zhpsЖурнал прикладной спектроскопииZhurnal Prikladnoii Spektroskopii0514-7506B. I. Stepanov Institute of Physics of the National Academy of Scienceszhps-1628Research ArticleАННОТАЦИИ АНГЛОЯЗЫЧНЫХ СТАТЕЙABSTRACTS ENGLISH-LANGUAGE ARTICLESКомпозитный катализатор α-nBACoPc/SnO2 синергетической фотокаталитической деградации красителейA New Type of Composite Catalyst α-nBACoPc/SnO2 Synergistic Photo-Catalytic Degradation of DyesYinY.YinY.

Цицикар, Хэйлунцзян

Yanbing Yin 

Qiqihar, Heilongjiang

ybyin@qqhru.edu.cnJiangB.JiangB.

Цицикар, Хэйлунцзян

Bei Jiang

Qiqihar, Heilongjiang

XuG.XuG.

Цицикар, Хэйлунцзян

Guopeng Xu

Qiqihar, Heilongjiang

LiuY.LiuY.

Цицикар, Хэйлунцзян

Yang Liu

Qiqihar, Heilongjiang

WangZ.WangZ.

Цицикар, Хэйлунцзян

Zhou Wang

Qiqihar, Heilongjiang

FengY.FengY.

Цицикар, Хэйлунцзян

Yongming Feng

Qiqihar, Heilongjiang

SunX.SunX.

Цицикар, Хэйлунцзян

Xinyu Sun

Qiqihar, Heilongjiang

Технологический инновационный центр регулирования государственного рынкаTechnology Innovation Center of Industrial Hemp for State Market Regulation202403082024914615615Copyright © Yin Y., Jiang B., Xu G., Liu Y., Wang Z., Feng Y., Sun X., 20242024Yin Y., Jiang B., Xu G., Liu Y., Wang Z., Feng Y., Sun X.Yin Y., Jiang B., Xu G., Liu Y., Wang Z., Feng Y., Sun X.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://zhps.ejournal.by/jour/article/view/1628

Композиты α-nBACoPc/SnO2 синтезированы in situ и охарактеризованы с помощью ИК-Фурье-спектроскопии (FT-IR), рентгеновской дифракции (XRD), рентгеновской фотоэлектронной спектроскопии (XPS) и подтверждены нагрузкой аминофталоцианина кобальта на SnO2. Для экспериментов по фотокаталитическому разложению в качестве моделируемого загрязнителя использован родамин Б. Композит показал высокую скорость фотокаталитической деградации (83.3%) по сравнению с α-nBACoPc и SnO2 в отдельности. Связь Co-O в композиционном материале усиливает перенос электронов от фталоцианина в зону проводимости SnO2, улучшая утилизацию света и усиливая синергетическое действие фталоцианина кобальта и SnO2. Композиты продемонстрировали хорошую стабильность и пригодность к вторичной переработке.

The α-nBACoPc/SnO2 composites were prepared using the in situ synthesis method and characterized by Fourier transform infrared (FT-IR), X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and confirmed by the loading of amino cobalt phthalocyanine on SnO2. Conduct photocatalytic degradation experiments used rhodamine B as a simulated pollutant. The composite exhibited a photo-catalytic degradation rate of 83.3%, which was higher than that of α-nBACoPc and SnO2 alone. The Co-O bond in the composite material enhances the transfer of electrons from phthalocyanine to the SnO2 conduction band, improving light utilization and strengthening the synergistic impact of cobalt phthalocyanine and SnO2. Furthermore, the composites demonstrated good stability and recyclability.

