zhpsЖурнал прикладной спектроскопииZhurnal Prikladnoii Spektroskopii0514-7506B. I. Stepanov Institute of Physics of the National Academy of Scienceszhps-1619Research ArticleАННОТАЦИИ АНГЛОЯЗЫЧНЫХ СТАТЕЙABSTRACTS ENGLISH-LANGUAGE ARTICLESСпектроскопические свойства наночастиц феррита марганца, допированного редкоземельным элементом Yb3+Influence of Rare Earth Yb3+ Dopant on the Spectroscopic Properties of Manganese Ferrite NanoparticlesGulatiS.GulatiS.

Дели

Sudha Gulati, Department of Physics

Delhi

sudhagulati@kalindi.du.ac.inDhingraM.DhingraM.

Дели

Mansi Dhingra, Department of Physics

Delhi

Колледж Калинди Делийского университетаKalindi College, University of DelhiКолледж Майтрейи Делийского университетаMaitreyi College, University of Delhi202402082024914606606Copyright © Gulati S., Dhingra M., 20242024Gulati S., Dhingra M.Gulati S., Dhingra M.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://zhps.ejournal.by/jour/article/view/1619

Методом соосаждения синтезированы наночастицы порошка MnFe2–xYbxO4 (x = 0, 0.025, 0.075, 0.1 и 0.2) различных размеров. Влияние легирующей добавки Yb3+ на свойства феррита марганца охарактеризовано методами рентгеновской дифракции (XRD), ИК-Фурье-спектроскопии (FT-IR), КР-спектроскопии и фотолюминесцентной (ФЛ) спектроскопии. Образцы имеют кубическую структуру с пространственной группой симметрии Fd3m, размеры 24.8–34.7 нм и плотность 5.07– 5.49 г/см3. ИК-Фурье-анализ указывает на наличие двух полос поглощения в диапазоне 400–600 см–1, которые характерны для ферритов. Полоса v2 (мода растяжения Fe-O в октаэдрической позиции) смещается в сторону меньшего волнового числа, что подтверждает заселенность октаэдрической позиции более крупными ионами Yb3+. Пики КР наблюдались при 228, 295, 405, 502 и 634 см–1 для нелегированного феррита марганца. В соответствии с КР-спектрами ионы Mn2+ занимают октаэдрические (B) позиции, замещая ионы Fe3+. Обнаружено, что редкоземельные ионы преимущественно занимают октаэдрические позиции. Смещение КР-полос преимущественно связано с большими радиусами редкоземельных ионов по сравнению с ионами Fe3+ и Mn2+, а смещение пиков указывает на присутствие Yb3+ в октаэдрической позиции. В спектре ФЛ наблюдается излучение при 560 нм с ростом интенсивности при увеличении содержания примеси Yb3+, что может быть связано с включением Yb3+ в структуру шпинели, приводящим к излучательной рекомбинации в желтой области электромагнитного спектра.

A series of MnFe2–xYbxO4 powder nanoparticles (for x = 0, 0.025, 0.075, 0.1, and 0.2) of different crystallite sizes were synthesised using the co-precipitation method. The effect of Yb3+ dopant on the properties of manganese ferrite was characterised by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), Raman measurements, and photoluminescence spectroscopy (PL). The crystallite size and density of the samples have a cubic structure with an Fd3m space group. Their sizes and densities were found to be in the range of 24.8–34.7 nm and 5.07–5.49 g/cc3. FT-IR analysis indicates the presence of two absorption bands in the range 400–600 cm–1, which is a fingerprint region of ferrites. The v2 band (Fe-O stretching mode of the octahedral site) shifts towards the lower wavenumber, which confirms the occupancy of larger-size Yb3+ ions at the octahedral site. The Raman peaks were observed at 228, 295, 405, 502, and 634 cm–1 for undoped manganese ferrite. Based on Raman observations, it has been observed that Mn2+ ions exhibit a preference for occupying octahedral (B) sites by substituting Fe3+ ions. Additionally, rare earth ions have been preferentially observed to occupy octahedral sites. The primary cause for the displacement of Raman bands was ascribed predominantly to the greater radii of rare earth ions in comparison to Fe3+ and Mn2+ ions, and the shifting of the peaks indicates the presence of Yb3+ at the octahedral site. The PL spectrum shows emission at 560 nm with a rise in intensity with an increase in dopant Yb3+, which could be because of the incorporation of Yb3+ in the spinel structure, leading to radiative recombination in the yellow region of the electromagnetic spectrum.

