STRUCTURAL AND LUMINESCENCE PROPERTIES OF Pb2+ DOPED Li6Gd(BO3)3 PHOSPHOR
Abstract
We synthesized pure and Pb2+ ion doped Li6Gd(BO3)3 phosphors via the solid-state reaction method at 700oC for 5 h in air. The phase analysis of the synthesized materials was determined using DTA/TGA, XRD, and FTIR. The photoluminescence characteristics of pure and Pb2+ doped phosphors were investigated at room temperature using a photoluminescence spectrophotometer. The emission and excitation bands of Pb2+ doped Li6Gd(BO3)3 were observed at 313 and 242 nm, respectively. The dependence of the PL intensities on the Pb2+ concentration for the Li6Gd1-xPbx(BO3)3 (0.005 £ x £ 0.025) phosphors was also studied. The highest emission intensity was obtained from 0.02 mol Pb2+ doped Li6Gd(BO3)3.
About the Authors
E. Erdoğmuş
Bartın University, Department of Environmental Engineering
Turkey
74100 Bartın
Turkey
74100 Bartın
E. Yildiz
Yozgat Bozok University, Department of Chemistry
Turkey
66900 Yozgat
Turkey
66900 Yozgat
References
1. R. Arun Kumar, J. Chem., 1 (2013); doi 10.1155/2013/154862.
2. D. Xue, K. Betzler, H. Hesse, D. Lammers, Solid State Commun., 114, 21–25 (2000).
3. T. Sasaki, Y. Mori, M. Yoshimura, Y. K. Yap, T. Kamimura, Mater. Sci. Eng. Rep., 30, 1–54 (2000).
4. V. T. Adamiv, Ya. V. Burak. I. M. Teslyuk, J. Cryst. Growth, 289, 157–160 (2006).
5. B. V. Padlyak, V. T. Adamiv, Ya. V. Burak, M. Kolcun, Physica B, 412, 79–82 (2013).
6. G. E. Malashkevich, V. N. Sigaev, N. V. Golubev, E. Kh. Mamadzhanova, A. V. Danil’chik, V. Z. Zubelevich, E. V. Lutsenko, JETP Lett., 92, 497–501 (2010).
7. M. Prokic, Radiat. Meas., 33, 393–396 (2001).
8. M. F. Dubovik, T. I. Korshikova, Yu. S. Oseledchik, S. V. Parkhomenko, A. L. Prosvirnin, N. V. Svitanko, A. V. Tolmachev, R. P. Yavetsky, Funct. Mater., 12, 685–688 (2005).
9. A. C. Fernandes, M. Osvay, J. P. Santos, V. Holovey, M. Ignatovych, Radiat. Meas., 43, 476–479 (2008).
10. I. N. Ogorodnikov, N. E. Poryvai, J. Lumin., 132, 1318–1324 (2012).
11. A. Un, Radiat. Phys. Chem., 85, 23–25 (2013).
12. M. Ishii, Y. Kuwano, S. Asaba, T. Asai, M. Kawamura, N. Senguttuvan, T. Hayashi, M. Koboyashi, M. Nikl, S. Hosoya, K. Sakai, T. Adachi, T. Oku, H. M. Shimizu, Radiat. Meas., 38, 571–574 (2004).
13. B. I. Zadneprowski, N. V. Eremin, A. A. Paskhalov, Funct. Mater., 12, 261–267 (2005).
14. E. W. Deeg, In: Industrial Borate Glasses, Eds. L. D. Pye, V. D. Frechette, N. J. Kreidl, Plenum Press, New York, 587–596 (1978).
15. D. Ehrt, Glass Technol., 41, 182–185 (2000).
16. R. Komatsu, H. Kawano, Z. Oumaru, K. Shinoda, V. Petrov, J. Cryst. Growth, 275, 843–847 (2005).
17. B. V. Padlyak, S. I. Mudry, Y. O. Kulyk, A. Drzewiecki, V. T. Adamiv, Y. V. Burak, I. M. Teslyuk, Mater. Sci. Pol., 30, 264–273 (2012).
