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Raman Spectroscopy of Multilayer Graphene Structures with Different Twist Angles Between Layers
Abstract
Graphene samples with a different number of layers and their relative rotation in graphene plane were obtained by chemical vapor deposition on a copper catalyst. The properties of the obtained graphene structures have been revealed by Raman spectroscopy. The position and form of the main peaks change depending on the number of layers and their rotation, which indicates a change in the nature of interaction between the layers. Additional peaks have been studied depending on the value of the angle of graphene layers rotation. Determining the distinctive characteristics of the studied twisted structures is a necessary step in optimizing the scalable process of synthesis and production of graphene-based nanoelectronic devices.
About the Authors
D. P. Borisenko
Institute for Nanoengineering in Electronics, Spintronics and Photonics, National Research Nuclear University “MEPhI”
Russian Federation
Russian Federation
Moscow
N. I. Kargin
Institute for Nanoengineering in Electronics, Spintronics and Photonics, National Research Nuclear University “MEPhI”
Russian Federation
Russian Federation
Moscow
M. G. Rybin
LCC RUSGRAPHENE
Russian Federation
Russian Federation
Serpukhov
References
1. A. Geim, K. Novoselov. Nature Mater., 6 (2007) 183—191
2. A. K. Geim. Science, 324, N 5934 (2009) 1530—1534
3. R. M. Westervelt. Science, 320, N 5874 (2008) 324—325
4. F. Bonaccorso, Z. Sun, T. Hasan, A. C. Ferrari. Nature Photon., 4, N 9 (2010) 611—622
5. D. P. Borisenko, A. S. Gusev, N. I. Kargin, P. L. Dobrokhotov, A. A. Timofeev, V. A. Labunov, M. M. Mikhalik, K. P. Katin, M. M. Maslov, P. S. Dzhumaev. Appl. Sci., 12 (2022) 11516
6. M. Losurdo, M. M. Giangregorio, P. Capezzuto, G. Bruno. Phys. Chem. Chem. Phys., 13, N 46 (2011) 20836
7. F. Kiani, Z. Razzaghi, B. Ghadiani, M. Tamizifar, M. H. Mohmmadi, A. Simchi. Ceram. Int., 43, N 17 (2017) 15010—15017
8. H. C. Lee, W.-W. Liu, S.-P. Chai, A. R. Mohamed, A. Aziz, C.-S. Khe, U. Hashim. RSC Adv., 7, N 26 (2017) 15644—15693
9. H. C. Hong, J. I. Ryu, H. C. Lee. Nanomaterials, 13, N 15 (2023) 2217
10. Y. Shan, Y. Li, D. Huang, Q. Tong, W. Yao, W.-T. Liu, S. Wu. Sci. Adv., 4, N 6 (2018) eaat0074
11. C. Zhiying, S. Yanping, Li Jing, He Kang, Shuang Wang, Sunwen Zhao, Xiuli Gao, Songang Peng, Zhi Jin, Xinyu Liu, Zh. Yanhui, Guanghui Yu. Carbon, 172 (2021) 480—487
12. C. Yelgel. J. Physics: Conf. Ser., 707 (2016) 012022
13. M. Wang, W. Shan, H. Wang. Phys. Status Solidi (b) (2023) 260
14. P. Novelli, I. Torre, F. H. L. Koppens, F. Taddei, M. Polini. Phys. Rev. B, 102, N 12 (2020)
15. Z. Hennighausen, S. Kar. Electron. Struct., 3 (2021) 014004
