zhpsЖурнал прикладной спектроскопииZhurnal Prikladnoii Spektroskopii0514-7506B. I. Stepanov Institute of Physics of the National Academy of Scienceszhps-785Research ArticleСтатьиМОРФОЛОГИЧЕСКИ НАПРАВЛЕННЫЙ НАНОСКОПИЧЕСКИЙ ПЕРЕНОС ЭНЕРГИИ В ПЛАЗМОННО-ОРГАНИЧЕСКИХ ГИБРИДАХMORPHOLOGY-DIRECTED NANOSCOPIC ENERGY TRANSFERS IN PLASMONIC-ORGANIC HYBRIDSGambhirK.GambhirK.

Нью-Дели 110012

New Delhi-110012

SharmaP.SharmaP.

Нью-Дели 110012

New Delhi-110012

sharmap2@nplindia.orgMehrotraR.MehrotraR.

Нью-Дели 110012

New Delhi-110012

Академия научных и инновационных исследований (AcSIR) Национальной физической лаборатории CSIR; Отдел физико-механической метрологии Национальной физической лаборатории CSIRAcademy of Scientific & Innovative Research (AcSIR) at CSIR-National Physical Laboratory campus; Physico Mechanical Metrology Division, CSIR-National Physical Laboratory, Dr. K.S. Krishnan Marg202129012021881171(1)-171(12)Copyright © Gambhir K., Sharma P., Mehrotra R., 20212021Gambhir K., Sharma P., Mehrotra R.Gambhir K., Sharma P., Mehrotra R.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://zhps.ejournal.by/jour/article/view/785

Реализован морфологически направляемый перенос энергии в наномасштабе между излучающим красителем эозином желтым и тремя различными наноформами золота — наносферами, наночастицами и наноцветами. Для подтверждения взаимодействия между связанными гибридными формами используется КР-спектроскопия. Установлено, что плазмонные структуры с острыми краями создают сильное локализованное электромагнитное поле, которое существенно подавляет фоновые сигналы флуоресценции аналита. Взаимосвязь между тушением флуоресценции красителя и геометрическими характеристиками наночастиц золота используется для понимания влияния передачи энергии на их усиленную нелинейность третьего порядка. Экспериментальные данные показывают взаимосвязь между эффективностью передачи энергии и увеличением нелинейно-оптических коэффициентов.

We have experimentally realized a morphology-directed nanoscale energy transfer between an emitter, Eosin yellow dye, and three distinct gold nanoshapes, namely, nanospheres, nanopebbles, and nanoflowers. Raman spectroscopy is employed to ensure mutual interaction among the couple hybrids. The results explicitly show that plasmonic structures with sharp edges produce a strong localized electromagnetic field, which substantially suppresses the background fluorescence signals of the analyte. Further, the relationship between the observed quenching of the dye fluorescence and the geometrical factors of the gold nanoshapes is used to comprehend the influence of energy transfers on their enhanced third-order nonlinearity. The experimental findings reveal a relationship between the efficiency of energy transfers and the enhancement of the observed nonlinear optical coefficients. This study may act as the basis for designing active photonic nanocomposites based on their efficient energy transfer interactions.

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The authors declare that there are no conflicts of interest present.