феррит марганцаредкоземельный элементиттербийИК-Фурье-спектроскопиякомбинационное рассеяние светафотолюминесценцияmanganese ferriterare earthYbFourier transform infrared spectroscopyRamanphotoluminescenceThe authors would like to thank CEF, Delhi University, Delhi for the XRD measurements. The authors are thankful to “University Science Instrumentation Centre (USIC), University of Delhi, Delhi” for the VSM, FESEM, FT-IR, Raman and PL measurements.ReferencesJ. Li, Y. He, W. Sun, Y. Luo, H. Cai, Y. Pan, M. Shen, J. Xia, X. Shi, Biomaterials, 35 , 3666–3677 (2014), https://doi.org/10.1016/j.biomaterials.2014.01.011.J. Li, Y. He, W. Sun, Y. Luo, H. Cai, Y. Pan, M. Shen, J. Xia, X. Shi, Biomaterials, 35 , 3666–3677 (2014), https://doi.org/10.1016/j.biomaterials.2014.01.011.A. C. C. Arantes, L. E. Silva, D. F. Wood, C. das G. Almeida, G. H. D. Tonoli, J. E. de Oliveira, J. P. da Silva, T. G. Williams, W. J. Orts, M. L. Bianchi, Carbohydrate Polymers, 207 , 100–107 (2019), https://doi.org/10.1016/j.carbpol.2018.11.081.A. C. C. Arantes, L. E. Silva, D. F. Wood, C. das G. Almeida, G. H. D. Tonoli, J. E. de Oliveira, J. P. da Silva, T. G. Williams, W. J. Orts, M. L. Bianchi, Carbohydrate Polymers, 207 , 100–107 (2019), https://doi.org/10.1016/j.carbpol.2018.11.081.T. M. Freire, L. M. U. Dutra, D. C. Queiroz, N. M. P. S. Ricardo, K. Barreto, J. C. Denardin, F. R. Wurm, C. P. Sousa, A. N. Correia, P. de Lima-Neto, P. B. A. Fechine, Carbohydrate Polymers, 151 , 760–769 (2016), https://doi.org/10.1016/j.carbpol.2016.05.095.T. M. Freire, L. M. U. Dutra, D. C. Queiroz, N. M. P. S. Ricardo, K. Barreto, J. C. Denardin, F. R. Wurm, C. P. Sousa, A. N. Correia, P. de Lima-Neto, P. B. A. Fechine, Carbohydrate Polymers, 151 , 760–769 (2016), https://doi.org/10.1016/j.carbpol.2016.05.095.N. Kostevšek, Magnetochemistry, 6 , 11 (2020), https://doi.org/10.3390/magnetochemistry6010011.N. Kostevšek, Magnetochemistry, 6 , 11 (2020), https://doi.org/10.3390/magnetochemistry6010011.S. Gul, S. B. Khan, I. U. Rehman, M. A. Khan, M. I. Khan, Front. Mater., 6 , 179 (2019), https://doi.org/10.3389/fmats.2019.00179.S. Gul, S. B. Khan, I. U. Rehman, M. A. Khan, M. I. Khan, Front. Mater., 6 , 179 (2019), https://doi.org/10.3389/fmats.2019.00179.K. Tanbir, M. P. Ghosh, R. K. Singh, M. Kar, S. Mukherjee, J. Mater. Sci.: Mater. Electron., 31 , 435–443 (2020), https://doi.org/10.1007/s10854-019-02546-9.K. Tanbir, M. P. Ghosh, R. K. Singh, M. Kar, S. Mukherjee, J. Mater. Sci.: Mater. Electron., 31 , 435–443 (2020), https://doi.org/10.1007/s10854-019-02546-9.Aakash, R. Choubey, D. Das, S. Mukherjee, J. Alloys and