|Generate QR code
Open Access
Subscription Access
Influence of synthesis conditions of perovskite nanocrystals of mixed composition CsPbClxBr3–x on their optical properties
Abstract
The possibility of controlling the position of the luminescence maximum in the region of 440–510 nm of halide perovskite nanocrystals of mixed composition CsPbClxBr3-x by changing the molar ratio of the initial reagents PbBr2:PbCl2 during synthesis, as well as by choosing a solvent for postsynthetic treatment of nanocrystals, has been demonstrated. Using X-ray fluorescence spectroscopy, it was found that the ratio of Br–:Cl– ions in the synthesized nanocrystals is lower than their ratio in the initial reagents. Using the Fourier transform infrared spectroscopy method, it was shown that postsynthetic treatment in acetone, in contrast to the treatment in acetonitrile, promotes the removal of oleylamine, predominantly along with bromide ion, from the surface of nanocrystals, which leads to a shift of the photoluminescence maximum to the short-wave region and a decrease in the quantum yield of photoluminescence. The results are important for the development of new combined luminophores based on perovskite nanocrystals when it is necessary to precisely select their color characteristics.
About the Authors
O. I. Patsinko
B. I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus
Belarus
Belarus
Minsk
O. S. Kulakovich
B. I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus
Belarus
Belarus
Minsk
A. A. Ramanenka
B. I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus
Belarus
Belarus
Minsk
V. P. Kulakovich
BELLIS Testing and Certification of Home Appliances and Industrial Products, JSC
Belarus
Belarus
Minsk
S. V. Gaponenko
B. I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus
Belarus
Belarus
Minsk
References
1. F. Li, S. Zhou, J. Yuan, C. Qin, Y. Yang, J. Shi, X. Ling, Y. Li, W. Ma. ACS Energy Lett., 4, N 11 (2019) 2571—2578
2. W. Yang, S. Jo, Y. Tang, J. Park, S. G. Ji, S. H. Cho, Y. Hong, D. Kim, J. Park, E. Yoon, H. Zhou, S. Woo, H. Kim, H. J. Yun, Y. S. Lee, J. Y. Kim, B. Hu, T. Lee. Adv. Mater., 35, N 39 (2023) 2304533
3. Y.-H. Suh, T. Kim, J. W. Choi, C.-L. Lee, J. Park. ACS Appl. Nano Mater., 1, N 2 (2018) 488—496
4. M. Chen, Y. Zou, L. Wu, Q. Pan, D. Yang, H. Hu, Y. Tan, Q. Zhong, Y. Xu, H. Liu, B. Sun, Q. Zhang. Adv. Funct. Mater., 27, N 23 (2017) 1701121
5. C. Chen, D. Li, Y. Wu, C. Chen, Z.-G. Zhu, W. Y. Shih, W.-H. Shih. Nanotechnology, 31, N 22 (2020) 225602
6. J. Song, J. Li, X. Li, L. Xu, Y. Dong, H. Zeng. Adv. Mater., 27, N 44 (2015) 7162—7167
7. D. Chen, X. Chen. J. Mater. Chem. C, 7, N 6 (2019) 1413—1446
8. V. Naresh, B. H. Kim, N. Lee. Nano Res., 14, N 4 (2021) 1187—1194
