zhpsЖурнал прикладной спектроскопииZhurnal Prikladnoii Spektroskopii0514-7506B. I. Stepanov Institute of Physics of the National Academy of Scienceszhps-1495Research ArticleАННОТАЦИИ АНГЛОЯЗЫЧНЫХ СТАТЕЙABSTRACTS ENGLISH-LANGUAGE ARTICLESМетоды пробоподготовки для лазерного атомно-эмиссионного анализа жидких микроэлементных Ca-Fe-Zn-комплексов для детейEvaluation of Sample Preparation Methods for the Classification of Children’s Ca-Fe-Zn Oral Liquid by LIBSXieW.XieW.

Наньчан

Nanchang

FuG.FuG.

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Nanchang

XuJ.XuJ.

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Nanchang

ZengM.ZengM.

Наньчан

Nanchang

WanQ.WanQ.

Наньчан

Nanchang

YaoX.YaoX.

Наньчан

Nanchang

YangP.YangP.

Чанчжоу

Changzhou

YaoM.YaoM.

Наньчан

Nanchang

mingyin800@126.comИнженерный колледж Сельскохозяйственного университета ЦзянсиКитайCollege of Engineering, Jiangxi Agricultural UniversityChinaКолледж профессионального образования и технологий Сельскохозяйственного университета ЦзянсиКитайCollege of Vocational Education and Technology, Jiangxi Agricultural UniversityChinaКолледж информационных технологий ЧанчжоуКитайChangzhou College of Information TechnologyChina202414022024911167167Copyright © Xie W., Fu G., Xu J., Zeng M., Wan Q., Yao X., Yang P., Yao M., 20242024Xie W., Fu G., Xu J., Zeng M., Wan Q., Yao X., Yang P., Yao M.Xie W., Fu G., Xu J., Zeng M., Wan Q., Yao X., Yang P., Yao M.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://zhps.ejournal.by/jour/article/view/1495

целью выявления на рынке контрафактных пероральных жидкостей и эффективного контроля их качества использована лазерно-искровая эмиссионная спектроскопия (LIBS) с пробоподготовкой образцов. Пробоподготовка образцов включает в себя адсорбцию на фильтровальной бумаге (FPA), в том числе с элементарной медью (Сu), добавление по каплям на предметные стекла, том числе с Cu, и приготовление геля. Зарегистрированы спектры LIBS пероральных жидкостей от восьми производителей. Модель eXtreme Gradient Boosting (XGBoost) создана для классификации пероральных жидкостей на основе пяти методов пробоподготовки с точностью 91.25, 94.17, 55.42, 91.25 и 91.29% соответственно. Метод FPA более простой, эффективный и меньше зависит от цвета образца. Добавление по каплям на предметные стекла и приготовление геля чувствительны к цветовым характеристикам образца и не подходят для прямого обнаружения прозрачных жидкостей. Показано, что пероральные жидкости можно различать путем анализа спектра LIBS в сочетании с моделью XGBoost. Подготовка образцов, как и метод FPA, может повысить точность LIBS-классификации.

Different manufacturers do not produce the same quality of children’s Ca-Fe-Zn oral liquid due to different production materials and processes. To improve the phenomenon of counterfeit and imitation oral liquid on the market and effectively monitor its quality, laser-induced breakdown spectroscopy (LIBS) fingerprinting with sample preparation methods can provide a tool for real-time and rapid detection of oral liquids. The sample preparation methods include filter paper adsorption (FPA), filter paper adsorption with elemental Cu (FPA with Cu), adding dropwise to glass slides (ADS), adding dropwise to glass slides with elemental Cu (ADS with Cu), and gel preparation (GP). This work collected LIBS spectrum of oral liquids from eight manufacturers. The model for eXtreme Gradient Boosting (XGBoost) was constructed for classifying oral liquids based on five sample preparation methods. The accuracy was 91.25, 94.17, 55.42, 91.25, and 91.29%, respectively. The results show that the FPA method is more straightforward, efficient, and less affected by the specificity of the color of the sample. Both ADS and GP are susceptible to the color characteristics of the sample and are not well suited to the direct detection of transparent liquids. This work demonstrated that oral liquids could be discriminated by analyzing LIBS spectrum combined with the XGBoost model. Additionally, sample preparation, like the simple FPA method, can improve the accuracy of LIBS classification.

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The authors declare that there are no conflicts of interest present.