zhpsЖурнал прикладной спектроскопииZhurnal Prikladnoii Spektroskopii0514-7506B. I. Stepanov Institute of Physics of the National Academy of Scienceszhps-1625Research ArticleАННОТАЦИИ АНГЛОЯЗЫЧНЫХ СТАТЕЙABSTRACTS ENGLISH-LANGUAGE ARTICLESЭкранирующие ультрафиолетовое излучение пленки на основе поливинилхлорида, модифицированные ZnO-гидроксиапатитом, стабилизированным хитозаномPVC-Based Ultraviolet Screening Films Modified by Chitosan Capped ZnO-HydroxyapatiteWangB.WangB.

Хуайнань

Bin Wang

Huainan

ZhangX.ZhangX.

Хуайнань

Xiao Zhang

Huainan

MaX.MaX.

Хуайнань

Xiangmei Ma

Huainan

wb6314005@126.comШкола химической и взрывотехнической инженерии Аньхойского университета науки и технологийSchool of Chemical and Blasting Engineering, Anhui University of Science and Technology202403082024914612612Copyright © Wang B., Zhang X., Ma X., 20242024Wang B., Zhang X., Ma X.Wang B., Zhang X., Ma X.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://zhps.ejournal.by/jour/article/view/1625

Методом полива из раствора получены пленки на основе поливинилхлорида, модифицированные ZnO-гидроксиапатитом, стабилизированным хитозаном (ZnO-Hap/CS). Полученный композит демонстрирует наилучшие характеристики УФ-экранирования, значительно снижает активность фотокаталитического разложения ZnO. Подход перспективен для получения наночастиц ZnO с превосходными характеристиками блокирования УФ-излучения и низкой активностью фотокаталитического разложения.

Exploring new material structures of low photocatalytic degradation activity for ultraviolet screening is one of the important methods for improving polyvinylchloride (PVC) performance. As an important kind of ultraviolet (UV) shielding agent material, nano zinc oxide (ZnO) has been applied extensively in many fields due to its outstanding properties. However, the severe aggregation behavior between nanoparticles (NPs) and photocatalytic activity greatly limits the application. In this work, surface modification of ZnO with hydroxyapatite and chitosan (ZnO-Hap/CS) was fabricated. Then via a solution casting technique dispersed within the PVC matrix. The results demonstrated that the obtained composite exhibited the best ultraviolet screening performance greatly decreasing the photocatalytic degradation activity of ZnO. It is expected that this approach is prospective for the large-scale preparation of nano ZnO with excellent UV-blocking performance and low photocatalytic degradation activity.

