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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">zhps</journal-id><journal-title-group><journal-title xml:lang="ru">Журнал прикладной спектроскопии</journal-title><trans-title-group xml:lang="en"><trans-title>Zhurnal Prikladnoii Spektroskopii</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">0514-7506</issn><publisher><publisher-name>B. I. Stepanov Institute of Physics of the National Academy of Sciences</publisher-name></publisher></journal-meta><article-meta><article-id custom-type="elpub" pub-id-type="custom">zhps-2082</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>Статьи</subject></subj-group></article-categories><title-group><article-title>Влияние отжига в атмосфере атомарного кислорода на фотолюминесцентные и электрические свойства гидротермальных монокристаллов оксида цинка</article-title><trans-title-group xml:lang="en"><trans-title>Effect of Annealing in an Atomic Oxygen Atmosphere on Photoluminescent and Electrical Properties of Hydrothermal Single Crystals ZnO</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Рогозин</surname><given-names>И. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Rogozin</surname><given-names>I. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Бердянск Запорожской обл.</p></bio><bio xml:lang="en"><p>Berdyansk</p></bio><email xlink:type="simple">rivrov@yandex.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Рогозина</surname><given-names>О. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Rogozina</surname><given-names>O. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Бердянск Запорожской обл.</p></bio><bio xml:lang="en"><p>Berdyansk</p></bio><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Азовский государственный педагогический университет им. П. Д. Осипенко</institution></aff><aff xml:lang="en"><institution>P. D. Osipenko Azov State Pedagogical University</institution></aff></aff-alternatives><pub-date pub-type="collection"><year>2026</year></pub-date><pub-date pub-type="epub"><day>22</day><month>01</month><year>2026</year></pub-date><volume>93</volume><issue>1</issue><fpage>50</fpage><lpage>56</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Рогозин И.В., Рогозина О.В., 2026</copyright-statement><copyright-year>2026</copyright-year><copyright-holder xml:lang="ru">Рогозин И.В., Рогозина О.В.</copyright-holder><copyright-holder xml:lang="en">Rogozin I.V., Rogozina O.V.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://zhps.ejournal.by/jour/article/view/2082">https://zhps.ejournal.by/jour/article/view/2082</self-uri><abstract><p>Изучено влияние отжига в атмосфере атомарного кислорода на фотолюминесцентные и электрические свойства высококачественных монокристаллов оксида цинка (ZnO), выращенных гидротермальным методом. В спектре исходных образцов ZnО наблюдается серия узких линий в ультрафиолетовой области, а также длинноволновое излучение с максимумом при 510 нм. Обсуждается природа наблюдаемых полос. Измерения эффекта Холла указывают на то, что доминирующий донор в исходных образцах ZnO имеет энергию ионизации ED = 67 мэВ и концентрацию ND = 3.6 × 1018 см–3. После термической обработки в атмосфере атомарного кислорода при 600—700 °C в течение 1 ч ND уменьшается до 3.7 × 1017 см–3, тогда как ED не изменяется. Монокристалл ZnO, отожженный при 800 °C, показывает проводимость p-типа с концентрацией акцепторов NA = 2.7 × 1016 см–3.</p></abstract><trans-abstract xml:lang="en"><p>The effect of annealing in atomic oxygen atmosphere on the photoluminescence and electrical properties of high-quality ZnO single crystals grown by the hydrothermal method was studied. The spectrum of as-prepared ZnO samples exhibited a series of narrow lines in the ultraviolet region and long-wavelength emission peaking at 510 nm. The nature of the observed bands was discussed. Hall effect measurements indicated that the dominant donor in as-prepared ZnO samples had ED = 67 meV and ND = 3.6 × 1018 cm–3. After heat treatment in atomic oxygen atmosphere at 600–700°C for 1 h, ND value decreased to 3.7 × 1017 cm–3, while ED value did not change. Although, ZnO annealed at 800°C showed p-type conductivity with an acceptor concentration NA = 2.7 × 1016 cm–3.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>ZnO</kwd><kwd>фотолюминесценция</kwd><kwd>эффект Холла</kwd><kwd>собственные дефекты</kwd><kwd>донор</kwd><kwd>акцептор</kwd></kwd-group><kwd-group xml:lang="en"><kwd>ZnO</kwd><kwd>photoluminescence</kwd><kwd>Hall effect</kwd><kwd>intrinsic defects</kwd><kwd>donor</kwd><kwd>acceptor</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">D. K. Sharma, S. Shukla, K. K. Sharma, V. Kumar. Mater. Today. Proc., 49 (2020) 3028—3035, doi: 10.1016/j.matpr.2020.10.238</mixed-citation><mixed-citation xml:lang="en">D. K. Sharma, S. Shukla, K. K. Sharma, V. Kumar. Mater. Today. 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