zhpsЖурнал прикладной спектроскопииZhurnal Prikladnoii Spektroskopii0514-7506B. I. Stepanov Institute of Physics of the National Academy of Scienceszhps-1486Research ArticleАННОТАЦИИ АНГЛОЯЗЫЧНЫХ СТАТЕЙABSTRACTS ENGLISH-LANGUAGE ARTICLESИдентификация желтовато-зеленой имитации жадеита, состоящей из волластонита и натриево-известково-глиноземно-кремнеземного стекла с сильной флуоресценциейIdentification of a Convincing Yellowish Green Jadeite Imitation with Strong Fluorescence Composed of Wollastonite and Soda–Lime–Alumina–Silica GlassGaoK.GaoK.

Гуанчжоу;

Шэньчжэнь

gaok@gzpyp.edu.cn

Guangzhou;

Shenzhen

gaok@gzpyp.edu.cn

gaob.j.gem@gmail.comQuanX.Y.QuanX.Y.

Пекин

Beijing

LiangR.LiangR.

Шэньчжэнь

Shenzhen

YuanY.YuanY.

Пекин

Beijing

GaoL.L.GaoL.L.

Иньчуань

Yinchuan

LuT.J.LuT.J.

Пекин

Beijin

ChenM.Y.ChenM. Y.

Шэньчжэнь

Shenzhen

Школа геммологии Политехнического института Гуанчжоу Панью; Шэньчжэньский научно-исследовательский институт, Национальный административный центр технологий драгоценных камней и ювелирных изделий (NGTC)School of Gemology, Guangzhou Panyu Polytechnic; Shenzhen Research Institute, National Gems & Jewellery Technology Administrative Center (NGTC)China United Test & Certification Co. Ltd.China United Test & Certification Co. Ltd.Шэньчжэньский научно-исследовательский институт, Национальный административный центр технологий драгоценных камней и ювелирных изделий (NGTC)Shenzhen Research Institute, National Gems & Jewellery Technology Administrative Center (NGTC)Школа геммологии Китайского университета геонаукSchool of Gemology, China University of Geosciences in BeijingШкола химии и химического машиностроения Университета НинсяSchool of Chemistry and Chemical Engineering, Ningxia UniversityПекинский институт NGTCBeijing Institute, NGTC202413022024911159159Copyright © Gao K., Quan X., Liang R., Yuan Y., Gao L., Lu T., Chen M.Y., 20242024Gao K., Quan X., Liang R., Yuan Y., Gao L., Lu T., Chen M.Gao K., Quan X., Liang R., Yuan Y., Gao L., Lu T., Chen M.Y.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://zhps.ejournal.by/jour/article/view/1486

Исследована имитация жадеита — востребованного нефритового минерала, который часто имитируют с использованием природных и искусственных материалов. Имитация полупрозрачная, желтовато-зеленого и белого цвета, имеет стеклянный блеск. Стандартные геммологические исследования и спектральная характеризация показали, что имитация жадеита состоит из волластонита и натриево-известково-глиноземно-кремнеземного стекла. Волластонит добавляли в процессе спекания, что отличало его от волластонитовых стекол, полученных расстеклованием в более ранних работах. Показано, что разностная спектроскопия комбинационного рассеяния света со смещенным возбуждением является экономически выгодным, эффективным и неразрушающим методом идентификации драгоценных камней и их имитаций, особенно тех, которые демонстрируют сильную флуоресценцию.

Jadeite is a sought-after jade mineral that is often imitated using natural and artificial materials. A jadeite imitation that is convincing to the naked eye is investigated. The imitation is yellowish green and white, subtranslucent, and exhibits a vitreous luster. Standard gemological testing and spectral characterization revealed the composition to be wollastonite and soda–lime–alumina–silica glass. The wollastonite was added during the sintering process, making it different to wollastonite glasses prepared by devitrification in earlier reports. The findings demonstrated that shifted excitation Raman difference spectroscopy is a cost-effective, efficient, and nondestructive technique for identifying gemstones and their imitations, particularly those showing strong fluorescence.