оксид цинкагидроксиапатитхитозанагент ультрафиолетового экранированияполивинилхлоридzinc oxidehydroxyapatitechitosanultraviolet screening agentpolyvinylchlorideThis work was supported by the Institute of Environmently Friendly Materials and the Department of Occupational Health at Anhui University of Science and Technology (Wuhu) (Grant No. ALW2020YF06).ReferencesK. B. Barun, S. H. Ørjan, H. Ayako, N. Tadaaki, ACS Sustain. Chem. Eng., 9, 9879–9890 (2021), https://doi.org/10.1021/acssuschemeng.1c02791.K. B. Barun, S. H. Ørjan, H. Ayako, N. Tadaaki, ACS Sustain. Chem. Eng., 9, 9879–9890 (2021), https://doi.org/10.1021/acssuschemeng.1c02791.Samira Maou, Ahmed Meghezzi, Yves Grohens, Yazid Meftah, Antoine Kervoelen, Anthony Magueresse, Ind. Crops & Products, 171, 113974–113985 (2021), https://doi.org/10.1016/j.indcrop.2021.113974.Samira Maou, Ahmed Meghezzi, Yves Grohens, Yazid Meftah, Antoine Kervoelen, Anthony Magueresse, Ind. Crops & Products, 171, 113974–113985 (2021), https://doi.org/10.1016/j.indcrop.2021.113974.Orli Weizman, A. Uziel, Joey Mead, Hanna Dodiuk, Amos Ophir, Shmeul Kenig, Polym. Adv. Technol., 33, 3411–3417 (2022), https://doi.org/10.1002/pat.5791.Orli Weizman, A. Uziel, Joey Mead, Hanna Dodiuk, Amos Ophir, Shmeul Kenig, Polym. Adv. Technol., 33, 3411–3417 (2022), https://doi.org/10.1002/pat.5791.Anname Lourens, Anzel Falch, Daniel Otto, Rehana Malgas-Enus, Inorg. Chem. Commun., 142, 109586–109598 (2022), https://doi.org/10.1016/j.inoche.2022.109586.Anname Lourens, Anzel Falch, Daniel Otto, Rehana Malgas-Enus, Inorg. Chem. Commun., 142, 109586–109598 (2022), https://doi.org/10.1016/j.inoche.2022.109586.T. Jiang, Z. Mao, Y Qi, Y. Wu, J. Zhang, Polym. Adv. Technol., 32, 4915–4925 (2021), https://doi.org/10.1002/pat.5486.T. Jiang, Z. Mao, Y Qi, Y. Wu, J. Zhang, Polym. Adv. Technol., 32, 4915–4925 (2021), https://doi.org/10.1002/pat.5486.P. Li, W. Guo, Z. Lu, J. Tian, X. Li, H. Wang, Progress in Organic Coatings, 151, 106046–116053 (2021), https://doi.org/10.1016/j.porgcoat.2020.106046.P. Li, W. Guo, Z. Lu, J. Tian, X. Li, H. Wang, Progress in Organic Coatings, 151, 106046–116053 (2021), https://doi.org/10.1016/j.porgcoat.2020.106046.M. W. Aladailah, O. L. Tashlykov, T. P. Volozheninov, D. O. Kaskov, K. S. Iuzbashieva, Rama Al-Abed, Abuzer Acikgoz, Nuri Yorulmaz, Mehmet Murat Yaşar, Walaa Al-Tamimi, Marwan Alshipli, Opt. Mater., 134, 113197–113206 (2022), https://doi.org/10.1016/j.optmat.2022.113197.M. W. Aladailah, O. L. Tashlykov, T. P. Volozheninov, D. O. Kaskov, K. S. Iuzbashieva, Rama Al-Abed, Abuzer Acikgoz, Nuri Yorulmaz, Mehmet Murat Yaşar, Walaa Al-Tamimi, Marwan Alshipli, Opt. Mater., 134, 113197–113206 (2022), https://doi.org/10.1016/j.optmat.2022.113197.Q. Yang, L. Zhao, H. Yu, Q. Min, C. Chen, D. Zhou, X. Yu, J. Qiu, B. Li, X. Xu, J. Alloys and Compounds, 784, 535–540 (2019), https://doi.org/10.1016/j.jallcom.2019.01.078.Q. Yang, L. Zhao, H. Yu, Q. Min, C. Chen, D. Zhou, X. Yu, J. Qiu, B. Li, X. Xu, J. Alloys and