|Generate QR code
Open Access
Subscription Access
Application of Plasmonic Nanoparticles for the Composition Analysis of Paint Layers by Surface Enhanced Raman Scattering
Abstract
Sample preparation methods have been developed and adapted for using gold nanoparticles in the qualitative analysis of paint layers composition with the surface-enhanced Raman scattering (SERS) method. The use of plasmonic nanoparticles for the SERS analysis of art materials in real objects of painting can significantly reduce the luminescent background caused by the presence of organic binders of the paint layer, and, along with multiple amplification of the chromophore Raman line`s intensities, leads to an increase in the signal-to-noise ratio. The techniques are successfully tested on the paint layers of 12 easel paintings of the XVI—XIX centuries in close cooperation with the museums of the Republic of Belarus, can be systematically used in art history expertise for identification of the composition of paints and attribution of cultural heritage objects.
About the Author
O. S. Kulakovich
B. I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus
Belarus
Belarus
Minsk
References
1. S. L. McCall, P. M. Platzman, P. A. Wolff. Phys. Lett. A, 77, N 5 (1980) 381—383
2. S. V. Gaponenko. Introduction to Nanophotonics, CUP, Cambridge (2010) [3] M. Moskovits. Rev. Mod. Phys., 57, N 3 (1985) 783—828
3. S. Nie, S. R. Emory. Science, 275, N 5303 (1997) 1102—1106
4. M. Fleischmann, P. J. Hendra, A. J. McQuillan. Chem. Phys. Lett., 26, N 2 (1974) 163—166
5. E. Klyachkovskaya, N. Strekal, I. Motevich, S. Vaschenko, A. Harbachova, M. Belkov, S. Gaponenko, Ch. Dais, H. Sigg, T. Stoica, D. Grützmacher. Plasmonics, 6, N 2 (2011) 413—418
6. Е. В. Клячковская, Н. Д. Стрекаль, И. Г. Мотевич, С. В. Ващенко, М. Я. Валах, А. Н. Горбачева, М. В. Бельков, С. В. Гапоненко. Опт. и спектр., 110, № 1 (2011) 53—59
7. E. V. Klyachkovskaya, D. V. Guzatov, N. D. Strekal, S. V. Vaschenko, A. N. Harbachova, M. V. Belkov, S. V. Gaponenko. J. Raman Spectr., 43, N 6 (2012) 741—744
8. E. V. Shabunya-Klyachkovskaya, S. V. Gaponenko, S. V. Vaschenko, V. V. Stankevich, N. P. Stepina, A. S. Matsukovich. J. Appl. Spectr., 81 (2014) 399—403]
9. Ю. И. Гренберг. Технология и исследование произведений станковой и настенной живописи, Москва, ГосНИИР (2000)
10. J. Grand, M. Lamy de la Chapelle, J.-L. Bijeon, P.-M. Adam, A. Vial, P. Royer. Phys. Rev. B, 72, N 3 (2005) 033407(1—4)
11. G. McNay, D. Eustace, W. E. Smith, K. Faulds, D. Graham. Appl. Spectr., 65, N 8 (2011) 825—837
12. J. Turkevich, P. C. Stevenson, J. Hillier. Disc. Faraday Soc., 11, N 4 (1951) 55—57
13. B. Nikoobakht. Chem. Mater., 15, N 10 (2003) 1957—1962
14. A. Matsukovich, L. Trotsiuk, O. Kulakovich, E. Shabunya–Klyachkovskaya, I. Mamedova. J. Nanophotonics, 15, N 1 (2021) 016010(1—8)
