zhpsЖурнал прикладной спектроскопииZhurnal Prikladnoii Spektroskopii0514-7506B. I. Stepanov Institute of Physics of the National Academy of Scienceszhps-1541Research ArticleАННОТАЦИИ АНГЛОЯЗЫЧНЫХ СТАТЕЙABSTRACTS ENGLISH-LANGUAGE ARTICLESХромогенные сигнальные зонды с различными донорами “N, O” для зондирования Fe3+ и визуализации клетокChromogenic Signaling Probes with Different “N, O” Donors for Fe3+ Sensing and Cell ImagingGengМ.GengM.

Чанчунь

Changchun, Jilin

ZhangC.ZhangC.

Чанчунь

Changchun, Jilin

YuL.YuL.

Чанчунь

Changchun, Jilin

WangW.WangW.

Чжэнчжоу

Zhengzhou

LiuL.LiuL.

Чжэньцзян, Цзянсу

Zhenjiang, Jiangsu

SongK.SongK. 

Changchun, Jilin

songkai@ccsfu.edu.cnЧанчуньский политехнический институтCollege of Food and Biology, Changchun PolytechnicШкола машиностроения Северо-Китайского университета водных ресурсов и электроэнергетикиSchool of Mechanical Engineering, North China University of Water Resources and Electric PowerШкола материаловедения и инженерии Университета ЦзянсуSchool of Materials Science and Engineering, Jiangsu UniversityШкола естественных наук Чанчуньского педагогического университетаSchool of Life Science, Changchun Normal University202429042024912315315Copyright © Geng М., Zhang C., Yu L., Wang W., Liu L., Song K., 20242024Geng М., Zhang C., Yu L., Wang W., Liu L., Song K.Geng M., Zhang C., Yu L., Wang W., Liu L., Song K.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://zhps.ejournal.by/jour/article/view/1541

С помощью одностадийной реакции синтезированы три новых флуоресцентных колориметрических хемосенсора (CS1, CS2 и CS3) для селективного обнаружения Fe3+ в водных средах. Для эффективной координации ионов металлов сенсоры содержат производные родамина с разными донорными атомами “N, O”. Из этих датчиков CS2 и CS3 продемонстрировали чувствительность и колориметрическое распознавание Fe3+ по различным биологически важным ионам металлов, обеспечивая хорошую селективность. Для подтверждения возможности применения датчиков в живых клетках проведена флуоресцентная визуализация.

Iron, as the most prevalent critical trace element in the human body, is crucial for many basic physiological functions and has many environmental applications. Therefore, excellent chemosensors with high sensitivity and good selectivity toward iron are highly desired. Three new fluorescent colorimetric chemosensors (CS1, CS2, and CS3) were synthesized and prepared through a one-step reaction to selectively detect Fe3+ in aqueous media. To effectively coordinate metal ions, the sensors contain rhodamine derivatives with different “N, O” donor atoms. Of these sensors, CS2 and CS3 demonstrated sensing behavior and colorimetric “off-on” sensing for Fe3+ over various biologically important metal ions, rendering good selectivity. Fluorescent imaging was performed to confirm the possibility of applying the sensors in living cells.