Compd., 668 , 33–39 (2016), https://doi.org/10.1016/j.jallcom.2016.01.198.Aakash, R. Choubey, D. Das, S. Mukherjee, J. Alloys and Compd., 668 , 33–39 (2016), https://doi.org/10.1016/j.jallcom.2016.01.198.K. S. Nalwa, A. Garg, A. Upadhyaya, Mater. Lett., 62 , 878–881 (2008).K. S. Nalwa, A. Garg, A. Upadhyaya, Mater. Lett., 62 , 878–881 (2008).S. Debnath, R. Das, J. Mol. Struct., 1199 , 127044 (2020), https://doi.org/10.1016/j.molstruc.2019.127044.S. Debnath, R. Das, J. Mol. Struct., 1199 , 127044 (2020), https://doi.org/10.1016/j.molstruc.2019.127044.C. Venkataraju, G. Sathishkumar, K. Sivakumar, J. Alloys and Compd., 498 , 203–206 (2010), https://doi.org/10.1016/j.jallcom.2010.03.160.C. Venkataraju, G. Sathishkumar, K. Sivakumar, J. Alloys and Compd., 498 , 203–206 (2010), https://doi.org/10.1016/j.jallcom.2010.03.160.J. Li, H. Yuan, G. Li, Y. Liu, J. Leng, J. Magnetism and Magnetic Mater., 322 , 3396–3400 (2010), https://doi.org/10.1016/j.jmmm.2010.06.035.J. Li, H. Yuan, G. Li, Y. Liu, J. Leng, J. Magnetism and Magnetic Mater., 322 , 3396–3400 (2010), https://doi.org/10.1016/j.jmmm.2010.06.035.J. Kwon, J.-H. Kim, S.-H. Kang, C.-J. Choi, J. A. Rajesh, K.-S. Ahn, Appl. Surf. Sci., 413 , 83–91 (2017), https://doi.org/10.1016/j.apsusc.2017.04.022.J. Kwon, J.-H. Kim, S.-H. Kang, C.-J. Choi, J. A. Rajesh, K.-S. Ahn, Appl. Surf. Sci., 413 , 83–91 (2017), https://doi.org/10.1016/j.apsusc.2017.04.022.N. Akhlaghi, G. Najafpour-Darzi, J. Ind. and Eng. Chem., 103 , 292–304 (2021), https://doi.org/10.1016/j.jiec.2021.07.043.N. Akhlaghi, G. Najafpour-Darzi, J. Ind. and Eng. Chem., 103 , 292–304 (2021), https://doi.org/10.1016/j.jiec.2021.07.043.M. Y. Rafique, L.-Q. Pan, Q. Javed, M. Z. Iqbal, H.-M. Qiu, M. H. Farooq, Z.-G. Guo, M. Tanveer, Chin. Phys. B, 22 , 107101 (2013), https://doi.org/10.1088/1674-1056/22/10/107101.M. Y. Rafique, L.-Q. Pan, Q. Javed, M. Z. Iqbal, H.-M. Qiu, M. H. Farooq, Z.-G. Guo, M. Tanveer, Chin. Phys. B, 22 , 107101 (2013), https://doi.org/10.1088/1674-1056/22/10/107101.E. A. Setiadi, Rahmat, S. Simbolon, M. Yunus, C. Kurniawan, A. P. Tetuko, S. Zelviani, Rahmaniah, P. Sebayang, J. Phys.: Conf. Ser., 979 , 012064 (2018), https://doi.org/10.1088/1742-6596/979/1/012064.E. A. Setiadi, Rahmat, S. Simbolon, M. Yunus, C. Kurniawan, A. P. Tetuko, S. Zelviani, Rahmaniah, P. Sebayang, J. Phys.: Conf. Ser., 979 , 012064 (2018), https://doi.org/10.1088/1742-6596/979/1/012064.N. Najmoddin, A. Beitollahi, H. Kavas, S. Majid Mohseni, H. Rezaie, J. Åkerman, M. S. Toprak, Ceram. Int., 40 , 3619–3625 (2014), https://doi.org/10.1016/j.ceramint.2013.09.063.N. Najmoddin, A. Beitollahi, H. Kavas, S. Majid