Compounds, 784, 535–540 (2019), https://doi.org/10.1016/j.jallcom.2019.01.078.Y. Zhang, X. Wang, Y. X. Liu, S. Y. Song, D. P. Liu, J. Mater. Chem., 22, 11971–11977 (2022), https://doi.org/10.1039/c2jm30672g.Y. Zhang, X. Wang, Y. X. Liu, S. Y. Song, D. P. Liu, J. Mater. Chem., 22, 11971–11977 (2022), https://doi.org/10.1039/c2jm30672g.X. Chen, D. Hu, Z. Zhang, W. Ma, J. Alloys and Compd., 811, 151986 (2019), https://doi.org/10.1016/j.jallcom.2019.151986.X. Chen, D. Hu, Z. Zhang, W. Ma, J. Alloys and Compd., 811, 151986 (2019), https://doi.org/10.1016/j.jallcom.2019.151986.D. M. Fernandes, A. A. W. Hechenleitner, S. M. Lima, L. H. Andrade, A. R. L. Caires, E. A. Pineda Gómez, Mater. Chem. and Phys., 128, 371–376 (2021), https://doi.org/10.1016/j.matchemphys.2011.03.002.D. M. Fernandes, A. A. W. Hechenleitner, S. M. Lima, L. H. Andrade, A. R. L. Caires, E. A. Pineda Gómez, Mater. Chem. and Phys., 128, 371–376 (2021), https://doi.org/10.1016/j.matchemphys.2011.03.002.Y. Tu, L. Zhou, Y. Z. Jin, C. Gao, Z. Z. Ye, Y. F. Yang, Q. L. Wang, J. Mater. Chem., 20, 1594–1599 (2020), https://doi.org/10.1039/b914156a.Y. Tu, L. Zhou, Y. Z. Jin, C. Gao, Z. Z. Ye, Y. F. Yang, Q. L. Wang, J. Mater. Chem., 20, 1594–1599 (2020), https://doi.org/10.1039/b914156a.H. T. Liu, X. F. Zeng, H. Zhao, J. F. Chen, Ind. Eng. Chem. Res., 51, 6753–6759 (2012), https://doi.org/10.1021/ie300425vH. T. Liu, X. F. Zeng, H. Zhao, J. F. Chen, Ind. Eng. Chem. Res., 51, 6753–6759 (2012), https://doi.org/10.1021/ie300425vM. Rashvand, Z. Ranjbar, S. Rastegar, Progress in Organic Coatings, 71, 362–368 (2011), https://doi.org/10.1016/j.porgcoat.2011.04.006.M. Rashvand, Z. Ranjbar, S. Rastegar, Progress in Organic Coatings, 71, 362–368 (2011), https://doi.org/10.1016/j.porgcoat.2011.04.006.D. Kim, K. Jeon, Y. Lee, J. Deo, K. Seo, H. Han, S. B. Khan, Progress in Organic Coatings, 74, 435–442 (2012), https://doi.org/10.1016/j.porgcoat.2012.01.007.D. Kim, K. Jeon, Y. Lee, J. Deo, K. Seo, H. Han, S. B. Khan, Progress in Organic Coatings, 74, 435–442 (2012), https://doi.org/10.1016/j.porgcoat.2012.01.007.J. Anita Lett, Suresh Sagadevan, Is Fatimah, Md Enamul Hoque, Yogeswaran Lokanathan, Estelle Léonard, Solhe F. Alshahateet, Romana Schirhagl, Won Chun Oh, Eur. Polymer J., 148, 110360–110377 (2021), https://doi.org/10.1016/j.eurpolymj.2021.110360.J. Anita Lett, Suresh Sagadevan, Is Fatimah, Md Enamul Hoque, Yogeswaran Lokanathan, Estelle Léonard, Solhe F. Alshahateet, Romana Schirhagl, Won Chun Oh, Eur. Polymer J., 148, 110360–110377 (2021), https://doi.org/10.1016/j.eurpolymj.2021.110360.J. V. Luis, P. Jordi, Encyclopedia of Materials Composites, 1, 785–803 (2021), https://doi.org/10.1016/B978-0-12-819724-0.00054-9.J. V. Luis, P. Jordi, Encyclopedia of Materials Composites, 1, 785–803 (2021), https://doi.org/10.1016/B978-0-12-819724-0.00054-9.S. P. Mondéjar, A. Kovtun, M. Epple, J. Mater. Chem., 17, 4153–4159 (2007), https://doi.org/10.1039/B708258D.S. P. Mondéjar, A. Kovtun, M. Epple, J. Mater. Chem., 