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Spectral-Luminescent Study of the Stability of meso-Substituted Porphyrins in the Reaction of Radical Copolymerization with Acrylamide
Abstract
A comparative study of the spectral-luminescent properties of mono- and tetra-meso-allyloxy-substituted porphyrins has been performed. The efficiency of the photosensitized formation of singlet molecular oxygen by porphyrins has been determined. The regularities of the formation of chlorin and bacteriochlorin structures in the process of radical-chain copolymerization of acrylamide with the investigated porphyrins are considered. The mechanism of their recovery is discussed.
About the Authors
N. L. Pechnikova
Research Institute of Macroheterocyclic compounds, Ivanovo State University of Chemistry and Technology
Russian Federation
Russian Federation
Ivanovo
E. A. Venediktov
G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences
Russian Federation
Russian Federation
Ivanovo
I. V. Shilov
Research Institute of Macroheterocyclic compounds, Ivanovo State University of Chemistry and Technology
Russian Federation
Russian Federation
Ivanovo
V. D. Korobova
Research Institute of Macroheterocyclic compounds, Ivanovo State University of Chemistry and Technology
Russian Federation
Russian Federation
Ivanovo
T. A. Ageeva
Research Institute of Macroheterocyclic compounds, Ivanovo State University of Chemistry and Technology
Russian Federation
Russian Federation
Ivanovo
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Review
For citations:
Pechnikova N.L., Venediktov E.A., Shilov I.V., Korobova V.D., Ageeva T.A. Spectral-Luminescent Study of the Stability of meso-Substituted Porphyrins in the Reaction of Radical Copolymerization with Acrylamide. Zhurnal Prikladnoii Spektroskopii. 2023;90(3):516-519. (In Russ.)
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