имитация жадеитаволластонитразностная спектроскопия комбинационного рассеяния света со смещенным возбуждениемjadeite imitationwollastoniteshifted excitation Raman difference spectroscopyThis work was supported by the NGTC Chief Scientist Apprenticeship Program (Grant No. NGTC20200909).ReferencesC. M. Ou Yang, L. Hansheng, J. Gemology, 26, No. 7, 417–424 (1999).C. M. Ou Yang, L. Hansheng, J. Gemology, 26, No. 7, 417–424 (1999).G. H. Shi, B. Stöckhert, W. Y. Cui, Mineral. Mag., 69, No. 6, 1059–1075 (2005).G. H. Shi, B. Stöckhert, W. Y. Cui, Mineral. Mag., 69, No. 6, 1059–1075 (2005).G. H. Shi, G. E. Harlow, J. Wang, J. Wang, N. G. Enoch, X. Wang, S. M. Cao, W. Enyuancui, Eur. J. Mineral., 24, No. 2, 345–370 (2012).G. H. Shi, G. E. Harlow, J. Wang, J. Wang, N. G. Enoch, X. Wang, S. M. Cao, W. Enyuancui, Eur. J. Mineral., 24, No. 2, 345–370 (2012).L. Franz, J. Gemology, 34, No. 3, 210–229 (2014).L. Franz, J. Gemology, 34, No. 3, 210–229 (2014).C. Williams, B. Williams, J. Gemology, 35, No. 4, 289 (2016).C. Williams, B. Williams, J. Gemology, 35, No. 4, 289 (2016).L. T. Lai, Gems & Gemology, 50, No. 4, 311–312 (2014).L. T. Lai, Gems & Gemology, 50, No. 4, 311–312 (2014).J. Liu, R. Li, M. Xie, Z. Xu, Gems & Gemology, 16, No. 6, 47–50 (2014).J. Liu, R. Li, M. Xie, Z. Xu, Gems & Gemology, 16, No. 6, 47–50 (2014).L. T. Lai, Gems & Gemology, 51, No. 3, 342–343 (2015).L. T. Lai, Gems & Gemology, 51, No. 3, 342–343 (2015).R. Li, Z. Xu, Y. Xiong, P. W. Zhang, Y. F. Zhang, Gems & Gemology, 16, No. 5, 49–54 (2014).R. Li, Z. Xu, Y. Xiong, P. W. Zhang, Y. F. Zhang, Gems & Gemology, 16, No. 5, 49–54 (2014).B. Zheng, K. Li, Y. Zhang, Crystals, 12, No. 5, 658 (2022).B. Zheng, K. Li, Y. Zhang, Crystals, 12, No. 5, 658 (2022).S. F. McClure, C. P. Smith, Gems & Gemology, 36, No. 4, 336–359 (2000).S. F. McClure, C. P. Smith, Gems & Gemology, 36, No. 4, 336–359 (2000).T. L. Tan, T. S. Tay, B. L. Tan, W. H. Tan, J. Gemology, 28, No. 7, 392–398 (2003).T. L. Tan, T. S. Tay, B. L. Tan, W. H. Tan, J. Gemology, 28, No. 7, 392–398 (2003).L. T. Lai, Gems & Gemology, 50, No. 1, 90–91 (2014).L. T. Lai, Gems & Gemology, 50, No. 1, 90–91 (2014).C. Y. Hu, N. C. Chen, Gems & Gemology, 3, No. 2, 23–56 (2001).C. Y. Hu, N. C. Chen, Gems & Gemology, 3, No. 2, 23–56 (2001).J. T. Qiu, L. Qiu, H. X. Mu, Spectrosc. Lett., 52, No. 9, 520–532 (2019).J. T. Qiu, L. Qiu, H. X. Mu, Spectrosc. Lett., 52, No. 9, 520–532 (2019).B. Chow, C. Reyes-Aldasoro, Minerals, 12, No. 1, 60 (2022).B. Chow, C. Reyes-Aldasoro, Minerals, 12, No. 1, 60 (2022).D. Bersani, P. P. Lottici, Analyt. Bioanalyt. Chem., 397, No. 7, 2631–2646 (2010).D. Bersani, P. P. Lottici, Analyt. Bioanalyt. Chem., 397, No. 7, 2631–2646 (2010).S. Eaton-Magaña, C. M. Breeding, A. C. Palke, A. Homkrajae, Z. Sun, G. McElhenny, Minerals, 11, No. 2, 177 (2021).S. Eaton-Magaña, C. M. Breeding, A. C. Palke, A. Homkrajae, Z. Sun, G. McElhenny, Minerals, 11, No. 2, 177 (2021).D. Wei, S. Chen, Q. Liu, Appl. Spectrosc. Rev., 50, No. 5, 387–406 (2015).D. Wei, S. Chen, Q. Liu, Appl. Spectrosc. Rev., 50, No. 5, 387–406 (2015).X. Wang, J. L. Wu, X. G. Fan, Y. J. Xu, X. C. Lu, Y. Zuo, Infrared