17, 4153–4159 (2007), https://doi.org/10.1039/B708258D.L. Li, Y. Liu, J. Tao, M. Zhang, H. Pan, X. Xu, R. Tang, J. Phys. Chem. C, 112, 12219–12224 (2008), https://doi.org/10.1021/jp8026463.L. Li, Y. Liu, J. Tao, M. Zhang, H. Pan, X. Xu, R. Tang, J. Phys. Chem. C, 112, 12219–12224 (2008), https://doi.org/10.1021/jp8026463.H. Liu, F. Chen, P. Xi, B. Chen, L. Huang, J. Cheng, C. Shao, J. Wang, D. Bai, Z. Zeng, Imaging Appl., 115, 18538–18544 (2011), https://doi.org/10.1021/jp206843w.H. Liu, F. Chen, P. Xi, B. Chen, L. Huang, J. Cheng, C. Shao, J. Wang, D. Bai, Z. Zeng, Imaging Appl., 115, 18538–18544 (2011), https://doi.org/10.1021/jp206843w.C. Zhang, J. Yang, Z. Quan, P. Yang, C. Li, Z. Hou, J. Lin, Cryst. Growth Des., 9, 2725–2733 (2009), https://doi.org/10.1021/cg801353n.C. Zhang, J. Yang, Z. Quan, P. Yang, C. Li, Z. Hou, J. Lin, Cryst. Growth Des., 9, 2725–2733 (2009), https://doi.org/10.1021/cg801353n.Akemi Yasukawa, Junna Tamura, Colloids and Surfaces A, 609, 125705 (2021), https://doi.org/10.1016/j.colsurfa.2020.125705.Akemi Yasukawa, Junna Tamura, Colloids and Surfaces A, 609, 125705 (2021), https://doi.org/10.1016/j.colsurfa.2020.125705.X. Li, X. Duan, S. Chen, H. Chen, Mater. Lett., 327, 133034 (2022), https://doi.org/10.1016/j.matlet.2022.133034.X. Li, X. Duan, S. Chen, H. Chen, Mater. Lett., 327, 133034 (2022), https://doi.org/10.1016/j.matlet.2022.133034.X. Ma, Z. Dong, B. Wang, L. Liu, R. Ye, Turk. J. Chem., 46, 542–549 (2022), https://doi.org/10.3906/kim-2110-13X. Ma, Z. Dong, B. Wang, L. Liu, R. Ye, Turk. J. Chem., 46, 542–549 (2022), https://doi.org/10.3906/kim-2110-13B. Wang, F. Jiang, X. Ma, Z. Dong, Y. Liu, Colloid and Polymer Sci., 300, 51–57 (2022), https://doi.org/10.1007/s00396-021-04929-z.B. Wang, F. Jiang, X. Ma, Z. Dong, Y. Liu, Colloid and Polymer Sci., 300, 51–57 (2022), https://doi.org/10.1007/s00396-021-04929-z.L. Zhang, C. Gao, Z. Wang, F. Xie, Y. Chen, L. Meng, X. Tang, ACS Sustainable Chem. Eng., 11, 708–717 (2023), https://doi.org/10.1021/acssuschemeng.2c05843.L. Zhang, C. Gao, Z. Wang, F. Xie, Y. Chen, L. Meng, X. Tang, ACS Sustainable Chem. Eng., 11, 708–717 (2023), https://doi.org/10.1021/acssuschemeng.2c05843.Ali Gharieh, Amin Abdollahi, Laleh Sohrabi, Polym. Adv. Technol., 34, 646–654 (2023), https://doi.org/10.1002/pat.5917.Ali Gharieh, Amin Abdollahi, Laleh Sohrabi, Polym. Adv. Technol., 34, 646–654 (2023), https://doi.org/10.1002/pat.5917.R. Nishant, Materials Today: Proceedings. Available online 28 May, 2021. https://doi.org/10.1016/j.matpr.2021.04.274.R. Nishant, Materials Today: Proceedings. Available online 28 May, 2021. https://doi.org/10.1016/j.matpr.2021.04.274.Rosa Taurino, Corrado Sciancalepore, Luca Collini, Moreno Bondi, Federica Bondioli, Composites Part B: Eng., 149, 240–247 (2018), https://doi.org/10.1016/j.compositesb.2018.05.021.Rosa Taurino, Corrado Sciancalepore, Luca Collini, Moreno Bondi, Federica Bondioli, Composites Part B: Eng., 149, 240–247 (2018), https://doi.org/10.1016/j.compositesb.2018.05.021.Ori