Mohseni, H. Rezaie, J. Åkerman, M. S. Toprak, Ceram. Int., 40 , 3619–3625 (2014), https://doi.org/10.1016/j.ceramint.2013.09.063.M. H. Abdellatif, A. A. Azab, M. Salerno, Mater. Res. Bull., 97 , 260–264 (2018), https://doi.org/10.1016/j.materresbull.2017.09.012.M. H. Abdellatif, A. A. Azab, M. Salerno, Mater. Res. Bull., 97 , 260–264 (2018), https://doi.org/10.1016/j.materresbull.2017.09.012.M. M. Baig, M. A. Yousuf, M. F. Warsi, P. O. Agboola, M. Sher, I. Shakir, Ceram. Int., 45 , 18014–18022 (2019), https://doi.org/10.1016/j.ceramint.2019.06.020.M. M. Baig, M. A. Yousuf, M. F. Warsi, P. O. Agboola, M. Sher, I. Shakir, Ceram. Int., 45 , 18014–18022 (2019), https://doi.org/10.1016/j.ceramint.2019.06.020.E. Chitra Devi, I. Soibam, Mater. Today: Proc., 5 , 2157–2162 (2018), https://doi.org/10.1016/j.matpr.2017.09.213.E. Chitra Devi, I. Soibam, Mater. Today: Proc., 5 , 2157–2162 (2018), https://doi.org/10.1016/j.matpr.2017.09.213.M. N. Akhtar, A. B. Sulong, M. N. Akhtar, M. A. Khan, J. Rare Earths, 36 , 156–164 (2018), https://doi.org/10.1016/j.jre.2017.09.003.M. N. Akhtar, A. B. Sulong, M. N. Akhtar, M. A. Khan, J. Rare Earths, 36 , 156–164 (2018), https://doi.org/10.1016/j.jre.2017.09.003.J. Song, L. Wang, N. Xu, Q. Zhang, J. Rare Earths, 28 , 451–455 (2010), https://doi.org/10.1016/S1002-0721(09)60132-0.J. Song, L. Wang, N. Xu, Q. Zhang, J. Rare Earths, 28 , 451–455 (2010), https://doi.org/10.1016/S1002-0721(09)60132-0.V. Jagadeesha Angadi, B. Rudraswamy, K. Sadhana, K. Praveena, Mater. Today: Proc., 3 , 2178–2186 (2016), https://doi.org/10.1016/j.matpr.2016.04.124.V. Jagadeesha Angadi, B. Rudraswamy, K. Sadhana, K. Praveena, Mater. Today: Proc., 3 , 2178–2186 (2016), https://doi.org/10.1016/j.matpr.2016.04.124.O. N. Shebanova, P. Lazor, J. Solid State Chem., 174 , 424–430 (2003), https://doi.org/10.1016/S0022-4596(03)00294-9.O. N. Shebanova, P. Lazor, J. Solid State Chem., 174 , 424–430 (2003), https://doi.org/10.1016/S0022-4596(03)00294-9.J. N. Anker, W. P. Hall, O. Lyandres, N. C. Shah, J. Zhao, R. P. Van Duyne, Nature Mater., 7 , 442–453 (2008), https://doi.org/10.1038/nmat2162.J. N. Anker, W. P. Hall, O. Lyandres, N. C. Shah, J. Zhao, R. P. Van Duyne, Nature Mater., 7 , 442–453 (2008), https://doi.org/10.1038/nmat2162.P. R. Graves, C. Johnston, J. J. Campaniello, Mater. Res. Bull., 23 , 1651–1660 (1988), https://doi.org/10.1016/0025-5408(88)90255-3.P. R. Graves, C. Johnston, J. J. Campaniello, Mater. Res. Bull., 23 , 1651–1660 (1988), https://doi.org/10.1016/0025-5408(88)90255-3.N. Amri, J. Massoudi, K. Nouri, M. Triki, E. Dhahri, L. Bessais, RSC