аминофталоцианинSnO2композиционный материалфотокаталитическая деградацияродамин Бamino-phthalocyanineSnO2composite materialphoto-catalytic degradationrhodamine BThis work was supported by the Natural Science Foundation of Heilongjiang Province of China (Grant No. LH2019B020) and the Research Foundation of Education Bureau of Heilongjiang Province of China (Grant No. 145109202). Qiqihar University Innovation and Entrepreneurship Training Program (Grant No. 202220232213).ReferencesV. S. Suvith, V. S. Devu, D. Philip, Ceram. Int., 46, No. 1, 786–794 (2020), https://doi.org/10.1016/j.ceramint.2019.09.033.V. S. Suvith, V. S. Devu, D. Philip, Ceram. Int., 46, No. 1, 786–794 (2020), https://doi.org/10.1016/j.ceramint.2019.09.033.S. A. Aladejare, Res. Policy, 78, 102909 (2022), https://doi.org/10.1016/j.resourpol.2022.102909.S. A. Aladejare, Res. Policy, 78, 102909 (2022), https://doi.org/10.1016/j.resourpol.2022.102909.Y. Fu, J. Li, Nanomaterials, 9, No. 3, 359 (2019), https://doi.org/10.3390/nano9030359.Y. Fu, J. Li, Nanomaterials, 9, No. 3, 359 (2019), https://doi.org/10.3390/nano9030359.M. Y. Xie, K. Y. Su, X. Y. Peng, et al., J. Taiwan Institute of Chemical Engineers, 70, 161–167 (2017), https://doi.org/10.1016/j.jtice.2016.10.034.M. Y. Xie, K. Y. Su, X. Y. Peng, et al., J. Taiwan Institute of Chemical Engineers, 70, 161–167 (2017), https://doi.org/10.1016/j.jtice.2016.10.034.T. Montini, M. Melchionna, M. Monai, P. Fornasiero, Chem. Rev., 116, 5987–6041 (2016), https://doi.org/10.1021/acs.chemrev.5b00603.T. Montini, M. Melchionna, M. Monai, P. Fornasiero, Chem. Rev., 116, 5987–6041 (2016), https://doi.org/10.1021/acs.chemrev.5b00603.J. Li, N. Wu, Catal. Sci. Technol., 5, 1360–1384 (2015), https://doi.org/10.1039/C4CY00974F.J. Li, N. Wu, Catal. Sci. Technol., 5, 1360–1384 (2015), https://doi.org/10.1039/C4CY00974F.S.-M. Lam, J.-C. Sin, A. R. Mohamed, Mater. Sci. Semicond. Process, 47, 62–84 (2016), https://doi.org/10.1016/j.mssp.2016.02.019.S.-M. Lam, J.-C. Sin, A. R. Mohamed, Mater. Sci. Semicond. Process, 47, 62–84 (2016), https://doi.org/10.1016/j.mssp.2016.02.019.W. Jin, H. Wang, Y. Liu, S. Yang, J. Zhou, W. Chen, ACS Appl. Nano Mater., 5, 10485–10494 (2022), https://doi.org/10.1021/acsanm.2c01819.W. Jin, H. Wang, Y. Liu, S. Yang, J. Zhou, W. Chen, ACS Appl. Nano Mater., 5, 10485–10494 (2022), https://doi.org/10.1021/acsanm.2c01819.T. A. Dontsova, A. S. Kutuzova, K. O. Bila, et al., J. Nanomaterials, 8349480 (2020), https://doi.org/10.1155/2020/8349480.T. A. Dontsova, A. S. Kutuzova, K. O. Bila, et al., J. Nanomaterials, 8349480 (2020), https://doi.org/10.1155/2020/8349480.M. Parthibavarman, K. Vallalperuman, S. Sathishkumar, et al., J. Mater. Sci.: Mater. Electron., 25, No. 2, 730–735 (2014), https://doi.org/10.1007/s10854-013-1637-9.M. Parthibavarman, K. Vallalperuman, S. Sathishkumar, et al., J. Mater. Sci.: Mater. Electron., 25, No. 2, 730–735 (2014), https://doi.org/10.1007/s10854-013-1637-9.A. E. Shalan, I. Osama, M. M. Rashad, et al., J. Mater. Sci.: Mater. Electron., 25, No. 1, 