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Fabrication of Tin-Ag@Ag Composite Substrate with SERS Performance and Application in Ibuprofen Detection
Abstract
TiN-Ag@Ag composite substrates were prepared via ammonia reduction nitridation followed by electrochemical deposition. Fabricated TiN-Ag@Ag substrates were characterized using X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, transmission electron microscopy, and ultraviolet-visible spectrophotometry. The surface-enhanced Raman spectroscopy activity of these substrates was evaluated using ibuprofen as the probe molecule. The size of the Ag particles prepared via electrochemical deposition was approximately 1 µm, and Ag nanoparticles with an average particle size of 100 nm were uniformly distributed on the surface of TiN-Ag films. The Raman signal of ibuprofen was significantly enhanced, and the minimum detection concentration of ibuprofen was 10–5 M. The mechanism by which the TiN-Ag@Ag composite substrate enhanced the Raman signals was analyzed using ultraviolet photoelectron spectroscopy and density functional theory implemented in the Gaussian software. Overall, charge transfer and the local electromagnetic field effect enhanced the Raman signals of ibuprofen.
Supporting agencies: The work was supported by Hebei Natural Science Foundation (No. H2022209066), Science and Technology Project of Hebei Education Department (No. JQN2022015), Hebei Key Laboratory of Hazardous Chemicals Safety and Control Technology (No. 20211204-5), and Tangshan Talent Funding Program (No. A202202013). We thank Liwen Bianji (Edanz) (www.liwenbianji.cn) for editing the language of a draft of this manuscript.
About the Authors
Z. Zheng
College of Pharmacy, North China University of Science and Technology
China
China
Zhiheng Zheng
Tangshan, Hebei
F. Zhang
College of Material Science and Engineering, North China University of Science and Technology
China
China
Fan Zhang
Tangshan, Hebei
Y. Liu
Institute of Oncology, Tangshan People's Hospital
China
China
Yankun Liu
Tangshan, Hebei
Z. Wang
Institute of Oncology, Tangshan People's Hospital
China
China
Zhiwu Wang
Tangshan, Hebei
Y. Pei
College of Pharmacy, North China University of Science and Technology
China
China
Yuan Pei
Tangshan, Hebei
Z. Wu
College of Pharmacy, North China University of Science and Technology
China
China
Zhengang Wu
Tangshan, Hebei
B. Li
North China Institute of Science and Technology
China
China
Bo Li, Key Laboratory of Safety and Control Technology of Hazardous Chemicals in Hebei Province
Langfang, Hebei
Y. Wei
College of Material Science and Engineering, North China University of Science and Technology
China
China
Yingna Wei
Tangshan, Hebei
Y. Chen
Analytical Testing Center, North China University of Science and Technology
China
China
Ying Chen
Tangshan, Hebei
H. Wei
College of Material Science and Engineering, North China University of Science and Technology
China
China
Hengyong Wei
Tangshan, Hebei
J. Li
Institute of Oncology, Tangshan People's Hospital
China
China
Jingwu Li
Tangshan, Hebei
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Review
For citations:
Zheng Z., Zhang F., Liu Y., Wang Z., Pei Y., Wu Z., Li B., Wei Y., Chen Y., Wei H., Li J. Fabrication of Tin-Ag@Ag Composite Substrate with SERS Performance and Application in Ibuprofen Detection. Zhurnal Prikladnoii Spektroskopii. 2024;91(4):610.
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