16. Giorgio Di Battista, K. Fong, A. Diez-Carlon, K. Watanabe. Sci. Adv., 10, N 38 (2024)
17. H. Agarwal, K. Nowakowski, A. Forrer. Nat. Photon., 17 (2023) 1047—1053
18. K. Kim, S. Coh, L. Z. Tan, W. Regan, J. M. Yuk, E. Chatterjee, A. Zettl. Phys. Rev. Lett., 108, N 24 (2012)
19. Anna K. Ott, Andrea C. Ferrari. Raman Spectroscopy of Graphene and Related Materials, Academic Press (2024) 233—247
20. A. Jorio. ISRN Nanotechnology, 8, N 8 (2012) 1—16
21. C. Cong, T. Yu, H. Wang. ACS Nano, 4, N 6 (2010) 3175—3180
22. F. Herziger, C. Tyborski, O. Ochedowski, M. Schleberger, J. Maultzsch. Phys. Rev. B, 90, N 24 (2014)
23. Z. Luo, C. Cong, J. Zhang, Q. Xiong, T. Yu. Carbon, 50, N 11 (2012) 4252—4258
24. J. S. Park, A. Reina, R. Saito, J. Kong, G. Dresselhaus, M. S. Dresselhaus. Carbon, 47, N 5 (2009) 1303—1310
25. V. Carozo, C. M. Almeida, E. H. M. Ferreira, L. G. Cançado, C. A. Achete, A. Jorio. Nano Lett., 11, N 11 (2011) 4527—4534
26. P. Ramnani, M. R. Neupane, A. A. Balandin, R. K. Lake, A. Mulchandani. Carbon, 123 (2017) 302—306
27. M. Long, A. Jimeno-Pozo, H. Sainz-Cruz, P. A. Pantaleón, F. Guinea. Proc. Natl. Acad. Sci., 121, N 32 (2024) e2405259121
28. Y. Cao, V. Fatemi, S. Fang, K. Watanabe, T. Taniguchi, E. Kaxiras, P. Jarillo-Herrero. Nature, 556, N 7699 (2018) 43—50
29. J. Yin, H. Wang, H. Peng, H. Nat. Commun., 7 (2016) 10699
30. K. Xin, X. Wang, K. Grove-Rasmussen, Z. Wei. J. Semicond., 43 (2022) 011001
31. O. V. Kononenko, M. Brzhezinskaya, A. O. Zotov, V. I. Korepanov, V. Levashov, V. Matveev, D. Roshchupkin. Carbon, 194 (2022) 52—61
32. M. G. Rybin, E. A. Guberna, E. A. Obraztsova, I. Kondrashov, I. I. Kurkina, S. A. Smagulova, E. D. Obraztsova. Carbon Trends, 15 (2024) 100349
33. Z. Liu, S. P. Lau, F. Yan. Chem. Soc. Rev., 44, N 15 (2015) 5638—5679
34. M. V. O. Moutinho, G. S. N. Eliel, A. Righi. Sci. Rep., 11 (2021) 17206
35. U. Mogera, G. U. Kulkarni. Carbon, 156 (2020) 470—487
36. G. S. N. Eliel, M. V. O. Moutinho, A. C. Gadelha. Nat. Commun., 9 (2018) 1221
37. C. Cong, T. Yu, R. Saito, G. F. Dresselhaus, M. S. Dresselhaus. ACS Nano, 5, N 3 (2011) 1600—1605
38. A. Niilisk, J. Kozlova, H. Alles, J. Aarik, V. Sammelselg. Carbon, 98 (2016) 658—665
39. Z. Tan, S. Han, J. Jia, M. Zhu, H. Xu, S. Mi, K. Li, L. Wang, Z. Cheng, S. Chen. ACS Appl. Mater Interfaces, 16, N 8 (2024) 10867—10876
40. V. Carozo, C. M. Almeida, B. Fragneaud, P. M. Bedê, M. V. O. Moutinho, J. Ribeiro-Soares, L. G. Cançado. Phys. Rev. B, 88, N 8 (2013)
Supplementary files
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For citations:
Borisenko D.P., Kargin N.I., Rybin M.G. Raman Spectroscopy of Multilayer Graphene Structures with Different Twist Angles Between Layers. Zhurnal Prikladnoii Spektroskopii. 2025;92(4):484-491. (In Russ.)
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