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CALCULATION OF BINDING PARAMETERS OF MAGNETIC IRON OXIDE NANOPARTICLES WITH DYES FROM SPECTROPHOTOMETRY DATA

Abstract

The possibility of using magnetic nanoparticles as an adsorbent for the effective removal of anionic dyes from aqueous solutions was investigated. The binding of eosin, tartrazine, and fast green with superparamagnetic Fe3O4 nanoparticles was studied using Vis spectroscopy. The binding parameters (constant and binding site) were obtained from spectrophotometric titration data using the Langmuir model for equilibrium binding. High values of binding constants (~105 M–1) indicate the promise of using magnetic nanoparticles to remove anionic dyes from polluted waters.

About the Authors

E. V. Dukhopelnikov
O. Ya. Usikov Institute for Radiophysics and Electronics, National Academy of Sciences of Ukraine; V. N. Karazin Kharkiv National University
Ukraine
Kharkiv, 61085; Kharkiv, 61077


D. A. Pesina
O. Ya. Usikov Institute for Radiophysics and Electronics, National Academy of Sciences of Ukraine
Ukraine
Kharkiv, 61085


E. G. Bereznyak
O. Ya. Usikov Institute for Radiophysics and Electronics, National Academy of Sciences of Ukraine
Ukraine
Kharkiv, 61085


N. A. Gladkovskaya
O. Ya. Usikov Institute for Radiophysics and Electronics, National Academy of Sciences of Ukraine
Ukraine
Kharkiv, 61085


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Review

For citations:


Dukhopelnikov E.V., Pesina D.A., Bereznyak E.G., Gladkovskaya N.A. CALCULATION OF BINDING PARAMETERS OF MAGNETIC IRON OXIDE NANOPARTICLES WITH DYES FROM SPECTROPHOTOMETRY DATA. Zhurnal Prikladnoii Spektroskopii. 2020;87(2):289-295. (In Russ.)

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