zhpsЖурнал прикладной спектроскопииZhurnal Prikladnoii Spektroskopii0514-7506B. I. Stepanov Institute of Physics of the National Academy of Scienceszhps-596Research Article******СПЕКТРОФОТОМЕТРИЯ РАСТВОРА АРСЕНАЗО III В УФ-ВИДИМОМ ДИАПАЗОНЕ ДЛЯ ОПРЕДЕЛЕНИЯ КОНЦЕНТРАЦИИ САМАРИЯUV-VISIBLE SPECTROPHOTOMETRY WITH ARSENAZO III FOR THE DETERMINATION OF SAMARIUMGuoX.-M.GuoXing-Min

Пекин 100083

Beijing 100083

guoxm@ustb.edu.cnYanQ.-C.YanQi-Cao

Пекин 100083

Beijing 100083

MengX.-T.MengXiao-Ting

Пекин 100083

Beijing 100083

MaR.-X.MaRui-Xin

Пекин 100083

Beijing 100083

maruixin@ustb.edu.cnШкола металлургического и экологического машиностроения, Пекинский научно-технический университетSchool of Metallurgical and Ecological Engineering, University of Science and Technology Beijing201921032020863492(1)-492(7)Copyright © Guo X., Yan Q., Meng X., Ma R., 20202020Guo X., Yan Q., Meng X., Ma R.Guo X., Yan Q., Meng X., Ma R.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://zhps.ejournal.by/jour/article/view/596

Для определения концентрации самария используется оптическая спектрофотометрия раствора Sm с Арсеназо III. Показано, что концентрация Sm3+ в водном растворе в диапазоне 2.7×10–6 – 10.8×10–6 моль/л подчиняется закону Ламберта–Бера. Получена количественная взаимосвязь между оптической плотностью и концентрацией Ca2+ и F– в растворе с 2.7×10–6 моль/л Sm3+. Показано, что оптическая плотность раствора, содержащего 10.8×10–6 моль/л Sm3+, составляет 0.58 независимо от концентрации Ca2+ и F–.

