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Influence of synthesis conditions of perovskite nanocrystals of mixed composition CsPbClxBr3–x on their optical properties
Abstract
The possibility of controlling the position of the luminescence maximum in the region of 440–510 nm of halide perovskite nanocrystals of mixed composition CsPbClxBr3-x by changing the molar ratio of the initial reagents PbBr2:PbCl2 during synthesis, as well as by choosing a solvent for postsynthetic treatment of nanocrystals, has been demonstrated. Using X-ray fluorescence spectroscopy, it was found that the ratio of Br–:Cl– ions in the synthesized nanocrystals is lower than their ratio in the initial reagents. Using the Fourier transform infrared spectroscopy method, it was shown that postsynthetic treatment in acetone, in contrast to the treatment in acetonitrile, promotes the removal of oleylamine, predominantly along with bromide ion, from the surface of nanocrystals, which leads to a shift of the photoluminescence maximum to the short-wave region and a decrease in the quantum yield of photoluminescence. The results are important for the development of new combined luminophores based on perovskite nanocrystals when it is necessary to precisely select their color characteristics.
About the Authors
O. I. Patsinko
B. I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus
Belarus
Belarus
Minsk
O. S. Kulakovich
B. I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus
Belarus
Belarus
Minsk
A. A. Ramanenka
B. I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus
Belarus
Belarus
Minsk
V. P. Kulakovich
BELLIS Testing and Certification of Home Appliances and Industrial Products, JSC
Belarus
Belarus
Minsk
S. V. Gaponenko
B. I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus
Belarus
Belarus
Minsk
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Review
For citations:
Patsinko O.I., Kulakovich O.S., Ramanenka A.A., Kulakovich V.P., Gaponenko S.V. Influence of synthesis conditions of perovskite nanocrystals of mixed composition CsPbClxBr3–x on their optical properties. Zhurnal Prikladnoii Spektroskopii. 2024;91(6):842-848. (In Russ.)
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