|Generate QR code
Open Access
Subscription Access
Amplification of the Signal of Surface- Enhanced Raman Scattering from a Monolayer of Organic Molecules in Sandwich Structures Based on Plasmonic Silver Nanoplates
Abstract
A novel technique was developed for fabrication of bilayer sandwich-type structures based on monolayers of laterally oriented silver nanoplates electrostatically deposited onto thin polymer films. We demonstrate a linear dependence of surface-enhanced Raman scattering (SERS) signal of 4-mercaptobenzoic acid ligand layer on surface concentration of deposited silver nanoplates in monolayer. We show the twofold enhancement of surface-enhanced Raman scattering signal of analyte, which is placed in the gaps between silver nanoplates monolayers in bilayer sandwich structures, comparing to the signal from a single silver nanoplates monolayer, with identical surface concentration of analyte molecules.
Keywords
surface-enhanced Raman scattering,
colloidal silver nanoplates,
electrostatic deposition,
sandwich-type structure
Supporting agencies: The work was carried out with the financial support of the Belarusian Republican Foundation for Basic Research within the framework of the X22M-051 project and partial financing within the framework of the assignment 2.1.04.01 GPNI “Chemical processes, reagents and technologies, bioregulators and bioorgchemistry”
About the Authors
P. O. Malakhovsky
Research Institute for Physical Chemical Problems of the Belarusian State University
Belarus
Belarus
Minsk
А. А. Ramanenka
B. I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus
Belarus
Belarus
Minsk
M. V. Artemyev
Research Institute for Physical Chemical Problems of the Belarusian State University
Belarus
Belarus
Minsk
References
1. J. Langer, D. Jimenez de Aberasturi, J. Aizpurua, R. A. Alvarez-Puebla, B. Auguié, J. J. Baumberg, G. C. Bazan, S. E. J. Bell, A. Boisen, A. G. Brolo, J. Choo, D. Cialla-May, V. Deckert, L. Fabris, K. Faulds, F. J. García de Abajo, R. Goodacre, D. Graham, A. J. Haes, C. L. Haynes, C. Huck, T. Itoh, M. Käll, J. Kneipp, Nicholas A. Kotov, H. Kuang, E. C. Le Ru, H. Kwee Lee, J.-F. Li, X. Y. Ling, S. A. Maier, T. Mayerhöfer, M. Moskovits, K. Murakoshi, J.-M. Nam, S. Nie, Y. Ozaki, I. Pastoriza-Santos, J. Perez-Juste, J. Popp, A. Pucci, S. Reich, B. Ren, G. C. Schatz, T. Shegai, S. Schlücker, L.-L. Tay, K. G. Thomas, Z.-Q. Tian, R. P. Van Duyne, T. Vo-Dinh, Y. Wang, K. A. Willets, C. Xu, H. Xu, Y. Xu, Y. S. Yamamoto, B. Zhao, L. M. Liz-Marzán. ACS Nano, 14 (2020) 28—117
2. S. Schlücker. Angew. Chem. Int. Ed., 53 (2014) 4756—4795
3. M. Futamata, M. Ishikura, C. Iida, S. Handa. Faraday Discuss., 178 (2015) 203—220
4. N. G. Khlebtsov, L. Lin, B. N. Khlebtsov, J. Ye. Theranostics, 10 (2020) 2067—2094
5. S. M. Stranahan, E. J. Titus, K. A. Willets. J. Phys. Chem. Lett., 2 (2011) 2711—2715
6. J. Smolsky, S. Kaur, C. Hayashi, S. K. Batra, A. V. Krasnoslobodtsev. Biosensors, 7 (2017) 7
7. S. E. J. Bell, M. R. McCourt. Phys. Chem. Chem. Phys., 11 (2009) 7348—7349
8. O. S. Kulakovich, E. V. Shabunya-Klyachkovskaya, A. S. Matsukovich, L. L. Trotsiuk, S. V. Gaponenko. J. Appl. Spectrosc., 83 (2016) 860—863
9. S. Schlucker [ed.]. Surface Enhanced Raman Spectroscopy: Analytical, Biophysical and Life Science Applications, Weinheim, Wiley-VCH (2011) 3—4
10. S.-H. Ciou, Y.-W. Cao, H.-C. Huang, D.-Y. Su, C.-L. Huang. J. Phys. Chem. C, 113 (2009) 9520—9525
11. Q. Zhang, N. Li, J. Goebl, Z. Lu, Y. Yin. J. Am. Chem. Soc., 133 (2011) 18931—18939
12. A. D. McFarland, M. A. Young, J. A. Dieringer, R. P. Van Duyne. J. Phys. Chem. C, 109 (2005) 11279—11285
13. X. Zou, S. Dong. J. Phys. Chem. B, 110 (2006) 21545—21550
14. T. A. Mai Ngoc, D. T. D. Nguyen, V. K. T. Ngo, P. P. Nguyen Thi, D. H. Nguyen, M. T. Nguyen-Le. Plasmonics, 15 (2020) 2185—2194[
15. C. H. Zhang, J. Zhu, J. J. Li, J. W. Zhao. ACS Appl. Mater. Interfaces, 9 (2017) 17387—17398
16. P. Malakhovsky, I. Reznikov, D. Murausky, M. Artemyev. J. Phys. Chem. C, 127 (2023) 20398—20410
17. P. Malakhovsky, D. Murausky, D. Guzatov, S. Gaponenko, M. Artemyev. Z. Phys. Chem., 235 (2021) 1831—1848
18. X. Li, X. Tian, S. Liu, C. Wu, Y. Han, L. Meng, L. Song, Y. Zhang. J. Mater. Sci., 55 (2020) 14019—14030
19. X. Zhang, Z. Yu, W. Ji, H. Sui, Q. Cong, X. Wang, B. Zhao. J. Phys. Chem. C, 119 (2015) 22439—22444
20. S. Zhu, C. Fan, J. Wang, J. He, E. Liang. Appl. Phys. A Mater. Sci. Process, 117 (2014) 1075—1083
21. J. S. Suh, J. Kim. J. Raman Spectrosc., 29 (1998) 143—148
22. T. Mostowtt, J. Munoz, B. McCord. Analyst, 144 (2019) 6404—6414
23. P. Fenter, P. Eisenberger, J. Li, N. Camillone III, S. Bernasek, G. Scoles, T. A. Ramanarayanan, K. S. Liang. Langmuir, 7 (1991) 2013—2016
24. B. N. Khlebtsov, V. A. Khanadeev, M. Y. Tsvetkov, V. N. Bagratashvili, N. G. Khlebtsov. J. Phys. Chem. C, 117 (2013) 23162—23171
Review
For citations:
Malakhovsky P.O., Ramanenka А.А., Artemyev M.V. Amplification of the Signal of Surface- Enhanced Raman Scattering from a Monolayer of Organic Molecules in Sandwich Structures Based on Plasmonic Silver Nanoplates. Zhurnal Prikladnoii Spektroskopii. 2024;91(5):675-681. (In Russ.)
Views: 63
Email this article 