303–310 (2014), https://doi.org/10.1007/s10854-013-1586-3.A. E. Shalan, I. Osama, M. M. Rashad, et al., J. Mater. Sci.: Mater. Electron., 25, No. 1, 303–310 (2014), https://doi.org/10.1007/s10854-013-1586-3.G. Mendoza-Damián, F. Tzompantzi, R. Pérez-Hernández, et al., Catalysis Today, 266, 82–89 (2016). https://doi.org/10.1016/j.cattod.2015.11.029.G. Mendoza-Damián, F. Tzompantzi, R. Pérez-Hernández, et al., Catalysis Today, 266, 82–89 (2016). https://doi.org/10.1016/j.cattod.2015.11.029.S. A. Ansari, M. M. Khan, M. O. Ansari, et al., New J. Chem., 38, No. 6, 2462–2469 (2014), https://doi.org/10.1039/C3NJ01488F.S. A. Ansari, M. M. Khan, M. O. Ansari, et al., New J. Chem., 38, No. 6, 2462–2469 (2014), https://doi.org/10.1039/C3NJ01488F.Z. He, J. Zhou, Mod. Res. Catalysis, 2, 13–18 (2013), http://dx.doi.org/10.4236/mrc.2013.23A003.Z. He, J. Zhou, Mod. Res. Catalysis, 2, 13–18 (2013), http://dx.doi.org/10.4236/mrc.2013.23A003.A. Kar, J. Olszówka, S. Sain, et al., J. Alloys and Compd., 810, 151718 (2019).A. Kar, J. Olszówka, S. Sain, et al., J. Alloys and Compd., 810, 151718 (2019).Y. Liu, D. Pan, M. Xiong, et al., Chin. J. Catalysis, 41, No. 10, 1554–1563 (2020).Y. Liu, D. Pan, M. Xiong, et al., Chin. J. Catalysis, 41, No. 10, 1554–1563 (2020).S. Gorduk, J. Mol. Struct., 1198, 126921 (2019), https://doi.org/10.1016/j.molstruc.2019.126921.S. Gorduk, J. Mol. Struct., 1198, 126921 (2019), https://doi.org/10.1016/j.molstruc.2019.126921.M. A. Deyab, G. Mele, J. Power Sources, 443, 227264 (2019), https://doi.org/10.1016/j.jpowsour.2019.227264.M. A. Deyab, G. Mele, J. Power Sources, 443, 227264 (2019), https://doi.org/10.1016/j.jpowsour.2019.227264.X. Li, T. Zhang, Y. Chen, Y. Fu, J. Su, L. Guo, Chem. Eng. J., 382, 122783 (2019), https://doi.org/10.1016/j.cej.2019.122783.X. Li, T. Zhang, Y. Chen, Y. Fu, J. Su, L. Guo, Chem. Eng. J., 382, 122783 (2019), https://doi.org/10.1016/j.cej.2019.122783.S. Moradian, H. Dezhampanah, J. B. Ghasemi, H. Behnejad, Spectrochim. Acta A: Mol. Biomol. Spectrosc., 227, 117621 (2020), https://doi.org/10.1016/j.saa.2019.117621.S. Moradian, H. Dezhampanah, J. B. Ghasemi, H. Behnejad, Spectrochim. Acta A: Mol. Biomol. Spectrosc., 227, 117621 (2020), https://doi.org/10.1016/j.saa.2019.117621.H. Yakan, M. S. Çavuş, E. Güzel, et al., J. Mol. Struct., 1202, 127259 (2020), https://doi.org/10.1016/j.molstruc.2019.127259.H. Yakan, M. S. Çavuş, E. Güzel, et al., J. Mol. Struct., 1202, 127259 (2020), https://doi.org/10.1016/j.molstruc.2019.127259.E Boutin, M Wang, J C Lin, et al., Angew. Chem. Int. Ed., 58, No. 45, 16172–16176 (2019), https://doi.org/10.1002/anie.201909257.E Boutin, M Wang, J C Lin, et al., Angew. Chem. Int. Ed., 58, No. 45, 16172–16176 (2019), https://doi.org/10.1002/anie.201909257.M. Wang, K. Torbensen, D. Salvatore, et al., Nature Commun., 10, No. 1, 1–8 (2019), https://doi.org/10.1038/s41467-019-11542-w.M. Wang, K. Torbensen, D. Salvatore, et al., Nature Commun., 10, No. 1, 1–8 (2019), https://doi.org/10.1038/s41467-019-11542-w.E. T. Saka, E. Dügdü, Y. Ünver, J. Coord. Chem., 