9. S. Wang, Y. Wang, Y. Zhang, X. Zhang, X. Shen, X. Zhuang, P. Lu, W. W. Yu, S. V. Kershaw, A. L. Rogach. J. Phys. Chem. Lett., 10, N 1 (2019) 90—96
10. S. Paul, T. Ahmed, S. Das, A. Samanta. J. Phys. Chem. C, 125, N 42 (2021) 23539—23547
11. B. Wang, H. Lin, J. Xu, H. Chen, Y. Wang. ACS Appl. Mater. Interfaces, 6, N 24 (2014) 22905—22913
12. C. Wang, D. Han, J. Wang, Y. Yang, X. Liu, S. Huang, X. Zhang, S. Chang, K. Wu, H. Zhong. Nat. Commun., 11, N 1 (2020) 6428
13. G. H. Ahmed, J. K. El-Demellawi, J. Yin, J. Pan, D. B. Velusamy, M. N. Hedhili, E. Alarousu, O. M. Bakr, H. N. Alshareef, O. F. Mohammed. ACS Energy Lett., 3, N 10 (2018) 2301—2307
14. T. Ahmed, S. Seth, A. Samanta. Chem. Mater., 30, N 11 (2018) 3633—3637
15. A. Hong, J. Kim, J. Kwak. Adv. Opt. Mater., 8, N 22 (2020) 2001051
16. О. И. Пацинко, А. А. Романенко, В. В. Крюков, Л. Л. Троцюк, О. С. Кулакович, С. В. Гапоненко. Журн. прикл. спектр., 90, N 1 (2023) 61—66 [O. I. Patsinko, A. A. Ramanenka, V. V. Krukov, L. L. Trotsiuk, O. S. Kulakovich, S. V. Gaponenko. J. Appl. Spectr., 90, N 1 (2023) 54—59]
17. S. Westland. J. Esthet. Restor. Dent., 15 (2003) s5—s12
18. J. Zhou, F. Huang, H. Lin, Z. Lin, J. Xu, Y. Wang. J. Mater. Chem. C, 4, N 32 (2016) 7601—7606
19. X. He, T. Li, Z. Liang, R. Liu, X. Ran, X. Wang, L. Guo, C. Pan. Adv. Opt. Mater. (2024) 2302726
20. W. Chung, K. Park, H. J. Yu, J. Kim, B.-H. Chun, S. H. Kim. Opt. Mater., 32, N 4 (2010) 515—521
21. Л. Л. Троцюк, Е. С. Тон, В. И. Цвирко, Л. Н. Сурвилло, С. И. Лишик, О. С. Кулакович, А. А. Романенко, В. В. Крюков, Ю. В. Трофимов, С. В. Гапоненко. Журн. прикл. спектр., 89, № 5 (2022) 662—667 [L. L. Trotsiuk, E. S. Ton, V. I. Tsvirka, L. N. Survilo, S. I. Lishik, O. S. Kulakovich, A. A. Ramanenka, V. V. Krukov, Yu. V. Trofimov, S. V. Gaponenko. J. Appl. Spectr., 89, N 5 (2022) 869—873]
22. L. Protesescu, S. Yakunin, M. I. Bodnarchuk, F. Krieg, R. Caputo, C. H. Hendon, R. X. Yang, A. Walsh, M. V. Kovalenko. Nano Lett., 15, N 6 (2015) 3692—3696
23. M. V. Kovalenko, L. Protesescu, M. I. Bodnarchuk. Science, 358, N 6364 (2017) 745—750
24. Q. A. Akkerman, V. D’Innocenzo, S. Accornero, A. Scarpellini, A. Petrozza, M. Prato, L. Manna. J. Am. Chem. Soc., 137, N 32 (2015) 10276—10281
25. R. Ahumada-Lazo, J. A. Alanis, P. Parkinson, D. J. Binks, S. J. O. Hardman, J. T. Griffiths, F. Wisnivesky Rocca Rivarola, C. J. Humphrey, C. Ducati, N. J. L. K. Davis. J. Phys. Chem. C, 123, N 4 (2019) 2651—2657
26. Y. Xu, S. Lou, C. Xia, T. Xuan, H. Li. J. Lumin., 222 (2020) 117132
27. G. Nedelcu, L. Protesescu, S. Yakunin, M. I. Bodnarchuk, M. J. Grotevent, M. V. Kovalenko. Nano Lett., 15, N 8 (2015) 5635—5640
28. R. K. Gautam, S. Das, A. Samanta. ChemNanoMat, 8, N 4 (2022) e202200029
29. https://next-gen.materialsproject.org/materials/mp-23037?chemsys=Cs-Pb-Cl#related_materials, время доступа 06.03.2024.