родаминFe3+-зондированиеколориметрический хемосенсорrhodamineFe3+-sensingcolorimetric chemosensorThis work was supported by the Jilin Province 2024 Annual Natural Special Program-Outstanding Talents (Teams) in Science and Technology Innovation and Entrepreneurship for the Middle-aged and Yong: Research and Development Team for Key Technologies in Blueberry Production.ReferencesXiang, A. Tong, P. Jin, J. Chem. Chem., 8, No. 13, 2863–2866 (2006).Xiang, A. Tong, P. Jin, J. Chem. Chem., 8, No. 13, 2863–2866 (2006).G. E. Tumarnbac, C. M. Rosencrance, C. Wolf, J. Tetrahedron, 60, 11293–11297 (2004).G. E. Tumarnbac, C. M. Rosencrance, C. Wolf, J. Tetrahedron, 60, 11293–11297 (2004).J. M. Liu, Q. Y. Zheng, J. L. Yang, C. F. Chen, Z. T. Huang, J. Tetrahedron Lett., 43, 9209–9212 (2002).J. M. Liu, Q. Y. Zheng, J. L. Yang, C. F. Chen, Z. T. Huang, J. Tetrahedron Lett., 43, 9209–9212 (2002).G. Alberti, C. Zanoni, L. R. Magnaghi, J. Chem. J. Chemosensors, 10, No. 11, 468 (2022).G. Alberti, C. Zanoni, L. R. Magnaghi, J. Chem. J. Chemosensors, 10, No. 11, 468 (2022).J. Kaur, M. Kaur, S. K. Kansal, J. Chem. Chemosphere, 311, 136832 (2023).J. Kaur, M. Kaur, S. K. Kansal, J. Chem. Chemosphere, 311, 136832 (2023).J. Mandal, K. Pal, S. G. Chowdhury, P. Karmakar, A. Panja, S. Banerjee, A. Saha, Dalton Trans., 51, 15555–15570 (2022)J. Mandal, K. Pal, S. G. Chowdhury, P. Karmakar, A. Panja, S. Banerjee, A. Saha, Dalton Trans., 51, 15555–15570 (2022)M. B. Maity, D. Talukdar, B. Dutta, G. Bairy, N. Murmu, G. Da, C. Sinha, Inorg. Chim. Acta, 545, 121276 (2023).M. B. Maity, D. Talukdar, B. Dutta, G. Bairy, N. Murmu, G. Da, C. Sinha, Inorg. Chim. Acta, 545, 121276 (2023).G. Gao, C. Hao, C. Ding, X. Zheng, L. Liu, P. Xie, F. Guo, Res. Chem. Intermed., 49, 1771–1783 (2023), doi: 10.1007/s11164-022-04920-5.G. Gao, C. Hao, C. Ding, X. Zheng, L. Liu, P. Xie, F. Guo, Res. Chem. Intermed., 49, 1771–1783 (2023), doi: 10.1007/s11164-022-04920-5.T. Gunnlaugsson, J. P. Leonard, N. S. Murray, J. Organic Lett., 6, 1557 (2004).T. Gunnlaugsson, J. P. Leonard, N. S. Murray, J. Organic Lett., 6, 1557 (2004).E. L. Que, D. W. Domaille, C. J. Chang, J. Chem. Rev., 108, 1517–1549 (2008).E. L. Que, D. W. Domaille, C. J. Chang, J. Chem. Rev., 108, 1517–1549 (2008).A. A. Ensafi, T. Khayamian, A. Benvidi, E. Mirmomtaz, J. Analyt. Chim. Acta, 561, 225–232 (2006).A. A. Ensafi, T. Khayamian, A. Benvidi, E. Mirmomtaz, J. Analyt. Chim. Acta, 561, 225–232 (2006).R. Sheng, P. Wang, Y. Gao, Y. Wu, W. Liu, J. Ma, H. Li, S. Wu, J. Organic Lett., 10, 5015–5018 (2008).R. Sheng, P. Wang, Y. Gao, Y. Wu, W. Liu, J. Ma, H. Li, S. Wu, J. Organic Lett., 10, 5015–5018 (2008).J. Tan, X.-P. Yan, J. Talanta, 76, 9 (2008).J. Tan, X.-P. Yan, J. Talanta, 76, 9 (2008).S.-P. Wu, R.-Y. Huang, K.-J. Du, J. Dalton Transact., 4735 (2009).S.-P. Wu, R.-Y. Huang, K.-J. Du, J. Dalton Transact., 4735 (2009).R. Martinez, F. Zapata, A. Caballero, A. Espinosa, A. Tarraga, P. Molina, J. Organic Lett., 8, 3235–3238 (2006).R. Martinez, F. Zapata, A. Caballero, A. Espinosa, A. Tarraga, P. Molina, J. Organic Lett., 8, 3235–3238 (2006).K. M. K. Swamy, S.-K. Ko, S. K. Kwon, H. N. Lee, C. Mao, J.-M. Kim, K.-H, Lee, J. Kim, I. Shin, J. Yoon, J. Chem. Commun., 5915 (2008).K. M. K. Swamy, S.-K. Ko, S. K. Kwon, H. N. Lee, C. Mao, J.-M. Kim, K.