zhpsЖурнал прикладной спектроскопииZhurnal Prikladnoii Spektroskopii0514-7506B. I. Stepanov Institute of Physics of the National Academy of Scienceszhps-1534Research ArticleАННОТАЦИИ АНГЛОЯЗЫЧНЫХ СТАТЕЙABSTRACTS ENGLISH-LANGUAGE ARTICLESЛюминесцентные свойства и перенос энергии от ионов Ce3+ к Yb3+ в люминофоре Sr5 (BO3)3CLuminescence Study and Energy Transfer from Ce3+ to Yb3+ in Sr5 (BO3)3Cl PhosphorTalewarR. A.TalewarR.  A.

Нагпур

Nagpur

talewarrupesh@gmail.comКолледж инженерии и менеджмента Шри РамдеобабаDepartment of Physics, Shri Ramdeobaba College of Engineering & Management202427042024912309309Copyright © Talewar R.A., 20242024Talewar R.A.Talewar R.A.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://zhps.ejournal.by/jour/article/view/1534

Новый люминофор Sr5(BO3)3Cl:Ce3+,Yb3+, который обеспечивает квантовую резку в ближнем инфракрасном диапазоне (NIR), получен с использованием традиционных методов твердофазных  реакций и исследован с помощью рентгеновской дифракции, спектроскопии фотолюминесценции и измерения затухания флуоресценции. При возбуждении Ce3+ УФ-светом с длиной волны 350 нм наблюдалось широкополосное излучение при 415 нм и интенсивное NIR-излучение при 982 нм. Полоса с максимумом 415 нм соответствует переходу 5d→4f ионов Ce3+, тогда как 982 нм приписывается характерному переходу 2F5/2→2F7/2 ионов Yb3+. Показано влияние концентрации Ce3+ на испускание излучения, установлены время затухания и эффективность переноса энергии (ηETE). В результате анализа спектров возбуждения и испускания фотолюминесценции и измерения времени затухания флуоресценции выявлен перенос энергии от ионов Ce3+ к ионам Yb3+ как процесс совместного переноса энергии (CET) с эффективностью 71.2% и суммарной теоретической квантовой эффективностью 171.2%.

A new phosphor Sr5(BO3)3Cl:Ce3+,Yb3+, which enables near-infrared (NIR) quantum cutting, was prepared using traditional solid-state reaction methods. Its properties were examined using X-ray diffraction, photoluminescence emission, excitation spectra, and measurements of fluorescence decay. Upon excitation of Ce3+ with an ultraviolent (UV) photon at 350 nm, broadband emission at 415 nm and an intense NIR emission at 982 nm were observed. Emission at 415 nm corresponds to 5d→4f transition of Ce3+ ions, whereas the NIR emission at 982 nm is ascribed to the characteristic 2F5/2→2F7/2 transition of Yb3+ ions. Thorough investigation delved into how the concentration of Ce3+ affects visible and NIR emissions, decay lifetime, and energy transfer efficiency (ηETE). Detailed analysis of photoluminescence excitation, emission spectra, and fluorescence decay measurements revealed a proficient energy transfer from Ce3+ to Yb3+ ions. This transfer was demonstrated as a cooperative energy transfer (CET) process, showcasing a CET efficiency of 71.2% and a total theoretical quantum efficiency of 171.2%.

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The authors declare that there are no conflicts of interest present.