169, 105899 (2020).M. Soylak, A. Aydin, N. Kizil, J. AOAC Int., 99, 273–278 (2016).M. Soylak, A. Aydin, N. Kizil, J. AOAC Int., 99, 273–278 (2016).E. Yildiz, Ş. Saçmaci, Ş. Kartal, M. Saçmaci, Food Chem., 194, 143–148 (2016).E. Yildiz, Ş. Saçmaci, Ş. Kartal, M. Saçmaci, Food Chem., 194, 143–148 (2016).H. Serencam, C. Duran, D. Ozdes, H. Bektas, Acta Chim. Slov., 60, 287–293 (2013).H. Serencam, C. Duran, D. Ozdes, H. Bektas, Acta Chim. Slov., 60, 287–293 (2013).M. Soylak, A. Aydin, Food Chem. Toxic., 49, 1242–1248 (2011).M. Soylak, A. Aydin, Food Chem. Toxic., 49, 1242–1248 (2011).Z. A. Alothman, E. Yilmaz, M. Habila, M. Soylak, Turk. J. Chem., 39, 1038–1049 (2015).Z. A. Alothman, E. Yilmaz, M. Habila, M. Soylak, Turk. J. Chem., 39, 1038–1049 (2015).G. Alpdoğan, Toxicol. Environ. Chem., 98, 179–188 (2016).G. Alpdoğan, Toxicol. Environ. Chem., 98, 179–188 (2016).B. Topuz, Biol. Trace Elem. Res., 194, 295–302 (2020).B. Topuz, Biol. Trace Elem. Res., 194, 295–302 (2020).M. A. Habila, Z. A. Alothman, E. Yilmaz, M. Soylak, Int. J. Environ. Anal. Chem., 98, 171–181 (2018).M. A. Habila, Z. A. Alothman, E. Yilmaz, M. Soylak, Int. J. Environ. Anal. Chem., 98, 171–181 (2018).A. Duran, M. Tuzen, M. Soylak, J. Hazard. Mater., 169, 466–471 (2009).A. Duran, M. Tuzen, M. Soylak, J. Hazard. Mater., 169, 466–471 (2009).L. Meng, C. Chen, Y. Yang, Anal. Lett., 48, 453–463 (2015).L. Meng, C. Chen, Y. Yang, Anal. Lett., 48, 453–463 (2015).M. Soylak, E. Yilmaz, J. Hazard Mater., 182, 704–709 (2010).M. Soylak, E. Yilmaz, J. Hazard Mater., 182, 704–709 (2010).M. Shirani, F. Salari, S. Habibollahi, A. Akbari, Microchem. J., 152, 104332–104340 (2020).M. Shirani, F. Salari, S. Habibollahi, A. Akbari, Microchem. J., 152, 104332–104340 (2020).M. Ghaedi, A. Shokrollahi, F. Ahmadi, H. R. Rajabi, M. Soylak, J. Hazard Mater., 150, 533–540 (2008).M. Ghaedi, A. Shokrollahi, F. Ahmadi, H. R. Rajabi, M. Soylak, J. Hazard Mater., 150, 533–540 (2008).A. A. Gouda, A. M. Summan, A. H. Amin, RSC Adv., 6, 94048–94057 (2016).A. A. Gouda, A. M. Summan, A. H. Amin, RSC Adv., 6, 94048–94057 (2016).N. K. Temel, K. Sertakan, R. Gürkan, Biol. Trace Elem. Res., 186, 597–607 (2019).N. K. Temel, K. Sertakan, R. Gürkan, Biol. Trace Elem. Res., 186, 597–607 (2019).H. Xu, W. Zhang, X. Zhang, J. Wang, J. Wang, Proc. Environ. Sci., 18, 258–263 (2013).H. Xu, W. Zhang, X. Zhang, J. Wang, J. Wang, Proc. Environ. Sci., 18, 258–263 (2013).A. Moghimi, M. J. Poursharifi, Asian J. Chem., 23, 1435–1438 (2011).A. Moghimi, M. J. Poursharifi, Asian J. Chem., 23, 1435–1438 (2011).M. Bahram, S. Khezri, Anal. Methods, 4, 384–393 (2012).M. Bahram, S. Khezri, Anal. Methods, 4, 384–393 (2012).M. Soylak, M. Koksal, Microchem. J., 147, 832–837 (2019)M. Soylak, M. Koksal, Microchem. J., 147, 832–837 (2019)S. M. Sorouraddin, M. A. Farajzadeh, T. Okhravi, Sep. Sci. Technol., 55, 2955–2966 (2020).S. M. Sorouraddin, M. A. Farajzadeh, T. Okhravi, Sep. Sci. Technol., 55, 2955–2966 (2020).T. Okhravi, S. M. Sorouraddin, M. A. Farajzadeh, A. Mohebbi, Anal. Bioanal. Chem., 412, 1675–1684 (2020).T. Okhravi, S. M. Sorouraddin, M. A. Farajzadeh, A. Mohebbi, Anal. Bioanal. Chem., 412, 1675–1684 (2020).Ç. Arpa, I. Arıdaşır, Food Chem., 284, 16–22 (2019).