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Preparation and Properties of Sr3B2O6:Dy3+,Eu3+
Abstract
Sr3B2O6:Dy3+,Eu3+ single-matrix white-light-emitting materials are prepared using the high-temperature solid-state method. The microstructure, emission spectrum, energy transfer mechanism, and color brightness of the samples are studied using scanning electron microscopy, X-ray diffraction, fluorescence spectrophotometry, and color coordinate (CIE) calculations. Furthermore, the effects of the synthesis temperature, holding time, rare-earth element doping amount, and charge compensation agent on the luminescence intensity of the samples are investigated. Results show that the luminescent effect of the sample containing Na+ as the charge compensator is better than that of the sample containing K+. When the concentrations of Dy3+ and Eu3+ are 2 and 3%, respectively, the calcination temperature is 700°C, and the holding time is 3 h, the samples exhibit the best luminescence performance and the color coordinates are in the white-light region, indicating a good white-light luminescent material.
Supporting agencies: This work was supported by the Guangxi Base and Talents Project (AD19110086), the Foundation of Guilin University of Technology (GUTQDJJ2018024), and the Open Foundation, Guangxi Key Laboratory of Optical and Electronic Materials and Devices (20KF-14).
About the Authors
Y. Li
Guangxi Key Laboratory of Optical and Electronic Materials and Devices, Guilin University of Technology
China
China
Guilin
W. H. Shi
Guangxi Key Laboratory of Optical and Electronic Materials and Devices, Guilin University of Technology
China
China
Guilin
L. M. Dong
Key Laboratory of Engineering Dielectrics and Its Application, Ministry of Education, Harbin University of Science and Technology
China
China
Harbin
S. X. Xu
Guangxi Key Laboratory of Optical and Electronic Materials and Devices, Guilin University of Technology
China
China
Guilin
H. J. Huang
Guangxi Key Laboratory of Optical and Electronic Materials and Devices, Guilin University of Technology
China
China
Guilin
J. R. Yin
Guangxi Key Laboratory of Optical and Electronic Materials and Devices, Guilin University of Technology
China
China
Guilin
References
1. Y. Xie, Y. Yin, R. X. Zhang, H. B. Wang, New. Chem. Mater., 40, No. 2, 24–27 (2012).
2. Q. Su, H. Wu, Y. X. Pan, C. F. Guo, J. Rare Earths., 23, No. 5, 513–517 (2005).
3. L. Kong, S. C. Gan, G. Y. Hong, J. L. Zhang, Chin. J. Lumin., 28, No. 3, 393–396 (2007).
4. Q. S. Liu, X. Y. Hao, G. F. Xu, L. Zhao, D. D Cao, Chin. J. Inorg. Chem., 26, No. 7, 1303–1306 (2010).
5. S. Pimputkar, J. S. Speck, S. P. DenBaars, S. Nakamura, Nat. Photon., 3, 180–182 (2009).
6. W. Y. He, Wang X. F. Wang, J. Zheng, X. H. Yan, J. Am. Ceram. Soc., 97, No. 6, 1750–1755 (2014).
7. W. Lv, Y. C. Jia, Q. Zhao, W. Z. Lv, H. P. You, Chem. Commun., 50, No. 20, 2635–2637 (2014).
8. H. X. Liu, Z. Y. Guo, J. Lumin., 187, 181–185 (2017).
9. R. L. Zheng, D. W. Luo, Y. Yuan, Z. Y. Wang, J. Am. Ceram. Soc., 98, No. 10, 3231–3235 (2015).
10. Y. Y. Li, Y. R. Shi, G. Zhu, Q. S. Wu, Inorg. Chem., 53, No. 14, 7668–7675 (2014).
11. X. Y. Huang, B. Li, H. Guo, J. Alloys Compd., 695, 2773–2780 (2017).
12. L. Fan, X. Zhao, S. Zhang, Y. Ding, J. Alloys Compd., 579, 432–437 (2013).
13. M. Xia, S. B. Zeng, J. Z. Wang, China Light & Lighting, 1, 9–12 (2015).
14. A. Xie, X. M. Yuan, New. Chem. Mater., 36, No. 12, 14–16 (2008)
15. S. H. Zhang, M. B. Zhou, J. F. Hu, B. Xie, Int. Mater. Rev., 23, No. 9, 25–29 (2009).
16. N. N. Trac, H. V. Tuyen, V. X. Quang, Phys. B, 595, 41237 (2020).
17. M. S. Huang, K. X. Zhang, Y. B. Zhang, Y. Z. Chen, Rare Met. Cem. Carbides, 40, No. 1, 34–37 (2012).
18. X. Ding, Y. Xu, C. F. Guo, Acta Phys. Sin., 59, No. 9, 6632–6636 (2010).
19. W. S. Song, Y. S. Kim, H. Yang, Mater. Chem. Phys., 117, No. 2-3, 500–503 (2009).
20. Z. P. Yang, F. L. Zhang, X. N. Li, Chin. J. Lumin., 29, No. 6, 941–944 (2008).
21. A. Lakshmanan, R. S. Bhaskar, P. C. Thomas, Mater. Lett., 64, No. 16, 1809–1812 (2010).
22. R. Wang, J. Xu, C. Chen, Chin. J. Lumin., 32, No. 10, 983–987 (2011).
23. H. H. Lin, S. Wu, Y. Y. Wu, Bull. Chin. Ceram. Soc., 32, No. 1, 154–157 (2012).
24. T. H. Van, S. N. Manh, Q. V. Xuan, S. Bounyavong, Luminescence, 31, No. 5, 1103–1108 (2015).
25. C. K. Chang, T. M. Chen, Appl. Phys. Lett., 91, No. 8, 81902–81903 (2007).
Review
For citations:
Li Y., Shi W.H., Dong L.M., Xu S.X., Huang H.J., Yin J.R. Preparation and Properties of Sr3B2O6:Dy3+,Eu3+. Zhurnal Prikladnoii Spektroskopii. 2022;89(3):429.
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