and Laser Eng., 45, No. 1, 64–69 (2016).X. Wang, J. L. Wu, X. G. Fan, Y. J. Xu, X. C. Lu, Y. Zuo, Infrared and Laser Eng., 45, No. 1, 64–69 (2016).F. Korinth, T. A. Shaik, J. Popp, C. Krafft, Analyst, 146, No. 22, 6760–6767 (2021).F. Korinth, T. A. Shaik, J. Popp, C. Krafft, Analyst, 146, No. 22, 6760–6767 (2021).K. Sowoidnich, M. Oster, K. Wimmers, M. Maiwald, B. Sumpf, J. Raman Spectrosc., 52, No. 8, 1418–1427 (2021).K. Sowoidnich, M. Oster, K. Wimmers, M. Maiwald, B. Sumpf, J. Raman Spectrosc., 52, No. 8, 1418–1427 (2021).Z. J. Tang, M. M. Zhang, T. J. Lu, L. X. Yang, X. M. Wang, F. Liu, L. Yin, Int. Gems & Jewelry Academic Conf., Beijing, 426–430 (2019).Z. J. Tang, M. M. Zhang, T. J. Lu, L. X. Yang, X. M. Wang, F. Liu, L. Yin, Int. Gems & Jewelry Academic Conf., Beijing, 426–430 (2019).S. Yu, J. Xia, Laser Technology, 45, No. 4, 511–515 (2021).S. Yu, J. Xia, Laser Technology, 45, No. 4, 511–515 (2021).A. Culka, J. Jehlička, J. Raman Spectrosc., 50, No. 2, 262–280 (2019).A. Culka, J. Jehlička, J. Raman Spectrosc., 50, No. 2, 262–280 (2019).A. Culka, J. Jehlička, Eur. Phys. J. Plus, 134, No. 4 (2019).A. Culka, J. Jehlička, Eur. Phys. J. Plus, 134, No. 4 (2019).K. Gao, G. Shi, M. Wang, G. Xie, J. Wang, X. Zhang, T. Fang, W. Lei, Y. Liu, Geoscience Frontiers, 10, No. 4, 1597–1612 (2019).K. Gao, G. Shi, M. Wang, G. Xie, J. Wang, X. Zhang, T. Fang, W. Lei, Y. Liu, Geoscience Frontiers, 10, No. 4, 1597–1612 (2019).C. E. McManus, N. J. McMillan, J. Dowe, J. Bell, Minerals, 10, No. 10, 916 (2020).C. E. McManus, N. J. McMillan, J. Dowe, J. Bell, Minerals, 10, No. 10, 916 (2020).B. Lafuente, R. T. Downs, H. X. Yang, N. Stone, In: Highlights in Mineralogical Crystallography, Eds. T. Armbruster, R. M. Danisi, Walter de Gruyter GmbH, Berlin, 1–29 (2016).B. Lafuente, R. T. Downs, H. X. Yang, N. Stone, In: Highlights in Mineralogical Crystallography, Eds. T. Armbruster, R. M. Danisi, Walter de Gruyter GmbH, Berlin, 1–29 (2016).D. Novembre, C. Pace, D. Gimeno, Mineral. Magazine, 82, No. 1, 95–110 (2018).D. Novembre, C. Pace, D. Gimeno, Mineral. Magazine, 82, No. 1, 95–110 (2018).B. E. Warren, J. Am. Ceram. Soc., 75, No. 1, 249–254 (1992).B. E. Warren, J. Am. Ceram. Soc., 75, No. 1, 249–254 (1992).R. L. Virta, B. S. Van Gosen, Fact Sheet – U. S. Geological Survey (2001).R. L. Virta, B. S. Van Gosen, Fact Sheet – U. S. Geological Survey (2001).L. Zhu, H. Y. Sohn, J. Ceram. Sci. Technol., 3, No. 4, 169–179 (2012).L. Zhu, H. Y. Sohn, J. Ceram. Sci. Technol., 3, No. 4, 169–179 (2012).G. Calas, O. Majérus, L. Galoisy, L. Cormier, Chem. Geology, 229, Nos. 1-3, 218–226 (2006).G. Calas, O. Majérus, L. Galoisy, L. Cormier, Chem. Geology, 229, Nos. 1-3, 218–226 (2006).W. Y. Zhao, Q. J. Zhang, C. Q. Peng, J. Chin. Ceram. Soc., 34, No. 9, 1137–1139 (2006).W. Y. Zhao, Q. J. Zhang, C. Q. Peng, J. Chin. Ceram. Soc., 34, No. 9, 1137–1139 (2006).M. M. Obeid, Int. J. Mater. Chem., 4, No. 4, 79–87 (2014).M. M. Obeid, Int. J. Mater. Chem., 4, No. 4, 79–87 (2014).F. Eric, E. Fritsch, M. Ostroumov, J. Mineral. Petrological Sci., 96, No. 3, 120–128 (2001).F. Eric, E. Fritsch, M. Ostroumov, J. Mineral. Petrological Sci., 96, No. 3, 120–128 (2001).H. A. Haenni, S. T. Wu, Y. Xingqiang, W. Tsai, J. Gemmology, 27, No. 5, 275–285 (2001).H. A. Haenni, S. T. Wu, Y. Xingqiang, W. Tsai, J. Gemmology, 27, No. 5, 275–285 (2001).Z. Q. Xu, H. X. Zhao, F. X. Gan, J. Chin. Ceram. Soc., 40, No. 3, 443–449 (2012).Z. Q. Xu, H. X. Zhao, F. X. Gan, J. Chin. Ceram. Soc., 40, No. 3, 443–449 (2012).L. Wang, D. M. Zhu, J. Y. Sun, A. P. Hu, F. Zhang, Gems & Gemmology, 17, No. 3, 43–47 (2015).L. Wang, D. M. Zhu, J. Y. Sun, A. P. Hu, F. Zhang, Gems & Gemmology, 17, No. 3, 43–47 (2015).L. Pilon, In: Foam Engineering: Fundamentals and Applications, 1st ed., Ed. P. Stevenson, John Wiley & Sons, Ltd., Chichester, UK, 355–409 (2012).L. Pilon, In: Foam Engineering: Fundamentals and Applications, 1st ed., Ed. P. Stevenson, John Wiley & Sons, Ltd., Chichester, UK, 355–409 (2012).P. F. Kerr, Optical Mineralogy, 3 ed., McGraw-Hill Book Co., New York, 344–382 (1959).P. F. Kerr, Optical Mineralogy, 3 ed., McGraw-Hill Book Co., New York, 344–382 (1959).Chen Fu, Wu Lihua, Zhao Enlu, Introduction to Colored Glass, 1 ed., Chemical Industry Press, Beijing, 81–167 (2009).Chen Fu, Wu Lihua, Zhao Enlu, Introduction to Colored Glass, 1 ed., Chemical Industry Press, Beijing, 81–167 (2009).U. Atikarnsakul, Gems Gemology, 54, No. 4, 230–231 (2018).U. Atikarnsakul, Gems Gemology, 54, No. 4, 230–231 (2018).J. B. Liu, Q. F. Ruan, X. Y. Li, J. F. Tong, J. Synthetic Crystal, 47, No. 11, 2350–2374 (2018).J. B. Liu, Q. F. Ruan, X. Y. Li, J. F. Tong, J. Synthetic Crystal, 47, No. 11, 2350–2374 (2018).Z. Zhou, Y. Q. Zhu, Y. F. Shan, Z. Y. Tang, Gems Gemmology, 20, No. 4, 38–45 (2018).Z. Zhou, Y. Q. Zhu, Y. F. Shan, Z. Y. Tang, Gems Gemmology, 20, No. 4, 38–45 (2018).J. Yu, W. Ye, J. C. Chen, J. Feng, X. L. Tang, M. Yang, E. D. Zu, CN201010547456.1, 6 (2013).J. Yu, W. Ye, J. C. Chen, J. Feng, X. L. Tang, M. Yang, E. D. Zu, CN201010547456.1, 6 (2013).H. M. Liu, Glass, 39, No. 6, 22–24 (2012).H. M. Liu, Glass, 39, No. 6, 22–24 (2012).Y. T. Jin, Glass Enamel., 47, No. 1, 36–43 (2019).Y. T. Jin, Glass Enamel., 47, No. 1, 36–43 (2019).X. Liu, Glass, 49, No. 4, 37–39 (2022).X. Liu, Glass, 49, No. 4, 37–39 (2022).W. O. George, J. Geology, 32, No. 5, 353–372 (1924).W. O. George, J. Geology, 32, No. 5, 353–372 (1924).B. N. Church, W. M. Johnson, Geolog. Soc. Am. Bull., 91, No. 10, 619–625 (1980).B. N. Church, W. M. Johnson, Geolog. Soc. Am. Bull., 91, No. 10, 619–625 (1980).K. Sowoidnich, H. Kronfeldt, ISRN Spectroscopy, 1–11 (2012).K. Sowoidnich, H. Kronfeldt, ISRN Spectroscopy, 1–11 (2012).K. Baert, W. Meulebroeck, A. Ceglia, H. Wouters, P. Cosyns, K. Nys, H. Thienpont, H. Terryn, H. Thienpont, W. Meulebroeck, K. Nys, D. Vanclooster, Integr. Approach. Study Historical Glass, SPIE, 8422, 54–62 (2012).K. Baert, W. Meulebroeck, A. Ceglia, H. Wouters, P. Cosyns, K. Nys, H. Thienpont, H. Terryn, H. Thienpont, W. Meulebroeck, K. Nys, D. Vanclooster, Integr. Approach. Study Historical Glass, SPIE, 8422, 54–62 (2012).

The authors declare that there are no conflicts of interest present.