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Electrocatalytic and Photoelectrochemical Properties of Nanotubular TiO2 Electrodes Thermally Treated in Air and Hydrogen
Abstract
Photoelectrochemical, structural, and electrocatalytic properties of titanium dioxide (TiO2) nanotubes obtained by the anodization of titanium with subsequent thermal treatment in air or hydrogen were studied. It was shown that thermal treatment of TiO2 nanotubes in hydrogen had no effect on the morphology and phase composition of TiO2 electrodes. However, such treatment led to a high concentration of defect states in the crystal lattice of TiO2 due to reductive doping accompanied by the conversion of Ti4+ to Ti3+. A rise of the defectiveness resulted in a lowering of the overpotential for oxygen electroreduction at titanium dioxide nanotubes annealed in hydrogen compared to those annealed in air. In addition, annealing in hydrogen led to a significant increase in the long-wavelength photocurrent generated under visible light irradiation.
About the Authors
H. M. Maltanava
Research Institute for Physical Chemical Problems of the Belarusian State University;
A. N. Sevchenko Institute of Applied Physical Problems of the Belarusian State University
Belarus
Belarus
Minsk
A. O. Konakov
Research Institute for Physical Chemical Problems of the Belarusian State University;
Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry of the Russian Academy of Sciences
Belarus
Belarus
Minsk, Chernogolovka, Moscow region
T. V. Gaevskaya
Research Institute for Physical Chemical Problems of the Belarusian State University
Belarus
Belarus
Minsk
N. V. Belko
A. N. Sevchenko Institute of Applied Physical Problems of the Belarusian State University
Belarus
Belarus
Minsk
M. P. Samtsov
A. N. Sevchenko Institute of Applied Physical Problems of the Belarusian State University
Belarus
Belarus
Minsk
S. K. Poznyak
Research Institute for Physical Chemical Problems of the Belarusian State University
Belarus
Belarus
Minsk
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Review
For citations:
Maltanava H.M., Konakov A.O., Gaevskaya T.V., Belko N.V., Samtsov M.P., Poznyak S.K. Electrocatalytic and Photoelectrochemical Properties of Nanotubular TiO2 Electrodes Thermally Treated in Air and Hydrogen. Zhurnal Prikladnoii Spektroskopii. 2023;90(6):882-896. (In Russ.)
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