zhpsЖурнал прикладной спектроскопииZhurnal Prikladnoii Spektroskopii0514-7506B. I. Stepanov Institute of Physics of the National Academy of Scienceszhps-2098Research ArticleАННОТАЦИИ АНГЛОЯЗЫЧНЫХ СТАТЕЙABSTRACTS ENGLISH-LANGUAGE ARTICLESКоличественное спектрофотометрическое определение витамина Н в исходных и лекарственных формах в мицеллярной средеKinetic Spectrophotometric Quantification of Vitamin H in Pristine and Drug Formulations in Micellar MediumSrivastavaA.SrivastavaAbhishek

Матхура, Уттар-Прадеш

Department of Chemistry

Mathura, U. P.

aabhichem@gla.ac.inBhattaraiA.BhattaraiAjaya

Трибхувана, Биратнагар

Department of Chemistry

M. M. A. M. C., Biratnagar

PandeyP. K.PandeyPradeep Kumar

Уннао, Уттар-Прадеш

Department of Chemistry

Unnao, Uttar Pradesh

SrivastavaN.SrivastavaNeetu

Горакхпур, Уттар-Прадеш

Department of Chemistry

Gorakhpur, U. P.

Университет GLAGLA UniversityУниверситет ТрибхуванаM. M. A. M. C., Tribhuvan UniversityЧандигархский университетChandighar UniversityУниверситет ГоракхпураD. D. U. Gorakhpur University202622012026931145145Copyright © Srivastava A., Bhattarai A., Pandey P.K., Srivastava N., 20262026Srivastava A., Bhattarai A., Pandey P.K., Srivastava N.Srivastava A., Bhattarai A., Pandey P.K., Srivastava N.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://zhps.ejournal.by/jour/article/view/2098

Разработан простой, эффективный и точный метод спектроскопии в видимой области для оценки витамина H (VIT-H) в лекарственных образцах, а также в чистом виде. Метод основан на ингибирующем влиянии VIT-H на реакцию замещения лиганда (LS), облегчаемую Hg2+, между фенилгидразином (PHZ) и [Fe(CN)6]4–. Стратегия включает в себя замену CN- на PHZ в [Fe(CN)6]4–, что приводит к образованию комплекса [Fe(CN)5 PHZ]3–. VIT-H количественно можно определить в диапазоне 0.017–1.710 мкг/мл, контролируя поглощение комплекса при 488 нм. Разработанный метод позволяет обнаружить VIT-H при концентрациях вплоть до 0.163 мкг/мл. Эксперименты по рекуперации подтвердили точность и достоверность метода количественного определения витамина Н. Предложенная методология успешно применена для оценки витамина Н в чистом виде и различных фармацевтических препаратах, продемонстрирована хорошая точность и воспроизводимость. Результаты соответствуют предписанному аналитическому протоколу. На предлагаемую методологию не влияют вспомогательные вещества, обычно используемые в лекарственных препаратах.

A simple, effective, and accurate visible-spectroscopic technique has been established to evaluate vitamin H (VIT-H) in medicinal samples as well as in its pure form. The method depends on the inhibitory influence of VIT-H on the Hg2+-facilitated ligand substitution (LS) reaction between phenylhydrazine (PHZ) and [Fe(CN)6]4–. The strategy involves substituting CN– with PHZ in [Fe(CN)6]4–, resulting in the formation of a [Fe(CN)5 PHZ]3 complex. The VIT-H can be quantified between 0.017 and 1.710 μg/mL by monitoring the absorbance of the complex at 488 nm during the process. The established method enables the detection of VIT-H at concentrations as low as 0.163 μg/mL. Recuperation experiments confirmed the precision and accuracy of the method for VIT-H quantification. The proposed methodology has been successfully employed for the assessment of VIT-H in pure samples and diverse pharmaceuticals, showcasing remarkable accuracy and precision. The results corresponded with the prescribed analytical protocol. The suggested methodology remains unaffected by the excipients typically employed in medications.

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The authors declare that there are no conflicts of interest present.