zhpsЖурнал прикладной спектроскопииZhurnal Prikladnoii Spektroskopii0514-7506B. I. Stepanov Institute of Physics of the National Academy of Scienceszhps-1615Research ArticleАННОТАЦИИ АНГЛОЯЗЫЧНЫХ СТАТЕЙABSTRACTS ENGLISH-LANGUAGE ARTICLESСпектроскопические свойства и термический анализ связанных цианидным мостиком гетероядерных соединений [Cd(NH3)(μ-3-аминометилпиридин)M(μ-CN)4]n (M: Pd(II) или Pt(II))Spectroscopic and Thermal Study of the Cyanide-Bridged Heteronuclear Compounds [Cd(NH3)(μ-3-Aminomethylpyridine)M(μ-CN) 4]n (M: Pd(II) or Pt(II))KaraağaçD.KaraağaçD.

Бурса

Dursun Karaağaç, Department of Physics, Faculty of Engineering and Natural Sciences

Bursa

dursun.karaagac@btu.edu.trKürkçüoğluG. S.KürkçüoğluG. S.

Эскишехир

Güneş Süheyla Kürkçüoğlu, Department of Physics, Faculty of Sciences

Eskişehir

Технический университет БурсыBursa Technical UniversityУниверситет Эскишехир ОсмангазиEskişehir Osmangazi University202402082024914602602Copyright © Karaağaç D., Kürkçüoğlu G.S., 20242024Karaağaç D., Kürkçüoğlu G.S.Karaağaç D., Kürkçüoğlu G.S.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://zhps.ejournal.by/jour/article/view/1615

Новые гетероядерные соединения с цианидными мостиками [Cd(NH3)(μ-ampy)M(μ-CN)4]n[ampy = 3-аминометилпиридин, M: Pd(II) или Pt(II) (далее — Cd-M-ampy)] приготовлены в виде порошка и исследованы с использованием элементного анализа, колебательной (ИК-Фурье и комбинационного рассеяния) спектроскопии и термического анализа. Результаты термического анализа и колебательной спектроскопии показывают, что структурные характеристики соединения Cd-M-ampy [M: Pd(II) или Pt(II)] и синтезированного ранее Cd-Ni-ampy аналогичны друг другу. В соединениях Cd-M-ampy сфера центра иона M(II) имеет квадратно-пирамидальную геометрию, а координационная сфера иона Cd(II) — искаженную октаэдрическую геометрию. В то время как один аминный, один ампиевый и четыре цианидных лиганда координируются с ионом Cd(II), трехмерный координационный полимер образуется за счет координации этих лигандов с ионами Cd(II) и M(II). Термическая деградация соединений протекает в две стадии: деградация ampy- и аминных лигандов и высвобождение цианидных групп. 

New cyanide-bridged heteronuclear compounds, [Cd(NH3)(μ-ampy)M(μ-CN)4]n [ampy = 3-aminomethylpyridine, M: Pd(II) or Pt(II) (hereafter abbreviated as Cd-M-ampy)] have been prepared in powder form and investigated by utilizing elemental analysis, vibrational (FT-IR and Raman) spectroscopy, and thermal analysis. In our previous work, we synthesized the [Cd(NH3)(μ-ampy)Ni(μ-CN)4]n compound and determined its crystal structure. The results of thermal analysis and vibrational spectroscopic show that the structural characteristics of Cd-Ni-ampy and Cd-M-ampy [M: Pd(II) or Pt(II)] compounds are analogous to each other. In these compounds, while the sphere of the center of the M(II) ion has a square pyramidal geometry, the coordination sphere of the Cd(II) ion is identified to have a distorted octahedral geometry. While one amine, one ampy, and four cyanide ligands coordinate to the Cd(II) ion, a three-dimensional coordination polymer forms by the coordination of these ligands to the Cd(II) and M(II) ions. Thermal degradation of the compounds occurs in two steps: degradation of ampy and amine ligands and release of the cyanide groups.

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The authors declare that there are no conflicts of interest present.