30. https://next-gen.materialsproject.org/materials/mp-600089?chemsys=Cs-Pb-Br, время доступа 06.03.2024
31. J. Ye, Z. Li, D. J. Kubicki, Y. Zhang, L. Dai, C. Otero-Martínez, M. A. Reus, R. Arul, K. R. Dudipala, Z. Andaji-Garmaroudi, Y.-T. Huang, Z. Li, Z. Chen, P. Müller-Buschbaum, H.-L. Yip, S. D. Stranks, C. P. Grey, J. J. Baumberg, N. C. Greenham, L. Polavarapu, A. Rao, R. L. Z. Hoye. J. Am. Chem. Soc., 144, N 27 (2022) 12102—12115
32. Y. Zhang, T. D. Siegler, C. J. Thomas, M. K. Abney, T. Shah, A. De Gorostiza, R. M. Greene, B. A. Korgel. Chem. Mater., 32, N 13 (2020) 5410—5423
33. L. Yuan, R. Patterson, X. Wen, Z. Zhang, G. Conibeer, S. Huang. J. Colloid Interface Sci., 504 (2017) 586—592
34. Y. Kim, E. Yassitepe, O. Voznyy, R. Comin, G. Walters, X. Gong, P. Kanjanaboos, A. F. Nogueira, E. H. Sargent. ACS Appl. Mater. Interfaces, 7, N 45 (2015) 25007—25013
35. H. Zhang, C. Sun, J. Han, J. Tao, C. Fan, X. Liu, W. Bi. J. Lumin., 250 (2022) 119060
36. J. Khan, I. Ullah, J. Yuan. Mater. Adv., 3, N 4 (2022) 1931—1952
37. H. Liu, X. Xiao, Y. Wu, D. Zhu, J. Sun, D. Chen, B. Tang, S. Wang, A. Portniagin, K. Vighnesh, W. C. H. Choy, A. L. Rogach. Mater. Today Energy (2024) 101533
38. R. Grisorio, M. E. Di Clemente, E. Fanizza, I. Allegretta, D. Altamura, M. Striccoli, R. Terzano, C. Giannini, M. Irimia-Vladu, G. P. Suranna. Nanoscale, 11, N 3 (2019) 986—999
39. A. Pan, B. He, X. Fan, Z. Liu, J. J. Urban, A. P. Alivisatos, L. He, Y. Liu. ACS Nano, 10, N 8 (2016) 7943—7954
40. L. He, S. Pan, Z. Lin, J. Peng. ACS Appl. Nano Mater., 2, N 12 (2019) 7910—7915
41. B. Pradhan, A. Mushtaq, D. Roy, S. Sain, B. Das, U. K. Ghorai, S. K. Pal, S. Acharya. J. Phys. Chem. Lett., 10, N 8 (2019) 1805—1812
42. Б. Н. Тарасевич. ИК спектры основных классов органических соединений, Москва, МГУ (2012)
43. И. А. Шуклов, В. Ф. Токнова, Д. В. Демкин, Г. И. Лапушкин, Л. М. Николенко, А. А. Лизунова, С. Б. Бричкин, В. Н. Василец, В. Ф. Разумов. ХВЭ, 54, N 3 (2020) 200—205
44. D. P. Nenon, K. Pressler, J. Kang, B. A. Koscher, J. H. Olshansky, W. T. Osowiecki, M. A. Koc, L.-W. Wang, A. P. Alivisatos. J. Am. Chem. Soc., 140, N 50 (2018) 17760—17772
Review
For citations:
Patsinko O.I., Kulakovich O.S., Ramanenka A.A., Kulakovich V.P., Gaponenko S.V. Influence of synthesis conditions of perovskite nanocrystals of mixed composition CsPbClxBr3–x on their optical properties. Zhurnal Prikladnoii Spektroskopii. 2024;91(6):842-848. (In Russ.)
Views: 100
Email this article 