самарийопределениеспектрофотометрия в УФ-видимом диапазонеАрсеназо IIIsamariumdeterminationUV-visible spectrophotometryArsenazo III.The authors would like to express their gratitude to the National Natural Science Foundation of China for financial support (No. 51374017, No.51774029 and U1460201).The authors would like to express their gratitude to the National Natural Science Foundation of China for financial support (No. 51374017, No.51774029 and U1460201).ReferencesZ. Q. Xue, L. Liu, Z. Liu, M. Li, D. Lee, R. J. Chen, Y. Q. Guo, A. R. Yan, Scr. Mater., 113, 226–230 (2016).Z. Q. Xue, L. Liu, Z. Liu, M. Li, D. Lee, R. J. Chen, Y. Q. Guo, A. R. Yan, Scr. Mater., 113, 226–230 (2016).W. Sun, M. G. Zhu, Y. K. Fang, Z. Y. Liu, H. S. Chen, Z. H. Guo, W. Li, J. Magn. Magn. Mater., 378, 214–216 (2015).W. Sun, M. G. Zhu, Y. K. Fang, Z. Y. Liu, H. S. Chen, Z. H. Guo, W. Li, J. Magn. Magn. Mater., 378, 214–216 (2015).M. Kuru, O. Sahin, S. Ozarslan, A. E. Ozmetin, J. Alloy. Compd., 694, 726–732 (2017).M. Kuru, O. Sahin, S. Ozarslan, A. E. Ozmetin, J. Alloy. Compd., 694, 726–732 (2017).R. K. Singh, S. V. Kamat, R. P. Mathur, J. Magn. Magn. Mater., 379, 300–304 (2015).R. K. Singh, S. V. Kamat, R. P. Mathur, J. Magn. Magn. Mater., 379, 300–304 (2015).V. I. Kushnirenko, M. V. Sopinskyy, E. G. Manoilov, V. S. Khomchenko, J. Alloy. Compd., 451, 209–211 (2008).V. I. Kushnirenko, M. V. Sopinskyy, E. G. Manoilov, V. S. Khomchenko, J. Alloy. Compd., 451, 209–211 (2008).H. Hakala, P. Liitti, K. Puukka, J. Peuralahti, K. Loman, J. Karvinen, P. Ollikka, A. Ylikoski, V. M. Mukkala, J. Hovinen, Inorg. Chem. Commun., 5, 1059–1062 (2002).H. Hakala, P. Liitti, K. Puukka, J. Peuralahti, K. Loman, J. Karvinen, P. Ollikka, A. Ylikoski, V. M. Mukkala, J. Hovinen, Inorg. Chem. Commun., 5, 1059–1062 (2002).J. D. Castillo, A. C. Yanes, S. Abe, P. F. Smet, J. Alloy. Compd., 635, 136–141 (2015).J. D. Castillo, A. C. Yanes, S. Abe, P. F. Smet, J. Alloy. Compd., 635, 136–141 (2015).T. Saito, H. Kitazima, J. Magn. Magn. Mater., 32, 2154–2157 (2011).T. Saito, H. Kitazima, J. Magn. Magn. Mater., 32, 2154–2157 (2011).G. Cordoba, C. Caravaca, J. Electroanal. Chem., 572, 145–151 (2004).G. Cordoba, C. Caravaca, J. Electroanal. Chem., 572, 145–151 (2004).T. Iida, T. Nohira, Y. Ito, Electrochim. Acta, 48, 2517–2521 (2003).T. Iida, T. Nohira, Y. Ito, Electrochim. Acta, 48, 2517–2521 (2003).T. Iida, T. Nohira, Y. Ito, Electrochim. Acta, 46, 2537–2544 (2001).T. Iida, T. Nohira, Y. Ito, Electrochim. Acta, 46, 2537–2544 (2001).T. Iida, T. Nohira, Y. Ito, Electrochim. Acta, 48, 901–906 (2003).T. Iida, T. Nohira, Y. Ito, Electrochim. Acta, 48, 901–906 (2003).L. Massot, P. Chamelot, P. Taxil, Electrochim. Acta, 50, 5510–5517 (2005).L. Massot, P. Chamelot, P. Taxil, Electrochim. Acta, 50, 5510–5517 (2005).Y. H. Liu, Y. D. Yan, M. L. Zhang, J. N. Zheng, Y. Zhao, P. Wang, T. Q. Yin, X. Y. Jing, W. Han, Electrochim. Acta, 163, D672–D681 (2016).Y. H. Liu, Y. D. Yan, M. L. Zhang, J. N. Zheng, Y. Zhao, P. Wang, T. Q. Yin, X. Y. Jing, W. Han, Electrochim. Acta, 163, D672–D681 (2016).Y. H. Liu, Y. D. Yan, M. L. Zhang, Y. Liang, J. M. Qu, P. Li, D. B. Ji, Y. Xue, X. Y. Jing, W. Han, Electrochim. Acta, 249, 278–289 (2017).Y. H. Liu, Y. D. Yan, M. L. Zhang, Y. Liang, J. M. Qu, P. Li, D. B. Ji, Y. Xue, X. Y. Jing, W. Han, Electrochim. Acta, 249, 278–289 (2017).Q. C. Yan, X. M. Guo. J. Alloy. Compd., 747, 994–1001 (2018).Q. C. Yan, X. M. Guo. J. Alloy. Compd., 747, 994–1001 (2018).X. M. Guo, Q. C. Yan, China Patent CN201610183598.1 (2016).X. M. Guo, Q. C. Yan, China Patent CN201610183598.1 (2016).Q. C. Yan, X. M. Guo, Solid State Commun., 272, 63–66 (2018).Q. C. Yan, X. M. Guo, Solid State Commun., 272, 63–66 (2018).R. Schramm, Phys. Sci. Rev., 1, 1–17 (2016).R. Schramm, Phys. Sci. Rev., 1, 1–17 (2016).L. O. Dubenskaya, G. D. Levitskaya, N. P. Poperechnaya, J. Anal. Chem., 60, 304–309 (2005).L. O. Dubenskaya, G. D. Levitskaya, N. P. Poperechnaya, J. Anal. Chem., 60, 304–309 (2005).É. Biémont, Recent Phys. Scr., 119, 55–60 (2005).É. Biémont, Recent Phys. Scr., 119, 55–60 (2005).H. Kunzendorf, H. A. Wollenberg, Nucl. Instrum. Methods, 87, 197–203 (1970).H. Kunzendorf, H. A. Wollenberg, Nucl. Instrum. Methods, 87, 197–203 (1970).E. Woznicka, M. Kopacz, M. Umbreit, J. Klos, J. Inorg. Biochem., 101, 774–782 (2007).E. Woznicka, M. Kopacz, M. Umbreit, J. Klos, J. Inorg. Biochem., 101, 774–782 (2007).N. T. Birgani, S. Elhami, J. AOAC Int., 100, 224–229 (2017).N. T. Birgani, S. Elhami, J. AOAC Int., 100, 224–229 (2017).B. Debus, M. Sliwa, H. Miyasaka, J. Abe, C. Ruckebusch, Chemometr. Intell. Lab., 128, 101–110 (2013).B. Debus, M. Sliwa, H. Miyasaka, J. Abe, C. Ruckebusch, Chemometr. Intell. Lab., 128, 101–110 (2013).T. I. Shabatina, A. V. Vlasov, E. V. Vovk, D. J. Stufkens, G. B. Sergeev, Spectrochim. Acta A, 56, 2539–2543 (2000).T. I. Shabatina, A. V. Vlasov, E. V. Vovk, D. J. Stufkens, G. B. Sergeev, Spectrochim. Acta A, 56, 2539–2543 (2000).M. B. Kime, D. Makgoale, Chem. Eng.Commun., 203, 1648–1655 (2016).M. B. Kime, D. Makgoale, Chem. Eng.Commun., 203, 1648–1655 (2016).N. H. Choi, S. K. Kwon, H. Kim, J. Electrochem. Soc., 160, A973–A979 (2013).N. H. Choi, S. K. Kwon, H. Kim, J. Electrochem. Soc., 160, A973–A979 (2013).H. Rohwer, E. Hosten, Anal. Chim. Acta, 339, 271–277 (1997).H. Rohwer, E. Hosten, Anal. Chim. Acta, 339, 271–277 (1997).H. Rohwer, N. Collier, E. Hosten, Anal. Chim. Acta, 314, 219–223 (1995).H. Rohwer, N. Collier, E. Hosten, Anal. Chim. Acta, 314, 219–223 (1995).B. Buděšínský, Collect. Czech. Chem. Commun., 28, 1858–1866 (1963).B. Buděšínský, Collect. Czech. Chem. Commun., 28, 1858–1866 (1963).N. C. Kendrick, Anal. Biochem., 76, 487–501 (1976).N. C. Kendrick, Anal. Biochem., 76, 487–501 (1976).R. Borissova, E. Mitropolitska, Talanta, 24, 49–51 (1979).R. Borissova, E. Mitropolitska, Talanta, 24, 49–51 (1979).L. F. Qiu, X. H. Kang, T. S. Wang, Sep. Sci. Technol., 11, 32–35 (1991).L. F. Qiu, X. H. Kang, T. S. Wang, Sep. Sci. Technol., 11, 32–35 (1991).M. D’Orazio, S. Tonarini, Anal. Chim. Acta, 351, 325–335 (1997).M. D’Orazio, S. Tonarini, Anal. Chim. Acta, 351, 325–335 (1997).Y. J. Dong, K. Gai, X. X. Gong, J. Chongqing Normal Un-ty (Nat. Sci. Ed.), 21, 43–45 (2004).Y. J. Dong, K. Gai, X. X. Gong, J. Chongqing Normal Un-ty (Nat. Sci. Ed.), 21, 43–45 (2004).Y. L. Shi, E. Edward, E. R. Van, J. Chem. Soc. Dalton Trans., 967–974 (1998).Y. L. Shi, E. Edward, E. R. Van, J. Chem. Soc. Dalton Trans., 967–974 (1998).K. Matharu, S. K. Mittal, S. K. A. Kumar, Spectrochim. Acta A, 145, 165–175 (2015).K. Matharu, S. K. Mittal, S. K. A. Kumar, Spectrochim. Acta A, 145, 165–175 (2015).X. Z. Yang, Hydrometallurgy China, 26, 109–112 (2007).X. Z. Yang, Hydrometallurgy China, 26, 109–112 (2007).

The authors declare that there are no conflicts of interest present.