X-Ray Photo electron and Rutherford Backscattering Spectroscopy Studies of Silicon Hyperdoped with Selenium
Abstract
The possibility of surface passivation with selenium for silicon layers hyperdoped with Se was estimated by the X-Ray photoelectron and Rutherford backscattering spectroscopy. Silicon layers hyperdoped with selenium have been formed by Se implantation (140 keV, 6.1 · 1015 cm–2) followed by pulsed laser annealing (PLA) (λ = 694 nm, W = 2.0 J/cm2, τ = 70 ns). It was found that the Se concentration in the sub-surface region (2.0–2.5 nm) is 0.67% (3.35 · 1020 cm–3). Such a high concentration of Se can be attributed to the effect of accumulation of these species in the near-surface region during the PLA process. It was shown that Se is solely bonded to Si, Se-O bonds were not formed in the sub-surface region of the implanted layer during PLA. The chosen laser pulse energy density of W = 2.0 J/cm2 has provided achieving the structural perfection (above 91 %) and high concentration of Se at the Si lattice sites (above 69 %).
About the Authors
F. F. KomarovBelarus
Minsk
Wang Ting
Belarus
Minsk
L. A. Vlasukova
Belarus
Minsk
I. N. Parkhomenko
Belarus
Minsk
O. V. Milchanin
Belarus
Minsk
References
1. A. J. Said, D. Recht, J. T. Sullivan, J. M. Warrender, T. Buonassisi, P. D. Persans, M. J. Aziz. Appl. Phys. Lett., 99, N 7 (2011) 073503
2. J. M. Warrender. Appl. Phys. Rev., 3, N 3 (2016) 031104
3. M. Ju. Sher, E. Garcia-Hemme. Semicond. Sci. Technol., 38 (2023) 033001
4. K. Sánchez, I. Aguilera, P. Palacios, P. Wahnón. Phys. Rev. B, 82 (2010) 165201
5. A. Luque, A. Martí, C. Stanley. Nature Photonics, 6 (2012) 146—152
6. M. Wang, E. García-Hemme, Y. Berencén, R. Hübner, Yu. Xie, L. Rebohle, Ch. Xu, H. Schneider, M. Helm, Sh. Zhou. Adv. Opt. Mater., 9 (2021) 2001546
7. Z. Y. Tong, M. X. Bu, Y. Q. Zhang, D. R. Yang, X. D. Pi. J. Semicond., 43 (2022) 093101
8. F. F. Komarov, G. Ivlev, G. Zayats, A. Komarov, N. Nechaev, I. Parkhomenko, L. Vlasukova, E. Wendler, S. Miskiewicz. Acta Phys. Polonica A, 136 (2019) 254—259
9. F. F. Komarov, N. S. Nechaev, G. D. Ivlev, L. A. Vlasukova, I. N. Parkhomenko, E. Wendler, I. A. Romanov, Y. Berencén, V. V. Pilko, D. V. Zhigulin, A. F. Komarov. Vacuum, 178 (2020) 109434
10. F. F. Komarov, L. A. Vlasukova, O. V. Milchanin, I. N. Parkhomenko, Y. Berencen, A. E. Alzhanova, Ting Wang, J. Zuk. J. Appl. Spectr., 90 (2023) 358—365
11. Y. Berencén, S. Prucnal, F. Liu, I. Skorupa, R. Hübner, L. Rebohle, S. Zhou, H. Schneider, M. Helm, W. Skorupa. Sci. Rep., 7 (2017) 1—9
12. F. Aguirre-Tostado, D. Layton, A. Herrera-Gomez, R. Wallace, J. Zhu, G. Larrieu, E. Maldonado, W. Kirk, M. Tao. J. Appl. Phys., 102 (2007) 084901
13. P. Krüger, J. Pollmann. Phys. Rev. B, 47 (1993) 1898—1910
14. D. Udeshi, M. Y. Ali, M. Tao, E. Maldonado, N. Basit, W. P. Kirk. Int. J. Electron., 92 (2005) 719—727
15. M. Ahmad, S. Al-Hawat, M. Akel. Mater. Res. Express, 6 (2019) 096412
16. M. Hu, T. C. Hauger, B. C. Olsen, E. J. Luber, J. M. Buriak. J. Phys. Chem. C, 122 (2018) 13803—13814
17. A. Taskin, E. Tishkovskii. Semiconductors, 36 (2002) 605—614
18. A. V. Naumkin, A. Kraut-Vass, S. W. Gaarenstroom, C. J. Powell. NIST Standard Reference Database 20, Version 4.1 (2012)
19. D. R. Lide. CRC Handbook of Chemistry and Physics. 81st Edition, Boca Raton, CRC press (2000)
20. R. D. Bringans, Marjorie A. Olmstead. J. Vac. Sci. Technol. B, 7 (1989) 1232—1235
21. T. L. Alford, L. C. Feldman, J. W. Mayer. Fundamentals of Nanoscale Film Analysis, Berlin, Springer Science & Business Media (2007)
22. M. Seah. Surface and Interface Analysis, 2 (1980) 222—239
23. M. Mayer. SIMNRA User’s Guide, Garching, Max-Planck-Institut für Physik (1997) [24] V. D. Phu, L. H. Khiem, A. P. Kobzev, M. Kulik. Commun. Phys., 26 (2016) 83—92
Review
For citations:
Komarov F.F., Ting W., Vlasukova L.A., Parkhomenko I.N., Milchanin O.V. X-Ray Photo electron and Rutherford Backscattering Spectroscopy Studies of Silicon Hyperdoped with Selenium. Zhurnal Prikladnoii Spektroskopii. 2024;91(3):436-443. (In Russ.)