Geuli, Israel Lewinstein, Daniel Mandler, ACS Appl. Nano Mater., Publication Date (Web): 22 Apr. 2019, https://doi.org/10.1021/acsanm.9b00369.Ori Geuli, Israel Lewinstein, Daniel Mandler, ACS Appl. Nano Mater., Publication Date (Web): 22 Apr. 2019, https://doi.org/10.1021/acsanm.9b00369.Ariel Nenen, Miguel Maureira, Miguel Neira, Sandra L. Orellana, Cristian Covarrubias, Ignacio Moreno-Villoslada, Ceram. Int., 48, 34750–34759 (2022), https://doi.org/10.1016/j.ceramint.2022.08.064.Ariel Nenen, Miguel Maureira, Miguel Neira, Sandra L. Orellana, Cristian Covarrubias, Ignacio Moreno-Villoslada, Ceram. Int., 48, 34750–34759 (2022), https://doi.org/10.1016/j.ceramint.2022.08.064.K. Du, X. Liu, S. Li, L. Qiao, H. Ai, ACS Sustain. Chem. Eng., Publication Date (Web): 13 Aug 2018 (2018), https://doi.org/10.1021/acssuschemeng.K. Du, X. Liu, S. Li, L. Qiao, H. Ai, ACS Sustain. Chem. Eng., Publication Date (Web): 13 Aug 2018 (2018), https://doi.org/10.1021/acssuschemeng.Kashif Rasool, Gheyath K. Nasrallah, Nadin Younes, Ravi P. Pandey, P. Abdul Rasheed, Khaled A. Mahmoud, ACS Sustain. Chem. Eng., 6, 3896–3916 (2018), https://doi.org/10.1021/acssuschemeng.7b04248.Kashif Rasool, Gheyath K. Nasrallah, Nadin Younes, Ravi P. Pandey, P. Abdul Rasheed, Khaled A. Mahmoud, ACS Sustain. Chem. Eng., 6, 3896–3916 (2018), https://doi.org/10.1021/acssuschemeng.7b04248.M. A. Malimabe, B. F. Dejene, H. C. Swart, S. V. Motloung, L. F. Koao, J. Mol. Struct., 1202, 127339–127396 (2020), https://doi.org/10.1021/acssuschemeng.7b04248.M. A. Malimabe, B. F. Dejene, H. C. Swart, S. V. Motloung, L. F. Koao, J. Mol. Struct., 1202, 127339–127396 (2020), https://doi.org/10.1021/acssuschemeng.7b04248.W Li, J Liu, B Liang, Y Shu, J. Wang, Composites Part B, 204, 108492(1–8) (2021), https://doi.org/10.1016/j.compositesb.2020.108492.W Li, J Liu, B Liang, Y Shu, J. Wang, Composites Part B, 204, 108492(1–8) (2021), https://doi.org/10.1016/j.compositesb.2020.108492.Y. Cao, P. Xu, P. Lv, P. J. Lemstra, X. Cai, W. Yang, W. Dong, M. Chen, T. Liu, M. Du, P. Ma, ACS Appl. Mater. Interfaces, 12, 49090–49100 (2020), https://doi.org/10.1021/acsami.0c1442.Y. Cao, P. Xu, P. Lv, P. J. Lemstra, X. Cai, W. Yang, W. Dong, M. Chen, T. Liu, M. Du, P. Ma, ACS Appl. Mater. Interfaces, 12, 49090–49100 (2020), https://doi.org/10.1021/acsami.0c1442.Y. Wang, T. Li, P. Ma, H. Bai, M. Chen, Y. Xie, W. Dong, ACS Sustain. Chem. Eng., 4, 2252–2258 (2016), https://doi.org/10.1021/acssuschemeng.5b01734.Y. Wang, T. Li, P. Ma, H. Bai, M. Chen, Y. Xie, W. Dong, ACS Sustain. Chem. Eng., 4, 2252–2258 (2016), https://doi.org/10.1021/acssuschemeng.5b01734.Antonio Greco, Francesca Ferrari, Alfonso Maffezzoli, J. Cleaner Prod., 164, 757–764 (2017), https://doi.org/10.1016/j.jclepro.2017.07.009.Antonio Greco, Francesca Ferrari, Alfonso Maffezzoli, J. Cleaner Prod., 164, 757–764 (2017), https://doi.org/10.1016/j.jclepro.2017.07.009.

The authors declare that there are no conflicts of interest present.