zhpsЖурнал прикладной спектроскопииZhurnal Prikladnoii Spektroskopii0514-7506B. I. Stepanov Institute of Physics of the National Academy of Scienceszhps-1102Research ArticleАННОТАЦИИ АНГЛОЯЗЫЧНЫХ СТАТЕЙABSTRACTS ENGLISH-LANGUAGE ARTICLESИнверсия концентрации смешанного газа на основе ультрафиолетового поглощения с помощью иерархической сверточной нейронной сетиMixed Gas Concentration Inversion Based on the Ultraviolet Absorption Spectrum by a Hierarchical Convolutional Neural NetworkLuC.LuC.

Нанкин, Цзянсу

Nanjing, Jiangsu

changguilu@seu.edu.cnBianY.BianY.

Нанкин, Цзянсу

Nanjing, Jiangsu

HuX.HuX.

Нанкин, Цзянсу

Nanjing, Jiangsu

JinS.JinS.

Нанкин, Цзянсу

Nanjing, Jiangsu

HuangY.HuangY.

Нанкин, Цзянсу

Nanjing, Jiangsu

CuiY.CuiY.

Нанкин, Цзянсу

Nanjing, Jiangsu

Центр передовой фотоники, Школа электронных наук и инженерии Юго-Восточного университетаAdvanced Photonics Center, School of Electronic Science & Engineering at Southeast University202228072022894591591Copyright © Lu C., Bian Y., Hu X., Jin S., Huang Y., Cui Y., 20222022Lu C., Bian Y., Hu X., Jin S., Huang Y., Cui Y.Lu C., Bian Y., Hu X., Jin S., Huang Y., Cui Y.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://zhps.ejournal.by/jour/article/view/1102

Предложена модель иерархической сверточной нейронной сети (CNN) для инверсии концентрации смешанного газа. Проанализированы смеси SO2, NO2 и NH3, где SO2 и NO2 — исследуемые газы, NH3 — “мешающий” газ. Для образцов моделирования получены средние абсолютные ошибки 0.5  и 0.9 ppm для SO2 и NO2. Модель хорошо зарекомендовала себя при различиях интенсивности поглощения компонентов не более чем на порядок. По сравнению с одномодульной моделью результаты CNN без иерархической структуры демонстрируют, что иерархическая структура значительно снижает перекрестные помехи и повышает точность прогнозирования.

A hierarchical convolutional neural network (CNN) model for mixed gas concentration inversion  is proposed. In our experiment, mixtures of SO2, NO2, and NH3 were analyzed. SO2 and NO2 were the detected gases, while NH3 was the interfering gas. For the simulation samples, the average absolute errors were 0.5 and 0.9 ppm for SO2 and NO2, respectively. For the experimental samples, the model performed well when the absorption intensities of components differed by no more than one order of magnitude. Compared with the single-module CNN model without a hierarchical structure, the results demonstrate that  the hierarchical structure reduces cross-interference and improves the prediction accuracy to a great extent. We believe that our model will have a promising application in the field of gas detection.