Adv., 11 , 13256–13268 (2021), https://doi.org/10.1039/D0RA10140K.N. Amri, J. Massoudi, K. Nouri, M. Triki, E. Dhahri, L. Bessais, RSC Adv., 11 , 13256–13268 (2021), https://doi.org/10.1039/D0RA10140K.K. Kombaiah, J. J. Vijaya, L. J. Kennedy, M. Bououdina, K. Kaviyarasu, R. J. Ramalingam, H. A. Al-Lohedan, M. A. Munusamy, J. Mater. Sci.: Mater. Electron., 28 , 10321–10329 (2017), https://doi.org/10.1007/s10854-017-6800-2.K. Kombaiah, J. J. Vijaya, L. J. Kennedy, M. Bououdina, K. Kaviyarasu, R. J. Ramalingam, H. A. Al-Lohedan, M. A. Munusamy, J. Mater. Sci.: Mater. Electron., 28 , 10321–10329 (2017), https://doi.org/10.1007/s10854-017-6800-2.S. Gulati, S. Gokhale, V. Luthra, J. Supercond. Nov. Magn. ( 2023 ), https://doi.org/10.1007/s10948-023-06534-3.S. Gulati, S. Gokhale, V. Luthra, J. Supercond. Nov. Magn. ( 2023 ), https://doi.org/10.1007/s10948-023-06534-3.F. ur Raheem, M. A. Khan, A. Majeed, A. Hussain, M. F. Warsi, M. N. Akhtar, J. Alloys and Compd., 708 , 903–910 (2017), https://doi.org/10.1016/j.jallcom.2017.03.040.F. ur Raheem, M. A. Khan, A. Majeed, A. Hussain, M. F. Warsi, M. N. Akhtar, J. Alloys and Compd., 708 , 903–910 (2017), https://doi.org/10.1016/j.jallcom.2017.03.040.N. H. Alonizan, R. Qindeel, Appl. Phys. A, 124 , 408 (2018), https://doi.org/10.1007/s00339-018-1825-9.N. H. Alonizan, R. Qindeel, Appl. Phys. A, 124 , 408 (2018), https://doi.org/10.1007/s00339-018-1825-9.Sh. Karamipour, M. S. Sadjadi, N. Farhadyar, Spectrochim. Acta A: Mol. and Biomol. Spectrosc., 148 , 146–155 (2015), https://doi.org/10.1016/j.saa.2015.03.078.Sh. Karamipour, M. S. Sadjadi, N. Farhadyar, Spectrochim. Acta A: Mol. and Biomol. Spectrosc., 148 , 146–155 (2015), https://doi.org/10.1016/j.saa.2015.03.078.A. Javed, T. Szumiata, A. Sarwar, T. Fatima, Mater. Chem. and Phys., 221 , 99–107 (2019), https://doi.org/10.1016/j.matchemphys.2018.09.042.A. Javed, T. Szumiata, A. Sarwar, T. Fatima, Mater. Chem. and Phys., 221 , 99–107 (2019), https://doi.org/10.1016/j.matchemphys.2018.09.042.M. K. Kokare, N. A. Jadhav, Y. Kumar, K. M. Jadhav, S. M. Rathod, J. Alloys and Compd., 748 , 1053–1061 (2018), https://doi.org/10.1016/j.jallcom.2018.03.168.M. K. Kokare, N. A. Jadhav, Y. Kumar, K. M. Jadhav, S. M. Rathod, J. Alloys and Compd., 748 , 1053–1061 (2018), https://doi.org/10.1016/j.jallcom.2018.03.168.S. J. Iyengar, M. Joy, C. K. Ghosh, S. Dey, R. K. Kotnala, S. Ghosh, RSC Adv., 4 , 64919–64929 (2014), https://doi.org/10.1039/C4RA11283K.S. J. Iyengar, M. Joy, C. K. Ghosh, S. Dey, R. K. Kotnala, S. Ghosh, RSC Adv., 4 , 64919–64929 (2014), https://doi.org/10.1039/C4RA11283K.D. Padalia, U. C. Johri, M. G. H. Zaidi, Mater. Chem. and