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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">zhps</journal-id><journal-title-group><journal-title xml:lang="ru">Журнал прикладной спектроскопии</journal-title><trans-title-group xml:lang="en"><trans-title>Zhurnal Prikladnoii Spektroskopii</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">0514-7506</issn><publisher><publisher-name>B. I. Stepanov Institute of Physics of the National Academy of Sciences</publisher-name></publisher></journal-meta><article-meta><article-id custom-type="elpub" pub-id-type="custom">zhps-908</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>Статьи</subject></subj-group></article-categories><title-group><article-title>Плазмонные структуры на основе нанокомпозита гидроксиапатит/серебро для спектроскопии гигантского комбинационного рассеяния</article-title><trans-title-group xml:lang="en"><trans-title>Plasmonic Structures Based on Hydroxyapatite/Silver Nanocomposite for Surface-Enhanced Raman Spectroscopy</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Панарин</surname><given-names>А. Ю.</given-names></name><name name-style="western" xml:lang="en"><surname>Panarin</surname><given-names>A. Yu.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Минск</p></bio><bio xml:lang="en"><p>Minsk</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Абакшонок</surname><given-names>А. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Abakshonok</surname><given-names>A. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Минск</p></bio><bio xml:lang="en"><p>Minsk</p></bio><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Мойзес</surname><given-names>П.</given-names></name><name name-style="western" xml:lang="en"><surname>Mojzes</surname><given-names>P.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Прага</p></bio><bio xml:lang="en"><p>Prague</p></bio><xref ref-type="aff" rid="aff-3"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Терехов</surname><given-names>С. Н.</given-names></name><name name-style="western" xml:lang="en"><surname>Terekhov</surname><given-names>S. N.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Минск</p></bio><bio xml:lang="en"><p>Minsk</p></bio><email xlink:type="simple">s.terekhov@ifanbel.bas-net.by</email><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Институт физики НАН Беларуси</institution></aff><aff xml:lang="en"><institution>B. I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus</institution></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="ru"><institution>Институт химии новых материалов НАН Беларуси</institution></aff><aff xml:lang="en"><institution>Institute of Chemistry of New Materials of the National Academy of Sciences of Belarus</institution></aff></aff-alternatives><aff-alternatives id="aff-3"><aff xml:lang="ru"><institution>Институт физики Карлова университета в Праге</institution></aff><aff xml:lang="en"><institution>Institute of Physics at Charles University</institution></aff></aff-alternatives><pub-date pub-type="collection"><year>2021</year></pub-date><pub-date pub-type="epub"><day>10</day><month>10</month><year>2021</year></pub-date><volume>88</volume><issue>5</issue><fpage>748</fpage><lpage>754</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Панарин А.Ю., Абакшонок А.В., Мойзес П., Терехов С.Н., 2021</copyright-statement><copyright-year>2021</copyright-year><copyright-holder xml:lang="ru">Панарин А.Ю., Абакшонок А.В., Мойзес П., Терехов С.Н.</copyright-holder><copyright-holder xml:lang="en">Panarin A.Y., Abakshonok A.V., Mojzes P., Terekhov S.N.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://zhps.ejournal.by/jour/article/view/908">https://zhps.ejournal.by/jour/article/view/908</self-uri><abstract><p>С использованием глюкозы в качестве восстановителя синтезирован нанокомпозит гидроксиапатит/серебро (ГА)Ag, в котором с каждой частицей ГА связана одна наночастица серебра. Исследованы структурные и оптические свойства нанокомпозита. Оптимизирована методика формирования плазмонных пленок (ГА)Ag на поверхности стеклянных подложек. Продемонстрирована роль модификации стеклянной поверхности полиэтиленимином в формировании однородных плазмонных покрытий. Измерены спектры гигантского комбинационного рассеяния (ГКР) катионного порфирина CuTMpyP4, адсорбированного на поверхности пленки (ГА)Ag. Установлен предел детектирования CuTMpyP4 10–12 М, что сравнимо с чувствительностью известных твердотельных ГКР-активных материалов.</p></abstract><trans-abstract xml:lang="en"><p>Using glucose as a reducing agent, a hydroxyapatite-silver (HA)Ag nanocomposite is synthesized, in which one silver nanoparticle is bound to each HA particle. The structural and optical properties of the nanocomposite are investigated. The technique of formation of plasmonic films (HA)Ag on the glass substrates surface is optimized. The role of modification of a glass surface with polyethyleneimine in the formation of homogeneous plasmonic coatings is demonstrated. The surface-enhanced Raman spectra (SERS) of the cationic porphyrin CuTMpyP4 adsorbed on the surface of the (HA)Ag film are measured. The detection limit of CuTMpyP4 is established as 10-12 M, which is comparable to the sensitivity of the wellknown solid-state SERS-active substrate.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>нанокомпозит</kwd><kwd>серебро</kwd><kwd>гидроксиапатит</kwd><kwd>гигантское комбинационное рассеяние</kwd><kwd>плазмонные пленки</kwd></kwd-group><kwd-group xml:lang="en"><kwd>nanocomposite</kwd><kwd>silver</kwd><kwd>hydroxyapatite</kwd><kwd>surface-enhanced Raman scattering</kwd><kwd>plasmonic films</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">M. Moskovits. Rev. Mod. 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