спектральный анализиерархическая сверточная нейронная сетьобнаружение газаspectral analysishierarchical convolutional neural networkgas detectionThis research was funded by the National Natural Science Foundation of China (NSFC) (No. 11874107).ReferencesH. Amal, D. Shi, R. Ionescu, W. Zhang, Q. Hua, Y. Pan, L. Tao, H. Liu, H. Haick, Int. J. Cancer., 136, No. 6, E614–E622 (2015).H. Amal, D. Shi, R. Ionescu, W. Zhang, Q. Hua, Y. Pan, L. Tao, H. Liu, H. Haick, Int. J. Cancer., 136, No. 6, E614–E622 (2015).T. Xu, C. Tang, T. Yang, W. Zhu, J. Liu, Int. J. Rock Mech. Min. Sci., 43, No. 6, 905–919 (2006).T. Xu, C. Tang, T. Yang, W. Zhu, J. Liu, Int. J. Rock Mech. Min. Sci., 43, No. 6, 905–919 (2006).Y. Zhang, H. Guo, Z. Lu, L. Zhan, P. Hung, Eng. Appl. Art. Intell., 92, 103643 (2020).Y. Zhang, H. Guo, Z. Lu, L. Zhan, P. Hung, Eng. Appl. Art. Intell., 92, 103643 (2020).M. Schroter, A. Obermeier, D. Bruggemann, M. Plechschmidt, O. Klemm, J. Air Waste Manage. Ass., 53, No. 6, 716–723 (2003).M. Schroter, A. Obermeier, D. Bruggemann, M. Plechschmidt, O. Klemm, J. Air Waste Manage. Ass., 53, No. 6, 716–723 (2003).J. H. Yang, J. Jung, J. H. Ryu, J. J. Yoh, Chemosphere, 257, 127237 (2020).J. H. Yang, J. Jung, J. H. Ryu, J. J. Yoh, Chemosphere, 257, 127237 (2020).M. Lassen, D. B. Harder, A. Brusch, O. S. Nielsen, D. Heikens, S. Persijn, J. C. Petersen, Opt. Express, 25, No. 3, 1806–1814 (2017).M. Lassen, D. B. Harder, A. Brusch, O. S. Nielsen, D. Heikens, S. Persijn, J. C. Petersen, Opt. Express, 25, No. 3, 1806–1814 (2017).J. Uotila, V. Koskinen, J. Kauppinen, Vib. Spectrosc., 38, No. 1-2, 3–9 (2005).J. Uotila, V. Koskinen, J. Kauppinen, Vib. Spectrosc., 38, No. 1-2, 3–9 (2005).H. O. Edwards, J. P. Dakin, Sens. Act. B: Chem., 11, No. 1-3, 9–19 (1993).H. O. Edwards, J. P. Dakin, Sens. Act. B: Chem., 11, No. 1-3, 9–19 (1993).J. Kong, N. R. Franklin, C. Zhou, M. G. Chapline, S. Peng, K. J. Cho, H. Dai, Science, 287, No. 5453, 622625 (2000).J. Kong, N. R. Franklin, C. Zhou, M. G. Chapline, S. Peng, K. J. Cho, H. Dai, Science, 287, No. 5453, 622625 (2000).S. Herberger, M. Herold, H. Ulmer, A. Burdack-Freitag, F. Mayer, Build. Environ., 45, No. 11, 2430–2439 (2010).S. Herberger, M. Herold, H. Ulmer, A. Burdack-Freitag, F. Mayer, Build. Environ., 45, No. 11, 2430–2439 (2010).V. Kampitakis, E. Gagaoudakis, D. Zappa, E. Comini, E. Aperathitis, A. Kostopoulos, G. Kiriakidis, V. Binas, Mat. Sci. Sem. Proc., 115, 105149 (2020).V. Kampitakis, E. Gagaoudakis, D. Zappa, E. Comini, E. Aperathitis, A. Kostopoulos, G. Kiriakidis, V. Binas, Mat. Sci. Sem. Proc., 115, 105149 (2020).P. Mahbub, A. Noori, J. S. Parry, J. Davis, A. Lucieer, M. Macka, Talanta, 218, 121144 (2020).P. Mahbub, A. Noori, J. S. Parry, J. Davis, A. Lucieer, M. Macka, Talanta, 218, 121144 (2020).Z. Bielecki, T. Stacewicz, J. Smulko, J. Wojtas, Appl. Sci.