Luminescent Thermometry (Y1–xEr x) 2O3 Oxides
Abstract
A fast and simple method for the synthesis of solid solutions based on erbium-doped yttrium oxide (Y1–xErx)2O3 has been proposed. The crystal structure of samples was determined by X-ray diffraction method. Compounds exhibit greenish-yellow upconversion emission upon IR laser excitation (980 nm). An increase in the erbium concentration in (Y1–xErx)2O3 causes a change in the color of the upconversion luminescence and a growth of its intensity. The maximum intensity of the upconversion luminescence is observed for oxide with x = 0.05. Based on the pumping power dependence of intensity of emission lines associated with 2H11/2/4S3/2→4I15/2 и 4F9/2→4I15/2 transitions, the two-photon excitation mechanism was determined. The absolute and relative sensitivities were calculated from the temperature dependences of the ratio of emission lines corresponding to transitions from thermally coupled excited 2H11/2 and 4S3/2 levels, these values showed the promise for use of oxides as materials for non-contact temperature sensing.
About the Authors
I. V. BaklanovaRussian Federation
Ekaterinburg
V. N. Krasil’nikov
Russian Federation
Ekaterinburg
A. P. Tyutyunnik
Russian Federation
Ekaterinburg
Ya. V. Baklanova
Russian Federation
Ekaterinburg
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Review
For citations:
Baklanova I.V., Krasil’nikov V.N., Tyutyunnik A.P., Baklanova Ya.V. Luminescent Thermometry (Y1–xEr x) 2O3 Oxides. Zhurnal Prikladnoii Spektroskopii. 2024;91(2):184-188. (In Russ.)