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Microstructure and Raman Scattering of CdS Films Obtained with Chemical Deposition Method
Abstract
The crystallographic structure, elemental composition, and surface morphology of the cadmium sulfide (CdS) thin films chemically deposited at Т = 62 ± 1 о С on glass substrates from aqueous solution consisting of NH4OH (25 %), 0.0096M CdSO4, and 0.8M CS(NH2)2 have been studied. The characteristics of these films have been obtained by the scanning electron microscopy, studies of the phase and elemental composition, as well as Raman spectra. It is shown that the selected solution’s composition and deposition modes allow to synthesize CdS films with stoichiometric composition, consisting of nanocrystals of hexagonal modification suitable for solar cells applications.
About the Authors
E. P. Zaretskaya
Scientific and Practical Center of the National Academy of Sciences of Belarus for Materials Science
Belarus
Belarus
Minsk
V. Ph. Gremenok
Scientific and Practical Center of the National Academy of Sciences of Belarus for Materials Science
Belarus
Belarus
Minsk
K. P. Buskis
Scientific and Practical Center of the National Academy of Sciences of Belarus for Materials Science
Belarus
Belarus
Minsk
O. V. Korolik
Belarusian State University
Belarus
Belarus
Minsk
S. T. Pashanyan
Institute of Physical Research National Academy of Sciences of Armenia;
Institute of Radiophysics and Electronics National Academy of Sciences of Armenia
Armenia
Armenia
Ashtarak
A. S. Tokmajyan
Institute of Radiophysics and Electronics National Academy of Sciences of Armenia
Armenia
Armenia
Ashtarak
A. S. Musayelyan
Institute of Radiophysics and Electronics National Academy of Sciences of Armenia
Armenia
Armenia
Ashtarak
S. G. Petrosyan
Institute of Radiophysics and Electronics National Academy of Sciences of Armenia
Armenia
Armenia
Ashtarak
References
1. P. K. Nair, J. Campos, M. T. S. Nair. Semicond. Sci. Technol., 3 (1998) 134-145
2. J. B. Seon, S. Lee, J. M. Kim, H. D. Jeong. Chem. Mater., 21, N 4 (2009) 604-611
3. Y. Wang, S. Ramanathan, Q. Fan, Q. Yun, H. Morkoc, S. Bandyopadhyay. J. Nanosci. Nanotechnol., 6 (2006) 2077-2080
4. D. I. Klevin, R. Roth, A. K. I. Lim, A. P. Alivisators. Nature, 389 (1997) 699-701
5. J. Zhang, D. Li, R. Chen, Q. Xiong. Nature, 493 (2013) 504-508
6. A. A. Yadav, E. U. Masumdar. J. Alloys Compd., 509 (2011) 5394-5399
7. X. Mathew, J. P. Enriquez, A. Romeo, A. N. Tiwari. Sol. Energy, 77 (2004) 831-838
8. D. Wang, Z. Hou, Z. Bai. J. Mater. Res., 26 (2011) 697-705
9. J. Sterner, J. Malmstrom, L. Stolt, J. Malmström, L. Stolt. Prog. Photovolt. Res. Appl., 13 (2005) 179-193
10. A. Klein. J. Phys. Cond. Matter, 27 (2015) 134201(1-24)
11. H. Moualkia, S. Hariech, M. S. Aida, N. Attaf, E. L. Laifa. J. Phys. D: Appl. Phys., 42, N 13 (2009) 135404 (7)
12. P. Jackson, D. Hariskos, R. Wuerz, O. Kiowski, A. Bauer, T.M. Friedlmeier, M. Powalla. Phys. Status Sol. Rapid Res. Lett., 9 (2015) 28-31
13. K. Shirai, Y. Moriguchi, M. Ichimura, A. Usami, M. Saji. Jpn. J. Appl. Phys., 35 (1996) 2057-2060
14. B. E. Warren. X-ray Diffraction, Dover, New York (1990) 63-66
15. G. K. Williamson, R. E. Smallman. Philos. Mag., 1 (1956) 34-36
16. H.-R. Wenk, S. Matthies, L. Lutterotti. Mater. Sci. Forum, 157–162 (1994) 473-480
17. L. Lutterotti, S. Matthies, H.-R. Wenk, A. J. Schultz, J. Richardson. J. Appl. Phys., 81, N 2 (1997) 594-600
18. A. Ashok, G. Regmi, A. Romero-Núñez, M. Solis-López, S. Velumani, H. Castaneda. J. Mater. Sci.: Mater. Electron., 31, N 10 (2020) 7499-7518
19. D. L. Andrews, A. A. Demidov. An Introduction to Laser Spectroscopy, Springer Science+Business Media, LLC, Springer, Boston, MA (2002) 77-104
20. B. Tell, T. C. Damen, S. P. S. Porto. Phys. Rev., 144, N 2 (1966) 771-774
21. M. A. Nusimovici, M. Balkanski, J. L. Birman. Phys. Rev. B, 1 (1970) 595-603
22. V. Dzhagan, A. G. Milekhin, M. Ya. Valakh, S. Pedetti, M. Tessier, B. Dubertrete, D. R. T. Zahna. Nanoscale, 8 (2016) 17204-17212
23. R. K. K. Nanda, S. N. Sarangi, S. N. Sahu, S. K. Deb, S. N. Behera. Physica B, 262 (1999) 31-39
24. О. Zelaya-Angel, F. de L. Castillo-Alvarado, J. Avendailo-Lopez, A. Escamilla-Esquivel, G. Contreras-Puente, R. Lozada-Morales, G. Torres-Delgadod. Solid State Commun., 104, N 3 (1997) 161-166
25. V. M. Dzhagan, M. Y. Valakh, C. Himcinschi, A. G. Milekhin, D. Solonenko, N. A. Yeryukov, O. E. Raevskaya, O. L. Stroyuk, D. R. T. Zahn. J. Phys. Chem. C, 118, N 33 (2014) 19492-19497
26. T. T. K. Chi, G. Gouadec, Ph. Colomban, G. Wang, L. Mazerolles, N. Q. Liem. J. Raman Spectrosc., 42 (2011) 1007-1015
27. Muhammad Farooq Saleem, Hua Zhang, Yi Deng, Deliang Wang. J. Raman Spectrosc., 48, N 2 (2016) 224-229
28. R. Keshav, A. Rao, M. G. Mahesha. Opt. Quant. Electron., 50 (2018) 186(1-14)
29. V. F. Gremenok, K. P. Buskis, K. D. Kunin, M. S. Tivanov, L. S. Lyashenko, S. T. Pashayan, A. S. Musayelyan, A. S. Tokmajyan. Proc. X Int. Sci. Conf. “Actual Problems of Solids State Physics”, 22-26 May 2023, Minsk, Belarus, publ. A. Varaksin (2023) 106-109
Review
For citations:
Zaretskaya E.P., Gremenok V.P., Buskis K.P., Korolik O.V., Pashanyan S.T., Tokmajyan A.S., Musayelyan A.S., Petrosyan S.G. Microstructure and Raman Scattering of CdS Films Obtained with Chemical Deposition Method. Zhurnal Prikladnoii Spektroskopii. 2024;91(1):32-38. (In Russ.)
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