-Basel., 10, No. 15, 5111 (2020).Z. Bielecki, T. Stacewicz, J. Smulko, J. Wojtas, Appl. Sci.-Basel., 10, No. 15, 5111 (2020).L. Shao, B. Fang, F. Zheng, X. Qiu, Q. He, J. Wei, C. Li, W. Zhao, Spectrochim. Acta A, 222, 117118 (2019).L. Shao, B. Fang, F. Zheng, X. Qiu, Q. He, J. Wei, C. Li, W. Zhao, Spectrochim. Acta A, 222, 117118 (2019).L. Dong, F. K. Tittel, C. Li, N. P. Sanchez, H. Wu, C. Zheng, Y. Yu, A. Sampaolo, R. J. Griffin, Opt. Express, 24, No. 6, A528–A535 (2016).L. Dong, F. K. Tittel, C. Li, N. P. Sanchez, H. Wu, C. Zheng, Y. Yu, A. Sampaolo, R. J. Griffin, Opt. Express, 24, No. 6, A528–A535 (2016).J. Zhao, S. Xiao, Optik, 195, 163142 (2019).J. Zhao, S. Xiao, Optik, 195, 163142 (2019).S. Khan, D. Newport, S. Le Calvé, Sensors, 19, No. 23, 5210 (2019).S. Khan, D. Newport, S. Le Calvé, Sensors, 19, No. 23, 5210 (2019).L. Mei, P. Guan, Z. Kong, Opt. Express, 25, No. 20, A953–A962 (2017).L. Mei, P. Guan, Z. Kong, Opt. Express, 25, No. 20, A953–A962 (2017).G. Hönninger, C. von Friedeburg, U. Platt, Atm. Chem. Phys., 4, No. 36, 231–254 (2004).G. Hönninger, C. von Friedeburg, U. Platt, Atm. Chem. Phys., 4, No. 36, 231–254 (2004).J. Mellqvist, A. Rosen, J. Quant. Spectrosc. Radiat. Transfer, 56, No. 2, 209–224 (1996).J. Mellqvist, A. Rosen, J. Quant. Spectrosc. Radiat. Transfer, 56, No. 2, 209–224 (1996).S. Determann, J. M. Lobbes, R. Reuter, J. Rullkotter, Mar. Chem., 62, No. 1-2, 137–156 (1998).S. Determann, J. M. Lobbes, R. Reuter, J. Rullkotter, Mar. Chem., 62, No. 1-2, 137–156 (1998).Y. Matsumi, H. Shigemori, K. Takahashi, Atm. Environ., 39, No. 17, 3177–3185 (2005).Y. Matsumi, H. Shigemori, K. Takahashi, Atm. Environ., 39, No. 17, 3177–3185 (2005).J. Yang, L. Du, Y. Cheng, S. Shi, C. Xiang, J. Sun, B. Chen, Opt. Express, 28, No. 13, 18728–18741 (2020).J. Yang, L. Du, Y. Cheng, S. Shi, C. Xiang, J. Sun, B. Chen, Opt. Express, 28, No. 13, 18728–18741 (2020).C. L. Hammer, G. W. Small, R. J. Combs, R. B. Knapp, R. T. Kroutil, Anal. Chem., 72, No. 7, 1680–1689 (2000).C. L. Hammer, G. W. Small, R. J. Combs, R. B. Knapp, R. T. Kroutil, Anal. Chem., 72, No. 7, 1680–1689 (2000).M. Caselli, L. Trizio, G. de Gennaro, P. Ielpo, Water Air Soil Poll., 201, No. 1-4, 365–377 (2009).M. Caselli, L. Trizio, G. de Gennaro, P. Ielpo, Water Air Soil Poll., 201, No. 1-4, 365–377 (2009).A. A. Tomchenko, G. Harmer, B. Marquis, J. Allen, Sens. Act. B: Chem., 93, No. 1-3, 