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Investigation of the Bleaching Properties of Photochromic Nanocomposites Based on Poly(Vinyl Alcohol) and Tungstophosphoric Acid

Abstract

We have shown that the discoloration of photochromic poly(vinyl alcohol)–tungstophosphoric acid  (PVA-TPA) nanocomposite films and PVA-TPA films containing glycerol (PVA-TPA-GL) colored by UV irradiation can be greatly accelerated by increasing the concentration of GL in the films and the ambient relative humidity. This study resolves the issues of polymer-heteropolyacid nanocomposites associated with their slow bleaching and, thus, makes them potentially applicable as new functional materials for inkless and erasable printing, anti-counterfeiting, sensors, smart windows.

About the Authors

A. A. Gorbachev
B. I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus
Belarus

Minsk



O. N. Tretinnikov
B. I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus
Belarus

Minsk



References

1. W. Feng, T. R. Zhang, Y. Liu, R. Lu, Y. Y. Zhao, J. N. Yao. J. Mater. Sci. Lett., 21, N 6 (2002) 497—499

2. L. M. Ai, W. Feng, J. Chen, Y. Liu, W. M. Cai. Mater. Chem. Phys., 109, N 1 (2008) 131—136

3. Z. Wang, R. Zhang, Y. Ma, L. Zheng, A. Peng, H. Fu, J. Yao. J. Mater. Chem., 20, N 6 (2010) 1107—1111

4. X. Jing, D. Zou, Q. Meng, W. Zhang, F. Zhang, W. Feng, X. Han. Inorg. Chem. Commun., 46 (2014) 149—154

5. O. N. Tretinnikov, N. I. Sushko. Appl. Phys. A, 125, N 12 (2019) 828

6. Н. И. Сушко, О. Н. Третинников. Журн. прикл. спектр., 77, № 4 (2010) 556—562 [N. I. Sushko, O. N. Tretinnikov. J. Appl. Spectr., 77, N 4 (2010) 516—521]

7. J. Fan, B. Bao, Z. Wang, H. Li, Y. Wang, Y. Chen, W. Wang, D. Yu. Chem. Eng. J., 404 (2021) 126488

8. Z. Liang, H. Cheng, H. Wang, L. Zhong, Q. Mao, D. Zhang. ACS Appl. Nano Mater., 5, N 12 (2022) 19043—19052

9. T. Yimyai, D. Crespy, A. Pena‐Francesch. Adv. Funct. Mater., 33, N 20 (2023) 2213717

10. N. Peng, J. Li, Y. Hua, S. Zhao, G. Li. ACS Appl. Mater. Interfaces, 16, N 6 (2024) 7973—7982

11. A. Sun, F. Nan, Q. Wei, L. Wang, W. W. Yu. Nano Energy, 126 (2024) 109679

12. T. Xiong, W. Yong, N. Chen, G. Fu. J. Photochem. Photobiol. A: Chem., 456 (2024) 115853

13. O. N. Tretinnikov, N. I. Sushko, A. V. Protosovskaya, A. V. Radkevich, E. I. Pavalanski. Polym. Adv. Technol., 33, N 1 (2022) 254—259

14. А. А. Горбачев, О. Н. Третинников. Журн. прикл. спектр., 91, № 3 (2024) 431—435 [A. A. Gorbachev, O. N. Tretinnikov. J. Appl. Spectr., 91, No. 3 (2024) 582—585]

15. A. A. Gorbachev, O. N. Tretinnikov. Mater. Lett., 397 (2025) 138868

16. G. M. Varga Jr., E. Papaconstantinou, M. T. Pope. Inorg. Chem., 9, N 33 (1970) 662—667

17. E. Papaconstantinou. Chem. Soc. Rev., 18 (1989) 1—31

18. W. Meng, J. Wang, L. Jiang. Responsive Mater., 2, N 3 (2024) e20240001

19. J. Gaume, P. Wong-Wah-Chung, A. Rivaton, S. Thérias, J. L. Gardette. RSC Adv., 1, N 8 (2011) 1471—1481

20. T. H. McHugh, J. M. Krochta. J. Agric. Food Chem., 42, N 4 (1994) 841—845

21. C. A. Finch. In: Chemistry and Technology of Water-Soluble Polymers, Boston, MA, Springer US (1983) 287—306


Review

For citations:


Gorbachev A.A., Tretinnikov O.N. Investigation of the Bleaching Properties of Photochromic Nanocomposites Based on Poly(Vinyl Alcohol) and Tungstophosphoric Acid. Zhurnal Prikladnoii Spektroskopii. 2025;92(5):588-592. (In Russ.)

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ISSN 0514-7506 (Print)