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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">zhps</journal-id><journal-title-group><journal-title xml:lang="ru">Журнал прикладной спектроскопии</journal-title><trans-title-group xml:lang="en"><trans-title>Zhurnal Prikladnoii Spektroskopii</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">0514-7506</issn><publisher><publisher-name>B. I. Stepanov Institute of Physics of the National Academy of Sciences</publisher-name></publisher></journal-meta><article-meta><article-id custom-type="elpub" pub-id-type="custom">zhps-1854</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>СПЕКТРОСКОПИЯ ТВЕРДЫХ ТЕЛ</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>SPECTROSCOPY OF SOLIDS</subject></subj-group></article-categories><title-group><article-title>Изменение толщины и оптических постоянных тонких пленок оксида бора в процессе их нагрева на воздухе</article-title><trans-title-group xml:lang="en"><trans-title>Changes of Thickness and Optical Constants of Boron Oxide Films During Heating on Air</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Акашев</surname><given-names>Л. А.</given-names></name><name name-style="western" xml:lang="en"><surname>Akashev</surname><given-names>L. A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Екатеринбург</p></bio><bio xml:lang="en"><p>Ekaterinburg</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Попов</surname><given-names>Н. А.</given-names></name><name name-style="western" xml:lang="en"><surname>Popov</surname><given-names>N. A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Екатеринбург</p></bio><bio xml:lang="en"><p>Ekaterinburg</p></bio><email xlink:type="simple">n168@mail.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Шевченко</surname><given-names>В. Г.</given-names></name><name name-style="western" xml:lang="en"><surname>Shevchenko</surname><given-names>V. G.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Екатеринбург</p></bio><bio xml:lang="en"><p>Ekaterinburg</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Спесивцев</surname><given-names>Е. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Spesivtsev</surname><given-names>E. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Новосибиpск</p></bio><bio xml:lang="en"><p>Novosibirsk</p></bio><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Резницких</surname><given-names>О. Г.</given-names></name><name name-style="western" xml:lang="en"><surname>Reznitskih</surname><given-names>O. G.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Екатеринбург</p></bio><bio xml:lang="en"><p>Ekaterinburg</p></bio><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Институт химии твердого тела УрО РАН</institution></aff><aff xml:lang="en"><institution>Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences</institution></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="ru"><institution>Институт физики полупроводников им. А.В. Ржанова СО РАН</institution></aff><aff xml:lang="en"><institution>A.V. Rzhanov Institute of Semiconductor Physics, Siberian Branch of RAS</institution></aff></aff-alternatives><pub-date pub-type="collection"><year>2025</year></pub-date><pub-date pub-type="epub"><day>20</day><month>05</month><year>2025</year></pub-date><volume>92</volume><issue>3</issue><fpage>318</fpage><lpage>325</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Акашев Л.А., Попов Н.А., Шевченко В.Г., Спесивцев Е.В., Резницких О.Г., 2025</copyright-statement><copyright-year>2025</copyright-year><copyright-holder xml:lang="ru">Акашев Л.А., Попов Н.А., Шевченко В.Г., Спесивцев Е.В., Резницких О.Г.</copyright-holder><copyright-holder xml:lang="en">Akashev L.A., Popov N.A., Shevchenko V.G., Spesivtsev E.V., Reznitskih O.G.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://zhps.ejournal.by/jour/article/view/1854">https://zhps.ejournal.by/jour/article/view/1854</self-uri><abstract><p>Методами одноволновой и спектральной эллипсометрии исследовано изменение толщины и оптических постоянных пленок оксида бора, осажденных на подложки из сапфирового стекла, ситалла и поликристаллического массивного алюминия, непосредственно в процессе их нагрева на воздухе в интервале температур 24—700 °С. Продемонстрирована высокая гигроскопичность пленок, которая уменьшается при их предварительном отжиге. Показано, что в исследуемом температурном диапазоне происходит непрерывное уменьшение толщины пленки. В диапазоне температур до 300 °С оно обусловлено процессами дегидратации. При более высоких температурах уменьшение толщины пленки объясняется медленным испарением образующейся в пленке борной кислоты. Показано, что осаждение пленки оксида бора на поверхность алюминия не влияет на скорость его окисления.</p></abstract><trans-abstract xml:lang="en"><p>The thickness and optical constants changes of boron oxide films deposited on substrates of sapphire glass, sitall, and polycrystalline massive aluminum were studied directly during heating on air in the temperature range of 24–700°C using single-wave and spectral ellipsometry methods. The high hygroscopicity of these films was demonstrated, which decreases upon their preliminary annealing. It was shown that a continuous decrease of the film thickness occurs in the studied temperature range. In the temperature range up to 300°C, it is due to dehydration processes. At higher temperatures, the decrease in the film thickness is explained by the slow evaporation of boric acid formed in the film. It was shown that the deposition of a boron oxide film on the aluminum surface does not affect the rate of its oxidation.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>эллипсометрия</kwd><kwd>пленка оксида бора</kwd><kwd>пленка оксида алюминия</kwd><kwd>термическое испарение</kwd><kwd>дегидратация</kwd></kwd-group><kwd-group xml:lang="en"><kwd>ellipsometry</kwd><kwd>boron oxide film</kwd><kwd>aluminum oxide film</kwd><kwd>thermal evaporation</kwd><kwd>dehydration</kwd></kwd-group><funding-group><funding-statement xml:lang="ru">Работа выполнена в соответствии с гос. заданием Института химии твердого тела УрО РАН (рег. № 124020600007-8)</funding-statement></funding-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Г. В. Самсонов. Физико-химические свойства окислов. Справочник, Москва, Металлургия (1978)</mixed-citation><mixed-citation xml:lang="en">Г. В. Самсонов. 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