Fluorozirconate Phosphate Glasses and Glass Ceramics: Visible and NIR Luminescence

I. G. Maslennikova; V. K. Goncharuk; A. G.  Mirochnik; A. A. Sergeev

Fluorozirconate Phosphate Glasses and Glass Ceramics: Visible and NIR Luminescence

I. G. Maslennikova, V. K. Goncharuk, A. G. Mirochnik, A. A. Sergeev

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Abstract

A comparative study of the luminescent properties of erbium(III)-doped fluorozirconate glass and fluorozirconate phosphate glass and glass ceramics containing NaPO₃ was carried out. The glasses were obtained by melt-quenching technique and characterized by methods of luminescent spectroscopy, differential thermal analysis, X-ray diffraction and transmission electron microscopy. When NaPO₃ is added, the relative luminescence intensity of Er(III) in the near infrared (IR) region doubles at 1530 nm (transition ⁴I_13/2→⁴I_15/2), the luminescence intensity of other bands in the visible and near IR regions decreases. The quantum yields and luminescence lifetimes of the studied samples were measured. The reasons for the change in luminescence intensity during the addition of NaPO₃ and after heat treatment of samples are discussed.

Keywords

fluorozirconate glasses, glass ceramics, luminescence, erbium(III)

About the Authors

I. G. Maslennikova

Institute of Chemistry, FEB Russian Academy of Sciences
Russian Federation

Vladivostok

V. K. Goncharuk

Institute of Chemistry, FEB Russian Academy of Sciences; Pacific S. O. Makarov Higher Naval School
Russian Federation

Vladivostok

A. G. Mirochnik

Institute of Chemistry, FEB Russian Academy of Sciences
Russian Federation

Vladivostok

A. A. Sergeev

Institute of Automation and Control Processes, FEB Russian Academy of Sciences
Russian Federation

Vladivostok

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For citations:

Maslennikova I.G., Goncharuk V.K., Mirochnik A.G., Sergeev A.A. Fluorozirconate Phosphate Glasses and Glass Ceramics: Visible and NIR Luminescence. Zhurnal Prikladnoii Spektroskopii. 2024;91(2):189-194. (In Russ.)

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Zhurnal Prikladnoii Spektroskopii

Fluorozirconate Phosphate Glasses and Glass Ceramics: Visible and NIR Luminescence

Full Text:

Abstract

Keywords

About the Authors

References

Review

For citations:

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