-H, Lee, J. Kim, I. Shin, J. Yoon, J. Chem. Commun., 5915 (2008).E. Ballesteros, D. Moreno, T. Gomez, T. Rodriguez, J. Rojo, M. Garcia-Valverde, T. Torroba, J. Organic Lett., 11, 1269–1272 (2009).E. Ballesteros, D. Moreno, T. Gomez, T. Rodriguez, J. Rojo, M. Garcia-Valverde, T. Torroba, J. Organic Lett., 11, 1269–1272 (2009).S. Senapati, R. Naik, J. Mater. Res. Bull., 111904 (2022).S. Senapati, R. Naik, J. Mater. Res. Bull., 111904 (2022).Z. Feng, J. Wu, M. Jiang, J. Chem. Electrochem., 366, 131963 (2022).Z. Feng, J. Wu, M. Jiang, J. Chem. Electrochem., 366, 131963 (2022).S. Lv, J. Zuo, S. Zhang, J. Chem. Reactive and Functional Polymers, 105354 (2022).S. Lv, J. Zuo, S. Zhang, J. Chem. Reactive and Functional Polymers, 105354 (2022).Y. Chen, K. Zhang, Y. Liu, J. Innovative Opt. Health Sci., 15, No. 05 (2022).Y. Chen, K. Zhang, Y. Liu, J. Innovative Opt. Health Sci., 15, No. 05 (2022).A. P. Silva, D. B. Fox, A. J. M. Huxley, T. S. Moody, J. Chem. Coord. Chem. Rev., 205, 41 (2000).A. P. Silva, D. B. Fox, A. J. M. Huxley, T. S. Moody, J. Chem. Coord. Chem. Rev., 205, 41 (2000).J. Tan, X.-P. Yan, J. Talanta, 76, 9 (2008).J. Tan, X.-P. Yan, J. Talanta, 76, 9 (2008).O. Sunnapu, N. G. Kotla, B. Maddiboyina, J. Chem. Chem., 6, No. 1, 656–660 (2015).O. Sunnapu, N. G. Kotla, B. Maddiboyina, J. Chem. Chem., 6, No. 1, 656–660 (2015).S. T. Hsieh, J. E. Cheeney, X. Ding, J. Chem. Chem., 132062 (2022).S. T. Hsieh, J. E. Cheeney, X. Ding, J. Chem. Chem., 132062 (2022).M. Gosi, A. C. Kumar, Y. Sunandamma, J. Biochem. Biochem., 32, No. 6, 2379–2393 (2022).M. Gosi, A. C. Kumar, Y. Sunandamma, J. Biochem. Biochem., 32, No. 6, 2379–2393 (2022).A. Y. Mironenko, M. V. Tutov, A. K. Chepak, J. Chem. Analyt., 1229, 340388 (2022).A. Y. Mironenko, M. V. Tutov, A. K. Chepak, J. Chem. Analyt., 1229, 340388 (2022).L. Wang, J. Wang, Y. Wang, J. Chem. Chem., 181, 105408 (2022).L. Wang, J. Wang, Y. Wang, J. Chem. Chem., 181, 105408 (2022).S. K. Ko, Y. K. Yang, J. Tae, I. Shin, J. Am. Chem. Soc., 128, 14150 (2006).S. K. Ko, Y. K. Yang, J. Tae, I. Shin, J. Am. Chem. Soc., 128, 14150 (2006).X.-F. Yang, P. Liu, L. Wang, M. Zhao, J. Fluoresc., 18, 453–459 (2008).X.-F. Yang, P. Liu, L. Wang, M. Zhao, J. Fluoresc., 18, 453–459 (2008).Y. K. Yang, K. J. Yook, J. Tae, J. Chem. Chem., 127, 16760–16761 (2005).Y. K. Yang, K. J. Yook, J. Tae, J. Chem. Chem., 127, 16760–16761 (2005).W. Wei, C. Xu, J. Ren, B. Xu, X. Qu, Chem. Commun., 48, 1284–1286 (2012).W. Wei, C. Xu, J. Ren, B. Xu, X. Qu, Chem. Commun., 48, 1284–1286 (2012).R. Bereczki, B. Agai, I. Bitter, L. Toke, J. Incl. Phenom. Macro., 45, 45–50 (2003).R. Bereczki, B. Agai, I. Bitter, L. Toke, J. Incl. Phenom. Macro., 45, 45–50 (2003).X. Y. Liu, D. R. Bai, S. Wang, J. Angew. Chem. Int. Ed., 45, 5475 (2006).X. Y. Liu, D. R. Bai, S. Wang, J. Angew. Chem. Int. Ed., 45, 5475 (2006).J. H. Soh, K. M. K. Swamy, S. K. Kim, S. Kim, S.-H. Lee, J. Yoon, J. Tetrahedron Lett., 48, 5966–5969 (2007).J. H. Soh, K. M. K. Swamy, S. K. Kim, S. Kim, S.-H. Lee, J. Yoon, J. Tetrahedron Lett., 48, 5966–5969 (2007).Y. Liu, R. Shen, J. Ru, X. Yao, Y. Yang, H. Liu, X. Tang, D. Bai, G. Zhang, W. Liu, RSC Adv., 6, 111754–111759 (2016), doi: 10.1039/c5ra09758d.Y. Liu, R. Shen, J. Ru, X. Yao, Y. Yang, H. Liu, X. Tang, D. Bai, G. Zhang, W. Liu, RSC Adv., 6, 111754–111759 (2016), doi: 10.1039/c5ra09758d.Y. Gao, J. Wang, M. Fu, H. Chen, M. Fang, Chin. J. Org. Chem., 37, 617–626 (2017), doi: 10.6023/cjoc201610014Y. Gao, J. Wang, M. Fu, H. Chen, M. Fang, Chin. J. Org. Chem., 37, 617–626 (2017), doi: 10.6023/cjoc201610014G. Li, J. Tang, P. Ding, Y. Ye, J. Fluoresc., 26, 155–161 (2016), doi: 10.1007/s10895-015-1696-9.G. Li, J. Tang, P. Ding, Y. Ye, J. Fluoresc., 26, 155–161 (2016), doi: 10.1007/s10895-015-1696-9.

The authors declare that there are no conflicts of interest present.