zhpsЖурнал прикладной спектроскопииZhurnal Prikladnoii Spektroskopii0514-7506B. I. Stepanov Institute of Physics of the National Academy of Scienceszhps-1185Research ArticleАННОТАЦИИ АНГЛОЯЗЫЧНЫХ СТАТЕЙABSTRACTS ENGLISH-LANGUAGE ARTICLESСинтез, характеристика и свойства рецепторов на основе олигомочевины, соединенных триэтиленгликольным мостиком, для распознавания фосфат-анионовSynthesis, Characterization, and Phosphate Anion Recognition Properties of Triethylene Glycol Bridged Oligourea ReceptorsYangZ.YangZ.

Сиань, Шэньси

Xi’an, Shaanxi

yzwxk@foxmail.comLiuJ.LiuJ.

Сиань, Шэньси

Xi’an, Shaanxi

SunS.SunS.

Сиань, Шэньси

Xi’an, Shaanxi

YuX.YuX.

Сиань, Шэньси

Xi’an, Shaanxi

LiuX.LiuX.

Сиань, Шэньси

Xi’an, Shaanxi

ZhaoS.ZhaoS.

Сиань, Шэньси

Xi’an, Shaanxi

YangZh.YangZh.

Сиань, Шэньси

Xi’an, Shaanxi

JiaX.JiaX.

Сиань, Шэньси

Xi’an, Shaanxi

Колледж химии и химической инженерии Сианьского университета науки и технологии; Главная лаборатория разведки и комплексного использования угольных ресурсов Министерства природных ресурсовCollege of Chemistry and Chemical Engineering, Xi’an University of Science and Technology; Key Laboratory of Coal Resources Exploration and Comprehensive Utilization, Ministry of Natural ResourcesКолледж химии и химической инженерии Сианьского университета науки и технологииCollege of Chemistry and Chemical Engineering, Xi’an University of Science and Technology202201122022896898898Copyright © Yang Z., Liu J., Sun S., Yu X., Liu X., Zhao S., Yang Z., Jia X., 20222022Yang Z., Liu J., Sun S., Yu X., Liu X., Zhao S., Yang Z., Jia X.Yang Z., Liu J., Sun S., Yu X., Liu X., Zhao S., Yang Z., Jia X.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://zhps.ejournal.by/jour/article/view/1185

Методами 1H ЯМР, ИК-Фурье-спектроскопии, определения температуры плавления и элементного анализа охарактеризованы два синтезированных рецептора R1 и R2 на основе олигомочевины, соединенных триэтиленгликольным мостиком. Распознающие PO43– свойства исследованы с помощью УФ-видимой спектроскопии, а также невооруженным глазом. Анализ графика Джоба подтверждает, что рецептор R1 и PO4 3– образуют комплекс при молярном соотношении 3:2, в то время как для R2 и PO43– соотношение 1:1. Рецептор R1 распознает PO43– с константой комплексообразования 1.46×105 М–1, для R2 – 2.75×105 М–1. Водородная связь R1 и R2 с PO43– исследована также при добавлении в систему ДМСО конкурентного растворителя этанола. Распознавание PO43– рецепторами R1 и R2 исследовано при добавлении в систему других анионов с той же концентрацией. 

Two triethylene glycol bridged oligourea receptors R1 and R2 were synthesized and characterized by 1H NMR, FT-IR, melting-point method and elemental analysis. The recognition properties of PO43– were studied by naked eye recognition and UV-vis spectroscopy. The Job’s plot analysis confirmed that the receptor R1 and PO43– formed a complex at a molar ratio of 3:2 while the binding ratio of R2 to PO43– was 1:1. The R1 recognized PO43– with a complexing constant of 1.46×105 M–1, and the complex constant of R2 recognizing PO43– was 2.75×105 M–1. In addition, the hydrogen bond between R1 and R2 with PO43– was examined with the method of alcohol effect by adding competitive solvent ethanol to the DMSO system. Furthermore, the recognition of PO43– by R1 and R2 was investigated through competitive measurements by adding other anions with the same concentration to the system. This study provides a simple and fast method for phosphate anion recognition. 

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The authors declare that there are no conflicts of interest present.