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In situ GENERATION OF Ag NANOPARTICLES ON POLY(VINYL ALCOHOL)/CHITOSAN NANOFIBERS AS FLEXIBLE SUBSTRATES FOR SURFACE-ENHANCED RAMAN SPECTROSCOPY DETECTION
Abstract
Flexible surface-enhanced Raman spectroscopy (SERS) substrates were produced by in situ chemical reduction of Ag+ on poly(vinyl alcohol)/chitosan (PVA/CS) nanofibers. PVA/CS nanofibers (which have a large number of amino and hydroxyl functional groups) were prepared by electrospinning, which can provide more sites for adsorbing Ag+ than pure PVA. The Ag nanoparticles were evenly distributed on the PVA/CS nanofibers. The SERS substrate also exhibited excellent water stability, sensitivity, and uniformity. The detection limit of probe molecule rhodamine 6G was 10−7 M and the relative standard deviation was 5%. In addition, the Ag-PVA/CS nanofibers substrate was effective for recognition and detection of norfloxacin, a well-known antibiotic that is pertinent to food safety and animal/human health.
Keywords
Supporting agencies: This work was financially supported by Science and Technology Project of Hebei Educational Department (QN2020401), Natural Science Foundation of Hebei Province (E2019209474), and Outstanding Youth Fund of North China University of Science and Technology (JQ201712). We thank Michael Scott Long, PhD, from Liwen Bianji (Edanz) (www.liwenbianji.cn) for editing the English text of a draft of this manuscript.
About the Authors
Y. Chen
School of Chemical Engineering and Technology at Hebei University of Technology; Testing and Analysis Center at North China University of Science and Technology
China
China
Ying Chen
Tianjin
Tangshan
J. Cao
School of Chemical Engineering and Technology at Hebei University of Technology
China
China
Jilin Cao
Tianjin
H. Wei
College of Material Science and Engineering at North China University of Science and Technology
China
China
Hengyong Wei
Tangshan
Z. Wu
College of Pharmaceutical Sciences at North China University of Science and Technology
China
China
Zhengang Wu
Tangshan
Y. Wei
College of Material Science and Engineering at North China University of Science and Technology
China
China
Yingna Wei
Tangshan
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For citations:
Chen Y., Cao J., Wei H., Wu Z., Wei Y. In situ GENERATION OF Ag NANOPARTICLES ON POLY(VINYL ALCOHOL)/CHITOSAN NANOFIBERS AS FLEXIBLE SUBSTRATES FOR SURFACE-ENHANCED RAMAN SPECTROSCOPY DETECTION. Zhurnal Prikladnoii Spektroskopii. 2022;89(5):746.
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