72, No. 5-7, 1119–1130 (2019), https://doi.org/10.1080/00958972.2019.1589461.E. T. Saka, E. Dügdü, Y. Ünver, J. Coord. Chem., 72, No. 5-7, 1119–1130 (2019), https://doi.org/10.1080/00958972.2019.1589461.L. A. Leal, W. F. da Cunha, L. A. Ribeiro Jr, et al., J. Mol. Modeling, 23, No. 5, 1–6 (2017), https://doi.org/10.1007/s00894-017-3338-4.L. A. Leal, W. F. da Cunha, L. A. Ribeiro Jr, et al., J. Mol. Modeling, 23, No. 5, 1–6 (2017), https://doi.org/10.1007/s00894-017-3338-4.B. Mecheri, A. Ficca, M. Oliveira, et al., Appl. Catalysis B: Environ., 237, No. 5, 699–707 (2018), https://doi.org/10.1016/j.apcatb.2018.06.031.B. Mecheri, A. Ficca, M. Oliveira, et al., Appl. Catalysis B: Environ., 237, No. 5, 699–707 (2018), https://doi.org/10.1016/j.apcatb.2018.06.031.H. Ahn, Y. C. Huang, C. W. Lin, et al., ACS Appl. Mater. Interfaces, 10, No. 34, 29145–29152 (2018), https://doi.org/10.1021/acsami.8b09378.H. Ahn, Y. C. Huang, C. W. Lin, et al., ACS Appl. Mater. Interfaces, 10, No. 34, 29145–29152 (2018), https://doi.org/10.1021/acsami.8b09378.A. Atxabal, M. Ribeiro, S. Parui, et al., Nature Comm., 7, No. 1, 1–7 (2016), https://doi.org/10.1038/ncomms13751.A. Atxabal, M. Ribeiro, S. Parui, et al., Nature Comm., 7, No. 1, 1–7 (2016), https://doi.org/10.1038/ncomms13751.R. Milan, G. Singh Selopal, M. Cavazzini, et al., Sci. Rep., 10, No. 1, 1–9 (2020), https://doi.org/10.1038/s41598-020-58310-1.R. Milan, G. Singh Selopal, M. Cavazzini, et al., Sci. Rep., 10, No. 1, 1–9 (2020), https://doi.org/10.1038/s41598-020-58310-1.N. K. Subbaiyan, F. D'Souza, Chem. Commun., 48, No. 30, 3641–3643 (2012), https://doi.org/10.1039/C2CC30614J.N. K. Subbaiyan, F. D'Souza, Chem. Commun., 48, No. 30, 3641–3643 (2012), https://doi.org/10.1039/C2CC30614J.H. Ghafuri, F. Mohammadi, R. Rahimi, et al., RSC Adv., 87, No. 6, 83947–83953 (2016), https://doi.org/10.1039/C6RA17712C.H. Ghafuri, F. Mohammadi, R. Rahimi, et al., RSC Adv., 87, No. 6, 83947–83953 (2016), https://doi.org/10.1039/C6RA17712C.G. Zhang, J. Ren, B. Liu, et al., Inorg. Chim. Acta, 471, 782–787 (2018), https://doi.org/10.1016/j.ica.2017.12.025.G. Zhang, J. Ren, B. Liu, et al., Inorg. Chim. Acta, 471, 782–787 (2018), https://doi.org/10.1016/j.ica.2017.12.025.Y. Yin, G. Xu, Z. Xin, et al., J. Coord. Chem., 75, No. 3-4, 535–547 (2022), https://doi.org/10.1080/00958972.2022.2058396.Y. Yin, G. Xu, Z. Xin, et al., J. Coord. Chem., 75, No. 3-4, 535–547 (2022), https://doi.org/10.1080/00958972.2022.2058396.J. Fang, H. Mao, J. Wu, et al., Appl. Surface Sci., 119, No. 3-4, 237–241 (1997), https://doi.org/10.1016/S0169-4332(97)00195-5.J. Fang, H. Mao, J. Wu, et al., Appl. Surface Sci., 119, No. 3-4, 237–241 (1997), https://doi.org/10.1016/S0169-4332(97)00195-5.H. Imahori, T. Umeyama, S. Ito, Acc. Chem. Res., 42, No. 11, 1809–1818 (2009), https://doi.org/10.1021/ar900034t.H. Imahori, T. Umeyama, S. Ito, Acc. Chem. Res., 42, No. 11, 1809–1818 (2009), https://doi.org/10.1021/ar900034t.

The authors declare that there are no conflicts of interest present.