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Synthesis and Spectral-Luminescent Properties of Light-Accumulating Oxides HfO2-ZrO2
Abstract
Light-accumulating oxide systems HfO2−ZrO2 with the duration of afterglow up to 10 min were synthesized by the method of chemical deposition and their spectral-luminescent properties were investigated. It was found that the value of HfO2:ZrO2 ratio has a significant influence on the intensity and decay kinetics of visible luminescence of such systems, as well as on the values of the weight coefficients and the positions of individual components of the spectral bands of luminescence and its excitation. The result is explained by the contribution of complex optical centers of titanium impurity in ZrO2 to the intracenter luminescence of oxygen vacancies in HfO2 and competing with quenching of luminescence by nonradiative recombination centers.
About the Authors
G. E. MalashkevichBelarus
Minsk
Yu. V. Bokshits
Belarus
Minsk
E. A. Kovel
Belarus
Minsk
V. A. Zhuravkov
Belarus
Minsk
G. P. Shevchenko
Belarus
Minsk
V. V. Kouhar
Belarus
Minsk
A. A. Ramanenka
Belarus
Minsk
I. V. Stanishevsky
Belarus
Minsk
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Review
For citations:
Malashkevich G.E., Bokshits Yu.V., Kovel E.A., Zhuravkov V.A., Shevchenko G.P., Kouhar V.V., Ramanenka A.A., Stanishevsky I.V. Synthesis and Spectral-Luminescent Properties of Light-Accumulating Oxides HfO2-ZrO2. Zhurnal Prikladnoii Spektroskopii. 2024;91(3):371-377. (In Russ.)