Ç. Arpa, I. Arıdaşır, Food Chem., 284, 16–22 (2019).N. Khorshidi, A. Niazi, Sep. Sci. Technol., 51, 1675–1683 (2016).N. Khorshidi, A. Niazi, Sep. Sci. Technol., 51, 1675–1683 (2016).B. Barfi, M Rajabi, A. Asghari, Biol. Trace Elem. Res., 170, 496–507 (2016).B. Barfi, M Rajabi, A. Asghari, Biol. Trace Elem. Res., 170, 496–507 (2016).H. R. Sobhi, A. Mohammadzadeh, M. Behbahani, A. Esrafili, Microchem. J., 146, 782–788 (2019).H. R. Sobhi, A. Mohammadzadeh, M. Behbahani, A. Esrafili, Microchem. J., 146, 782–788 (2019).M. Rajabi, M. Abolhosseini, A. Hosseini-Bandegharaei, M. Hemmati, N. Ghassab, Microchem. J., 159, 105450 (2020).M. Rajabi, M. Abolhosseini, A. Hosseini-Bandegharaei, M. Hemmati, N. Ghassab, Microchem. J., 159, 105450 (2020).J. M. Nakhaei, M. R. Jamali, S. Sohrabnezhad, R. Rahnama, Microchem. J., 144, 88–92 (2019).J. M. Nakhaei, M. R. Jamali, S. Sohrabnezhad, R. Rahnama, Microchem. J., 144, 88–92 (2019).B. Feist, R. Sitko, Microchem. J., 147, 30–36 (2019).B. Feist, R. Sitko, Microchem. J., 147, 30–36 (2019).C. H. Latorre, J. A. Mendez, J. B. Garcia, S. G. Martin, R. M. P. Crecente, Anal. Chim. Acta, 749, 16–35 (2012).C. H. Latorre, J. A. Mendez, J. B. Garcia, S. G. Martin, R. M. P. Crecente, Anal. Chim. Acta, 749, 16–35 (2012).M. Krawczyk, M. Jeszka-Skowron, Microchem. J., 126, 296–301 (2016).M. Krawczyk, M. Jeszka-Skowron, Microchem. J., 126, 296–301 (2016).M. Soylak, E. Yilmaz, M. Ghaedi, M. Montazerozohori, Toxicol. Environ. Chem., 93, 873–885 (2011).M. Soylak, E. Yilmaz, M. Ghaedi, M. Montazerozohori, Toxicol. Environ. Chem., 93, 873–885 (2011).B. Feist, Food Chem., 209, 37–42 (2016).B. Feist, Food Chem., 209, 37–42 (2016).Z. A. ALOthman, E. Yilmaz, M. Habila, I. H. Alsohaimi, A. M. Aldawsari, N. M. Al-Harbi, M. Soylak, RSC Adv., 5, 106905–106911 (2015).Z. A. ALOthman, E. Yilmaz, M. Habila, I. H. Alsohaimi, A. M. Aldawsari, N. M. Al-Harbi, M. Soylak, RSC Adv., 5, 106905–106911 (2015).E. Yilmaz, M. Soylak, Environ. Monit. Assess., 186, 5461–5468 (2014).E. Yilmaz, M. Soylak, Environ. Monit. Assess., 186, 5461–5468 (2014).Z. A. ALOthman, E. Yilmaz, M. Habila, M. Soylak, Ecotoxicol. Environ. Saf., 112, 74–79 (2015).Z. A. ALOthman, E. Yilmaz, M. Habila, M. Soylak, Ecotoxicol. Environ. Saf., 112, 74–79 (2015).A. A. Gouda, S. M. Al Ghannam, Food Chem., 202, 409–416 (2016).A. A. Gouda, S. M. Al Ghannam, Food Chem., 202, 409–416 (2016).S. Vellaichamy, K. Palanivelu, J. Hazard Mater., 185, 1131–1139 (2011).S. Vellaichamy, K. Palanivelu, J. Hazard Mater., 185, 1131–1139 (2011).Z. A. Al-Othman, M. Habilaa, E. Yilmaz, M. Soylak, Microchim. Acta, 177, 397–403 (2012).Z. A. Al-Othman, M. Habilaa, E. Yilmaz, M. Soylak, Microchim. Acta, 177, 397–403 (2012).A. A. Gouda, Int. J. Environ. Anal. Chem., 94, 1210–1222 (2014).A. A. Gouda, Int. J. Environ. Anal. Chem., 94, 1210–1222 (2014).A. M. Khedr, M. Gaber, Spectrosc. Lett., 38, 431–445 (2005).A. M. Khedr, M. Gaber, Spectrosc. Lett., 38, 431–445 (2005).A. M. Khedr, Chem. Pap., 60, 138–142 (2006).A. M. Khedr, Chem. Pap., 60, 138–142 (2006).H. T. S. Britton, Hydrogen Ions, 4th ed., London, Chapman and Hall, 1168 (1952).H. T. S. Britton, Hydrogen Ions, 4th ed., London, Chapman and Hall, 1168 (1952).A. A. Gouda, Talanta, 146, 435–441 (2016).A. A. Gouda, Talanta, 146, 435–441 (2016).L. A. Currie, Anal. Chim. Acta, 391, 105–126 (1999).L. A. Currie, Anal. Chim. Acta, 391, 105–126 (1999).

The authors declare that there are no conflicts of interest present.