126–134 (2003).A. A. Tomchenko, G. Harmer, B. Marquis, J. Allen, Sens. Act. B: Chem., 93, No. 1-3, 126–134 (2003).L. Song, H. Wu, Y. Yang, Q. Guo, J. Li, Appl. Opt., 59, No. 17, E9–E16 (2020).L. Song, H. Wu, Y. Yang, Q. Guo, J. Li, Appl. Opt., 59, No. 17, E9–E16 (2020).J. Wang, M. Shi, P. Zheng, Sh. Xue, R. Peng, J. Appl. Spectrosc., 85, 190–196 (2018).J. Wang, M. Shi, P. Zheng, Sh. Xue, R. Peng, J. Appl. Spectrosc., 85, 190–196 (2018).S. Cui, J. Wang, L. Yang, J. Wu, X. Wang, J. Pharm. Biomed. Anal., 102, 64–77 (2015).S. Cui, J. Wang, L. Yang, J. Wu, X. Wang, J. Pharm. Biomed. Anal., 102, 64–77 (2015).Y. Yu, Y. Qu, Optik, 217, 164915 (2020).Y. Yu, Y. Qu, Optik, 217, 164915 (2020).L. Xiao, K. Tong, L. Song, L. Wang, P. Wu, W. Liu, X. Zhao, Opt. Eng., 59, No. 12, 125101 (2020).L. Xiao, K. Tong, L. Song, L. Wang, P. Wu, W. Liu, X. Zhao, Opt. Eng., 59, No. 12, 125101 (2020).X. Wang, Z. Li, D. Zheng, W. Wang, J. Appl. Spectrosc., 87, 54–61 (2020).X. Wang, Z. Li, D. Zheng, W. Wang, J. Appl. Spectrosc., 87, 54–61 (2020).Y. Chen, H. Jiang, C. Li, X. Jia, P. Ghamisi, J. Geosci. Remote, 54, No. 10, 6232–6251 (2016).Y. Chen, H. Jiang, C. Li, X. Jia, P. Ghamisi, J. Geosci. Remote, 54, No. 10, 6232–6251 (2016).L. Jing, M. Zhao, P. Li, X. Xu, Measurement, 111, 1–10 (2017).L. Jing, M. Zhao, P. Li, X. Xu, Measurement, 111, 1–10 (2017).W. Wang, Y. Yang, X. Wang, W. Wang, J. Li, Opt. Eng., 58, No. 4, 040901 (2019).W. Wang, Y. Yang, X. Wang, W. Wang, J. Li, Opt. Eng., 58, No. 4, 040901 (2019).S. L. Manatt, A. L. Lane, J. Quant. Spectrosc. Radiat. Transfer, 50, 267–276 (1993).S. L. Manatt, A. L. Lane, J. Quant. Spectrosc. Radiat. Transfer, 50, 267–276 (1993).W. Schneider, G. K. Moortgat, J. P. Burrows, G. S. Tyndall, J. Photochem. Photobiol. A: Chem., 40, 195–217 (1987).W. Schneider, G. K. Moortgat, J. P. Burrows, G. S. Tyndall, J. Photochem. Photobiol. A: Chem., 40, 195–217 (1987).B. M. Cheng, H. C. Lu, H. K. Chen, M. Bahou, Y. P. Lee, A. M. Mebel, L. C. Lee, M. C. Liang, Y. L. Yung, Astrophys. J., 647, 1535–1542 (2006).B. M. Cheng, H. C. Lu, H. K. Chen, M. Bahou, Y. P. Lee, A. M. Mebel, L. C. Lee, M. C. Liang, Y. L. Yung, Astrophys. J., 647, 1535–1542 (2006).J. Brion, A. Chakir, D. Daumont, J. Malicet, C. Parisse, Chem. Phys. Lett., 213, 610–612 (1993).J. Brion, A. Chakir, D. Daumont, J. Malicet, C. Parisse, Chem. Phys. Lett., 213, 610–612 (1993).H. Grosch, A. Fateev, S. Clausen, J. Quant. Spectrosc. Radiat. Transfer, 154, 28–34 (2015).H. Grosch, A. Fateev, S. Clausen, J. Quant. Spectrosc. Radiat. Transfer, 154, 28–34 (2015).

The authors declare that there are no conflicts of interest present.