zhpsЖурнал прикладной спектроскопииZhurnal Prikladnoii Spektroskopii0514-7506B. I. Stepanov Institute of Physics of the National Academy of Scienceszhps-1579Research ArticleАННОТАЦИИ АНГЛОЯЗЫЧНЫХ СТАТЕЙABSTRACTS ENGLISH-LANGUAGE ARTICLESВысокоселективный флуоресцентный сенсор для обнаружения Al3+ на основе шиффова основания 2-гидрокси-1-нафтальдегида и 8-аминохинолинаHighly Selective Fluorescent Sensor for Detection of Al3+ Based on Schiff-Base of 2-Hydroxy-1-Naphthaldehyde and 8-Aminoquinoline and Its ApplicationsCaiS.-Q.CaiS.-Q.

Гуанси Гуйлинь

Guangxi Guilin

ZhangK.-F.ZhangK.-F.

Гуанси Гуйлинь

Guangxi Guilin

xueshengcailiao@163.comCaiX.-H.CaiX.-H.

Гуйян

Guiyang

caixh1111@163.comШкола фармацевтических наук Медицинского университета ГуйлиняSchool of Pharmaceutical Sciences, Guilin Medical UniversityШкола химического машиностроения Университета Гуйчжоу МиньцзуSchool of Chemical Engineering, Guizhou Minzu University202431052024913465465Copyright © Cai S., Zhang K., Cai X., 20242024Cai S., Zhang K., Cai X.Cai S., Zhang K., Cai X.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://zhps.ejournal.by/jour/article/view/1579

Для быстрого обнаружения Al3+ получен новый флуоресцентный зонд L “включения” на основе шиффова основания 2-гидрокси-1-нафтальдегида и 8-аминохинолина. Зонд L обладает важными свойствами: хорошей стабильностью, широким диапазоном pH, простотой проведения синтеза и возможностью эффективного высокоселективного обнаружения Al3+ в водном растворе ДМСО/H2O (7:3, об.:об.). Согласно кривой Джоба и флуоресцентным данным титрования, зонд L образует комплекс с Al3+ в соотношении 2:1, нижний предел обнаружения 3.23×10–8 моль/л. Для определения возможного режима комбинирования L с Al3+ проведено сравнение спектров ЯМР 1Н и FTIR зонда L и его комплекса с Al3+. Продемонстрирована потенциальная возможность использования зонда L в виде серии сенсорных полосок для быстрого обнаружения следов Al3+ в традиционной китайской медицине.

Aluminum is a widely distributed element and plays an indispensable role in our lives, but excessive intake of Al3+ can cause potential harm to human health. Highly selective methods for the rapid detection of Al3+ are urgently needed. Here, a novel “turn on” fluorescent probe L based on Schiff-base of 2-hydroxy-1- naphthaldehyde and 8-aminoquinoline was obtained in an excellent yield. Probe L presents significant properties such as rapid response, good stability, wide pH range, simple synthetic operation, and provides an efficient strategy for the highly selective detection of Al3+ in an aqueous solution of DMSO/H2O (7:3, v:v). According to Job's curve and fluorescence titration, probe L with Al3+ forms a 2:1 ratio of complex, and the lowest limit of detection is 3.23×10−8 mol/L. The possible combination mode for probe L with Al3+ was proposed by comparison with the changes of 1H NMR and FTIR spectra of L and its complex. In addition, the potent applicants for probe L were also investigated, and indicated that it could conveniently be made into a series of sensor strips and applied to rapidly detect trace Al3+ in traditional Chinese medicine.

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The authors declare that there are no conflicts of interest present.