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Highly Selective Fluorescent Sensor for Detection of Al3+ Based on Schiff-Base of 2-Hydroxy-1-Naphthaldehyde and 8-Aminoquinoline and Its Applications
Abstract
Aluminum is a widely distributed element and plays an indispensable role in our lives, but excessive intake of Al3+ can cause potential harm to human health. Highly selective methods for the rapid detection of Al3+ are urgently needed. Here, a novel “turn on” fluorescent probe L based on Schiff-base of 2-hydroxy-1- naphthaldehyde and 8-aminoquinoline was obtained in an excellent yield. Probe L presents significant properties such as rapid response, good stability, wide pH range, simple synthetic operation, and provides an efficient strategy for the highly selective detection of Al3+ in an aqueous solution of DMSO/H2O (7:3, v:v). According to Job's curve and fluorescence titration, probe L with Al3+ forms a 2:1 ratio of complex, and the lowest limit of detection is 3.23×10−8 mol/L. The possible combination mode for probe L with Al3+ was proposed by comparison with the changes of 1H NMR and FTIR spectra of L and its complex. In addition, the potent applicants for probe L were also investigated, and indicated that it could conveniently be made into a series of sensor strips and applied to rapidly detect trace Al3+ in traditional Chinese medicine.
Keywords
Supporting agencies: The authors gratefully acknowledge the financial support for this work from the National Natural Science Foundation of China (No. 22104024) and the Innovation and Venture Project of the University Students of Guizhou Province No. 202010672057.
About the Authors
S.-Q. Cai
School of Pharmaceutical Sciences, Guilin Medical University
China
China
Guangxi Guilin
K.-F. Zhang
School of Pharmaceutical Sciences, Guilin Medical University
China
China
Guangxi Guilin
X.-H. Cai
School of Chemical Engineering, Guizhou Minzu University
China
China
Guiyang
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Review
For citations:
Cai S., Zhang K., Cai X. Highly Selective Fluorescent Sensor for Detection of Al3+ Based on Schiff-Base of 2-Hydroxy-1-Naphthaldehyde and 8-Aminoquinoline and Its Applications. Zhurnal Prikladnoii Spektroskopii. 2024;91(3):465.
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