zhpsЖурнал прикладной спектроскопииZhurnal Prikladnoii Spektroskopii0514-7506B. I. Stepanov Institute of Physics of the National Academy of Scienceszhps-2171Research ArticleАННОТАЦИИ АНГЛОЯЗЫЧНЫХ СТАТЕЙABSTRACTS ENGLISH-LANGUAGE ARTICLESФлуоресцентный зонд на основе перилена с эффектом выключения для обнаружения антибиотиков тетрациклинового ряда с использованием наночастиц золотаPerylene-Based Turn-Off Fluorescent Probe for Tetracycline Antibiotics Detection with Gold NanoparticlesWuY. X.WuY. X.

Колледж экологической и химической инженерии.

Ваньчжоу

Chongqing Key Laboratory of Water Environment Evolution and Pollution Control in Three Gorges Reservoir, Three Gorges Reservoir Area Environment and Ecology of Chongqing Observation and Research Station, College of Environmental and Chemical Engineering, Chongqing Three Georges University.

Wanzhou

WangQ.WangQ.

Колледж экологической и химической инженерии.

Ваньчжоу

Chongqing Key Laboratory of Water Environment Evolution and Pollution Control in Three Gorges Reservoir, Three Gorges Reservoir Area Environment and Ecology of Chongqing Observation and Research Station, College of Environmental and Chemical Engineering, Chongqing Three Georges University.

Wanzhou

RaoT. D.RaoT. D.

Колледж экологической и химической инженерии.

Ваньчжоу

Chongqing Key Laboratory of Water Environment Evolution and Pollution Control in Three Gorges Reservoir, Three Gorges Reservoir Area Environment and Ecology of Chongqing Observation and Research Station, College of Environmental and Chemical Engineering, Chongqing Three Georges University.

Wanzhou

HuangM. Y.HuangM. Y.

Колледж экологической и химической инженерии.

Ваньчжоу

Chongqing Key Laboratory of Water Environment Evolution and Pollution Control in Three Gorges Reservoir, Three Gorges Reservoir Area Environment and Ecology of Chongqing Observation and Research Station, College of Environmental and Chemical Engineering, Chongqing Three Georges University.

Wanzhou

LiangL. J.LiangL. J.

Колледж экологической и химической инженерии.

Ваньчжоу

Chongqing Key Laboratory of Water Environment Evolution and Pollution Control in Three Gorges Reservoir, Three Gorges Reservoir Area Environment and Ecology of Chongqing Observation and Research Station, College of Environmental and Chemical Engineering, Chongqing Three Georges University.

Wanzhou

lianglijiao0326@163.comLiH. C.LiH. C.

Ваньчжоу

Wanzhou

lianglijiao0326@163.comЧунцинский университет “Три ущелья”Chongqing Three Georges UniversityСтанция экологического мониторинга окружающей средыEcological Environment Monitoring Station20263003202693229210Copyright © Wu Y.X., Wang Q., Rao T.D., Huang M.Y., Liang L.J., Li H.C., 20262026Wu Y.X., Wang Q., Rao T.D., Huang M.Y., Liang L.J., Li H.C.Wu Y.X., Wang Q., Rao T.D., Huang M.Y., Liang L.J., Li H.C.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://zhps.ejournal.by/jour/article/view/2171

Разработан флуоресцентный зонд на основе перилена с эффектом выключения для обнаружения тетрациклиновых антибиотиков (ТЦ) с использованием наночастиц золота. ТЦ непосредственно участвуют в восстановлении хлорауриновой кислоты с образованием атомов золота, которые впоследствии нуклеируются и собираются в наночастицы (ТЦ-AuNPs). Благодаря перекрытию между поглощением ТЦ-AuNPs и флуоресценцией периленового зонда (PDI) разработан метод флуоресцентного анализа с эффектом внутреннего фильтра (IFE). Максимумы флуоресценции PDI при 550 и 591 нм гасятся ТЦ-AuNPs в процессе IFE. Метод демонстрирует высокую чувствительность с пределом обнаружения 2.4 мкМ и селективность по отношению к распространенным мешающим веществам. Предлагаемый метод флуоресцентного анализа с эффектом внутреннего фильтра использован для обнаружения ТЦ в реальных образцах воды.

A perylene-based turn-off fluorescent strategy for tetracycline antibiotics (TCs) detection has been established with gold nanoparticles. TCs directly participate in the reduction of chloroauric acid to generate gold atoms, which subsequently nucleate and assemble into gold nanoparticles (TCs-AuNPs). Because of the overlap between the absorption of TCs-AuNPs and the fluorescence emission of the perylene probe (PDI), the inner filter effect (IFE)-based fluorescence turn-off assay was successfully established. Consequently, the fluorescence peaks of the PDI at 550 and 591 nm were quenched by TC-AuNPs via the IFE process. The assay method shows high sensitivity with a limit of detection of 2.4 mM, and remarkable selectivity against common interfering substances. The turn-off fluorescence sensing method is fairly simple, fast, and inexpensive, and it has also been successfully used for real water sample analysis. Consequently, a highly sensitive and selective method for the detection of TC via a fluorescent turn-off mechanism based on the IFE between the PDI probe and TC-AuNPs in aqueous media was successfully established.

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The authors declare that there are no conflicts of interest present.