zhpsЖурнал прикладной спектроскопииZhurnal Prikladnoii Spektroskopii0514-7506B. I. Stepanov Institute of Physics of the National Academy of Scienceszhps-952Research ArticleСтатьиСпектроскопический анализ водного раствора метиленового синего в видимом диапазонеVisible light spectroscopic analysis of methylene blue in waterFernández-PérezA.Fernández-PérezA.

33011 Овьедо

33011-Oviedo

MarbánG.MarbánG.

33011 Овьедо

33011-Oviedo

greca@incar.csic.esИнститут углеродной науки и техники (INCAR-CSIC)Instituto de Ciencia y Tecnología del Carbono (INCAR-CSIC)202130112021886976976Copyright © Fernández-Pérez A., Marbán G., 20212021Fernández-Pérez A., Marbán G.Fernández-Pérez A., Marbán G.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://zhps.ejournal.by/jour/article/view/952

Получена универсальная калибровочная кривая для определения концентрации полимеризуемых красителей в растворах в УФ-видимом диапазоне методом спектрофотометрии. Метод успешно применен для водных растворов метиленового синего в широком диапазоне концентраций метиленового синего и добавки NaCl независимо от распределения суммарной концентрации и температуры. Показано, что молярные доли каждого вида метиленового синего в растворе могут быть хорошо аппроксимированы с помощью простых алгебраических выражений для соотношения A650/A607. 

We herein report a universal calibration curve for the UV-visible spectrophotometric determination of the concentration of polymerizable dyes in solution. The method has been successfully applied to construct a calibration curve of methylene blue in water that is applicable over a wide range of methylene blue and chloride concentrations, regardless of both the aggregate concentration distribution and the temperature. In addition, it was found that the molar fractions of each methylene blue species in solution could be well approximated by means of simple algebraic expressions in the A650/A607 absorbance ratio. 

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The authors declare that there are no conflicts of interest present.