Phys., 169 , 89–95 (2016), https://doi.org/10.1016/j.matchemphys.2015.11.034.D. Padalia, U. C. Johri, M. G. H. Zaidi, Mater. Chem. and Phys., 169 , 89–95 (2016), https://doi.org/10.1016/j.matchemphys.2015.11.034.S. R. S. Veloso, R. G. D. Andrade, V. Gomes, C. O. Amorim, V. S. Amaral, V. Salgueiriño, P. J. G. Coutinho, P. M. T. Ferreira, M. A. Correa-Duarte, E. M. S. Castanheira, IJMS, 23 , 14145 (2022), https://doi.org/10.3390/ijms232214145.S. R. S. Veloso, R. G. D. Andrade, V. Gomes, C. O. Amorim, V. S. Amaral, V. Salgueiriño, P. J. G. Coutinho, P. M. T. Ferreira, M. A. Correa-Duarte, E. M. S. Castanheira, IJMS, 23 , 14145 (2022), https://doi.org/10.3390/ijms232214145.A. Shandilya, R. S. Yadav, A. K. Gupta, K. Sreenivas, Mater. Chem. and Phys., 264 , 124441 (2021), https://doi.org/10.1016/j.matchemphys.2021.124441.A. Shandilya, R. S. Yadav, A. K. Gupta, K. Sreenivas, Mater. Chem. and Phys., 264 , 124441 (2021), https://doi.org/10.1016/j.matchemphys.2021.124441.D. Bouokkeze, J. Massoudi, W. Hzez, M. Smari, A. Bougoffa, K. Khirouni, E. Dhahri, L. Bessais, RSC Adv., 9 , 40940–40955 (2019), https://doi.org/10.1039/C9RA07569K.D. Bouokkeze, J. Massoudi, W. Hzez, M. Smari, A. Bougoffa, K. Khirouni, E. Dhahri, L. Bessais, RSC Adv., 9 , 40940–40955 (2019), https://doi.org/10.1039/C9RA07569K.A. Manohar, C. Krishnamoorthi, C. Pavithra, N. Thota, J. Supercond. Nov. Magn., 34 , 251–259 (2021), https://doi.org/10.1007/s10948-020-05685-x.A. Manohar, C. Krishnamoorthi, C. Pavithra, N. Thota, J. Supercond. Nov. Magn., 34 , 251–259 (2021), https://doi.org/10.1007/s10948-020-05685-x.X. Wang, L. Gong, D. Zhang, X. Fan, Y. Jin, L. Guo, Sensors and Act. B: Chem., 322 , 128615 (2020), https://doi.org/10.1016/j.snb.2020.128615.X. Wang, L. Gong, D. Zhang, X. Fan, Y. Jin, L. Guo, Sensors and Act. B: Chem., 322 , 128615 (2020), https://doi.org/10.1016/j.snb.2020.128615.V. K. Sharma, A. Alipour, Z. Soran-Erdem, Y. Kelestemur, Z. G. Aykut, H. V. Demir, ACS Appl. Mater. Interfaces, 8 , 12352–12359 (2016), https://doi.org/10.1021/acsami.6b02407.V. K. Sharma, A. Alipour, Z. Soran-Erdem, Y. Kelestemur, Z. G. Aykut, H. V. Demir, ACS Appl. Mater. Interfaces, 8 , 12352–12359 (2016), https://doi.org/10.1021/acsami.6b02407.L. Y. Zhang, G. H. Zheng, Z. X. Dai, J. Mater. Sci.: Mater. Electron., 27 , 8138–8145 (2016), https://doi.org/10.1007/s10854-016-4816-7.L. Y. Zhang, G. H. Zheng, Z. X. Dai, J. Mater. Sci.: Mater. Electron., 27 , 8138–8145 (2016), https://doi.org/10.1007/s10854-016-4816-7.

The authors declare that there are no conflicts of interest present.