zhpsЖурнал прикладной спектроскопииZhurnal Prikladnoii Spektroskopii0514-7506B. I. Stepanov Institute of Physics of the National Academy of Scienceszhps-878Research ArticleАННОТАЦИИ АНГЛОЯЗЫЧНЫХ СТАТЕЙABSTRACTS ENGLISH-LANGUAGE ARTICLESИсследование термоокислительной стабильности смазочных материалов и их спектроскопический анализThermal and spectroscopic studies of the thermal-oxidation stabilities of lubricantsWangP.WangP.

Xuzhou 221004

WangY.WangY.

Сюйчжоу 221004

Xuzhou 221004

wangyuexing@163.comSunY.SunY.

Сюйчжоу 221004

Xuzhou 221004

CaoZ.CaoZ.

Сюйчжоу 221004

Xuzhou 221004

ZhuW.ZhuW.

Сюйчжоу 221004

Xuzhou 221004

WangH.WangH.

Сюйчжоу 221116

Xuzhou 221116

wanghy@jsnu.edu.cnState Key Laboratory of Intelligent Manufacturing of Advanced Construction Machinery, Jiangsu Xuzhou Construction Machinery Research Institute, Xuzhou Construction Machinery GroupChinaНаучно-исследовательский институт строительной техники ЦзянсуState Key Laboratory of Intelligent Manufacturing of Advanced Construction Machinery, Jiangsu Xuzhou Construction Machinery Research Institute, Xuzhou Construction Machinery GroupШкола химии и материаловедения Университета Цзянсу,Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, School of Chemistry & Materials Science at Jiangsu Normal University202123072021884662669Copyright © Wang P., Wang Y., Sun Y., Cao Z., Zhu W., Wang H., 20212021Wang P., Wang Y., Sun Y., Cao Z., Zhu W., Wang H.Wang P., Wang Y., Sun Y., Cao Z., Zhu W., Wang H.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://zhps.ejournal.by/jour/article/view/878

Влияние ароматических антиоксидантов 2,6-ди-трет-бутил-4-метилфенола (BHT) и дифениламина (DPA) на термоокислительную деструкцию базовых масел 150N изучено с помощью теста на окисление горячим маслом (HOOT) при температурах 100–200oC и времени в диапазоне 1–24 ч. Качественный и количественный анализ базовых масел и их фракций проведен с использованием газовой хроматографии–масс-спектрометрии (GC-MS) и спектроскопических методов (FTIR, UV-vis) для лучшего понимания их композиционных и структурных деталей. Изучены процессы окисления и выявлены структурные изменения, возникающие в результате термического окисления. Показано, что добавление антиоксидантов приводит к повышению устойчивости базовых масел к термоокислительной деградации. Смесь антиоксидантов проявляет лучшую термоокислительную стойкость, чем только фенольные или дифениламиновые антиоксиданты. 

The influence of aromatic antioxidants 2,6-di-tert-butyl-4-methylphenol (BHT) and diphenylamine (DPA) on the thermal–oxidative degradation of base oils 150N was studied by using the hot oil oxidation test (HOOT) with temperatures varying from 100 to 200o C and times ranging from 1–24 h. Qualitative as well as quantitative analyses of the base oils and their fractions were done using gas chromatography-mass spectrometry (GC-MS) and spectroscopic (FTIR, UV–visible) techniques to gain a better understanding of their compositional and structural details. Oxidization processes were also studied and structural changes resulting from thermal oxidation were identified. The results indicate that the addition of antioxidants causes an obvious enhancement in the resistance of base oils to thermal–oxidative degradation. Moreover, the mixture of antioxidants shows better thermal–oxidative resistance than the phenolic or diphenylamine antioxidants alone. 

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The authors declare that there are no conflicts of interest present.