18. Q. Wang, Z. Mu, S. Zhang, X. Feng, Q. Zhang, D. Zhu, Y. Yang, F. Wu, Optik, 174, 56–61 (2018).
19. I. Pekgozlu, E. Erdogmus, S. Cubuk, A. S. Basak, J. Lumin., 132, 1394–1399 (2012).
20. G. Blasse, Prog. Solid-State Chem., 18, 79–171 (1998).
21. J. Chaminade, V. Jubera, A. Garcia, P. Gravereau, C. Fouassier, J. Optoelectron. Adv. Mater., 2, 451–458 (2000).
22. S. P. Bhagat, A. B. Gawande, S. K. Omanwar, Opt. Mater., 40, 36–40 (2015).
23. J. Sablayrolles, V. Jubera, J.-P. Chaminade, I. Manek-Hönninger, S. Murugan, T. Cardinal, R. Olazcuaga, A. Garcia, F. Salin, Opt. Mater., 27, 1681–1685 (2005).
24. É. Tichy-Rács, Á. Péter, V. Horváth, K. Polgár, K. Lengyel, L. Kovács, Mater. Sci. Forum., 729, 493–496 (2013).
25. S. Pana, J. Zhanga, J. Pana, G. Ren, N. Lic, Z. Wuc, Y. Heng, J. Alloys Compd., 751, 129–137 (2018).
26. I. N. Ogorodnikov, V. A. Pustovarov, J. Lumin., 134, 113–125 (2013).
27. V. N. Baumer, M. F. Dubovik, B. V. Grinyov, T. I. Korshikova, A. V. Tolmachev, A. N. Shekhovtsov, Radiat. Meas., 38, 359–362 (2004).
28. F. Zhanga, Y. Wanga, Y. Taob, Phys. Procedia, 29, 55–61 (2012).
29. P. Chen, F. Mo, A. Guan, R. Wang, G. Wang, S. Xia, L. Zhou, Appl. Radiat. Isotop., 108, 148–153 (2016).
30. M. M. Yawalkar, G. D. Zade, V. Singh, S. J. Dhoble, J. Mater. Sci: Mater. Electron., 28, 180–189 (2017).
31. X. Ma, J. Li, Z. Zhu, Z. You, Y. Wang, C. Tu, J. Lumin., 128, 1660–1664 (2008).
32. W. G. Zou, M. K. Lü, F. Gu, S. Wang, Z. Xiu, G. Zhou, Mater. Sci. Eng. B, 127, 134–137 (2006).
33. G. Blasse, Solid State Chem., 18, 79–171 (1998).
34. A. A. Setlur, A. M. Srivastava, Opt Mater., 29, 410–415 (2006).
35. M. Paraschiva, I. Nicoara, M. Steff, M. Bunoiu, Acta Phys. Pol. A, 117, 466–470 (2010).
36. I. Pekgözlü, S. Taşcıoğlu, A. Menger, Inorg. Mater., 44, 1151–1154 (2008).
37. I. Pekgözlü, H. Karabulut, Inorg. Mater., 45, 61–64 (2009).
38. D. L. Dexter, J. H. Schulman, J. Chem. Phys., 22, 1063 (1954)
39. W. Zhang, P. Xie, C. Duan, K.Yan, M. Yin, L. Lou, S. Xia, J.-C. Krupa, Chem. Phys. Lett., 292, 133–136 (1998).
40. A. Manavbasi, J. C. LaCombe, J. Lumin., 128, 129–134 (2008).
41. S. F. Wang, M. K. Lü, F. Gu, C. F. Song, D. Xu, D. R. Yuan, G. J. Zhou, Y. X. Qi, Inorg. Chem. Commun., 6, 185–188 (2003).
42. Z. Xiu, S. Liu, F. Xu, M. Ren, J. Pan, X. Cui, W. Yu, J. Yu, J. Alloys Compd., 441, 219–221 (2007).
43. E. Erdoğmuş, İ. Pekgözlü, E. Korkmaz, A. S. Başak, J. Appl. Spectrosc., 81, 336–340 (2014).
44. L. Wu, Y. Zhang, Y. F. Kong, T. Q. Sun, J. J. Xu, X. L. Chen, Inorg. Chem., 13, 5207–5211 (2007).
45. G. Blasse, S. J. M. Sas, W. M. A. Smit, Mater. Chem. Phys., 14, 253–258 (1986).
Review
For citations:
Erdoğmuş E., Yildiz E. STRUCTURAL AND LUMINESCENCE PROPERTIES OF Pb2+ DOPED Li6Gd(BO3)3 PHOSPHOR. Zhurnal Prikladnoii Spektroskopii. 2020;87(4):555-560.
Views: 299
Email this article 