INFRARED REFLECTION AND TRANSMISSION SPECTRA OF MgAl2O4 CERAMIC SPINEL
Abstract
The infrared spectra of magnesium aluminate spinel (MAS, MgAl2O4) ceramic are recorded in a wide range from 50 to 1000 cm–1 (reflectivity) and 1000–5000 cm–1 (transmittance). In addition to the MAS reflectivity spectrum, the IR reflection spectrum of a-Al2O3 is recorded in the range of structural bands. A comparative analysis permits to clarify the origin of the series of structural bands in the spectrum, which is composed of vibrations localized in either octahedra AlO6 or tetrahedral MgO4 and AlO4 cells. A comparison of the spectra is carried out for two MAS ceramics synthesized both by the hydrolysis of double Mg-Al isopropylate method and the modified Pechini method.
About the Authors
E. V. Golieva
S. I. Vavilov State Optical Institute; Peter the Great St. Petersburg Polytechnic
University
Russian Federation
St. Petersburg
Russian Federation
St. Petersburg
A. A. Dunaev
S. I. Vavilov State Optical Institute
Russian Federation
St. Petersburg
Russian Federation
St. Petersburg
A. I. Markova
Tver’ State University
Russian Federation
Tver’
Russian Federation
Tver’
P. M. Pakhomov
Tver’ State University
Russian Federation
Tver’
Russian Federation
Tver’
S. D. Khizhnyk
Tver’ State University
Russian Federation
Tver’
Russian Federation
Tver’
A. E. Chmel
Ioffe Institute
Russian Federation
St. Petersburg
Russian Federation
St. Petersburg
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Review
For citations:
Golieva E.V., Dunaev A.A., Markova A.I., Pakhomov P.M., Khizhnyk S.D., Chmel A.E. INFRARED REFLECTION AND TRANSMISSION SPECTRA OF MgAl2O4 CERAMIC SPINEL. Zhurnal Prikladnoii Spektroskopii. 2020;87(3):434-447. (In Russ.)
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