15. L. Trotsiuk, A. Antanovich, A. Lizunova, O. Kulakovich. Colloid Interface Sci. Commun., 37 (2020) 100289(1—8)
16. O. Kulakovich, E. Shabunya‐Klyachkovskaya, L. Trotsiuk, A. Matsukovich, Y. Korza. J. Raman Spectrosc., 50, N 7 (2019) 936—944
17. E. Shabunya-Klyachkovskaya, O. Kulakovich, S. Vaschenko, D. Guzatov, S. Gaponenko. Eur. J. Sci. Theology, 12, N 3 (2016) 211—220
18. O. S. Kulakovich, E. V. ShabunyaKlyachkovskaya, A. S. Matsukovich, L. L. Trotsiuk, S. V. Gaponenko. J. Appl. Spectr., 83 (2016) 860—863
19. G. J. Kovacs, R. O. Loutfy, P. S. Vincett, C. Jennings, R. Aroca. Langmuir, 2, N 6 (1986) 689—694
20. M. Brust, M. Walker, D. Bethell, D. J. Schiffrin, R. J. Whyman. Chem. Soc., Chem. Commun., 7 (1994) 801—802
21. E. V. Shabunya-Klyachkovskaya, E. V. Korza, L. L. Trotsiuk, A. S. Matsukovich, O. S. Kulakovich. Proc. Int. Conf. “Nanomeeting-2017 (Physics, Chemistry and Applications of Nanostructures)”, Minsk, 30 May—2 June 2017, World Scientific Publishing, Ed. V. E. Borisenko, Singapore (2017) 236—239
22. J. I. Gersten. J. Chem. Phys., 72, N 10 (1980) 5779—5780
23. B. Nikoobakht, M. A. El-Sayed. J. Phys. Chem. A, 107, N 18 (2003) 3372—3378
24. I. Ros, T. Placido, V. Amendola, C. Marinzi, N. Manfredi, R. Comparelli, M. Striccoli, A. Agostiano, A. Abbotto, D. Pedron, R. Pilot, R. Bozio. Plasmonics, 9, N 3 (2014) 581—593
25. C. J. Orendorff, L. Gearheart, N. R. Janaz, C. J. Murphy. Phys. Chem. Chem. Phys., 8, N 1 (2006) 165—170
26. H. Guo, F. Ruan, L. Lu, J. Hu, J. Pan, Z. Yang, B. Ren. J. Phys. Chem. C, 113, N 24 (2009) 10459—10464
27. L. L. Trotsiuk, A. S. Matsukovich, E. V. Shabunya-Klyachkovskaya, O. S. Kulakovich. Proc. Int. Conf. “Nanomeeting-2017 (Physics, Chemistry and Applications of Nanostructures)”, Minsk, 30 May— 2 June 2017, World Scientific Publishing, Ed. V. E. Borisenko, Singapore (2017) 244—247
28. Л. Л. Троцюк, О. С. Кулакович, Е. В. Шабуня-Клячковская, С. В. Ващенко, С. В. Гапоненко. Докл. НАН Беларуси, 60, N 4 (2016) 44—48
29. М. К. Никитин, Е. П. Мельникова. Химия в реставрации, Ленинград, Химия (1990)
30. Л. Л Троцюк. Получение наночастиц золота и пленок на их основе для управления оптическими свойствами молекул, нано- и микрокристаллов: дис. … канд. хим. наук, Минск (2020)
31. E. V. Shabunya-Klyachkovskaya, O. S. Kulakovich, S. V. Gaponenko. Spectrochim. Acta A: Mol. Biomol. Spectrosc., 222, N 5 (2019) 117235(1—13)
32. E. V. Shabunya-Klyachkovskaya, A. G. Mitskevich, Y. F. Moiseev, L. L. Sysoeva, O. S. Kulakovich, V. V. Kiris, A. S. Matsukovich, A. G. Karoza, M. V. Belkov. J. Cult. Heritage, 28 (2017) 158—163
Review
For citations:
Kulakovich O.S. Application of Plasmonic Nanoparticles for the Composition Analysis of Paint Layers by Surface Enhanced Raman Scattering. Zhurnal Prikladnoii Spektroskopii. 2023;90(4):553-560. (In Russ.)
Views: 515
Email this article 