zhpsЖурнал прикладной спектроскопииZhurnal Prikladnoii Spektroskopii0514-7506B. I. Stepanov Institute of Physics of the National Academy of Scienceszhps-713Research ArticleСтатьиФОТОДЕГРАДАЦИЯ ГИДРОХЛОРИДА БЕРБЕРИНА ПРИ ОБЛУЧЕНИИ ИСКУССТВЕННЫМ СОЛНЕЧНЫМ ИЗЛУЧЕНИЕМPHOTODEGRADATION OF BERBERINE HYDROCHLORIDE UNDER SIMULATED SUNLIGHT IRRADIATIONXuCh.XuChengbin

Шэньян 110036

Shenyang 110036

HeJ.HeJiajia

Шэньян 110036

Shenyang 110036

WangY.WangYing

Шэньян 110036

Shenyang 110036

XuZ.XuZien

Шэньян 110036

Shenyang 110036

MaX.MaXiping

Шэньян 110036

Shenyang 110036

maxiping@163.comMengX.MengXuelian

Шэньян 110036

Shenyang 110036

rubymxl@163.comШкола экологических наук Ляонинского университетаSchool of Environmental Science, Liaoning UniversityФармацевтическая школа Ляонинского университетаSchool of Pharmacy, Liaoning University202002112020875853(1)-853(7 )Copyright © Xu C., He J., Wang Y., Xu Z., Ma X., Meng X., 20202020Xu C., He J., Wang Y., Xu Z., Ma X., Meng X.Xu C., He J., Wang Y., Xu Z., Ma X., Meng X.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://zhps.ejournal.by/jour/article/view/713

Исследована фотодеградация гидрохлорида берберина (ГБ) в чистой воде под действием искусственного солнечного излучения (290–800 нм) с помощью фотодеградационной камеры. Изучено влияние времени облучения, pH и наличия матрицы (нитрат, гуминовая кислота, медь и перекись водорода). Показано, что деградация ГБ соответствует кинетике псевдопервого порядка и незначительно уменьшается с увеличением времени облучения. Скорость фотолиза ГБ в практически нейтральной среде более высокая, чем в щелочных или кислых растворах, и увеличивается в присутствии нитрата и меди. Перекись водорода и гуминовая кислота ускоряют или ингибируют деградацию ГБ в зависимости от их концентрации. Быстрая фотодеградация ГБ под действием искусственного солнечного света позволяет предположить, что фотолитическое обеззараживание может быть эффективным средством для деградации целевых антибиотиков в воде.

Berberine hydrochloride (BH) is a frequently detected antibiotic in environmental waters. The objective of this study was to investigate the photodegradation of the problematic antibiotic in pure water under simulated sunlight (290–800 nm) using a photodegradation chamber. The effects of irradiation time, pH, and the presence of the matrix (nitrate, humic acid, copper, and hydrogen peroxide) were investigated in this study. The results showed that the BH degradation follows pseudo-first-order kinetics, with the degradation of BH decreasing slightly with increasing irradiation time. The rate of BH photolysis was more efficient in the near-neutral condition than in alkaline or acidic solutions and increased in the presence of nitrate and copper. Hydrogen peroxide and humic acid accelerated or inhibited degradation of BH depending on their concentration. The rapid photodegradation of BH under simulated sunlight suggested that photolytic disinfection could also be effective for degradation of the target antibiotics in water.

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The authors declare that there are no conflicts of interest present.