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MAX-PHASE STRUCTURE FORMATION IN COATING AND BULK MATERIAL Ti–Al–N AT HIGH-TEMPERATURE ANNEALING IN VACUUM
Abstract
A comparative study of the structural and phase state of Ti–Al–N systems obtained in the form of a coating and a bulk material is carried out. The methods of X-ray diffraction, energy-dispersive spectroscopy (EDS) and Raman spectroscopy (RS) are used to characterize the structure. The use of EDS and RS makes it possible to verify the X-ray diffraction data on the phase composition of the samples, which is especially important in the study of multiphase Ti–Al–N coatings, and to identify the features of the surface microstructure of the coating. The Ti–Al–N coating is obtained by chemical deposition of Ti and Al in an N2 atmosphere on a Ti substrate with subsequent annealing in vacuum at 700, 800, 900 and 1000 ºС. The bulk Ti–Al– N sample is obtained by reaction sintering of Ti, Al, TiN powders in vacuum at 1200 and 1300ºС. Ti2AlN MAX phase appears in the coating at a lower temperature than in the bulk sample and is characterized by lower thermal stability. Ti–Al–N coating is characterized by a greater multiphase nature; after annealing in vacuum at 900 ºС, the following phases are registered in it: Ti2AlN, Ti4AlN3, TiN, Ti2N, AlN. The destruction of the MAX phase structure occurs at 1000 ºС. In the bulk sample after annealing in vacuum at 1300ºС, the main phase is Ti2AlN with a small admixture of TiN and TiAl, the destruction of the Ti2AlN MAX phase occurs at 1400 ºС.
About the Authors
E. A. Ovodok
Research Institute for Physical Chemical Problems of the Belarusian State University
Belarus
Belarus
Minsk
M. I. Ivanovskaya
Research Institute for Physical Chemical Problems of the Belarusian State University
Belarus
Belarus
Minsk
A. E. Seleznev
Moscow State Technological University “STANKIN”
Russian Federation
Russian Federation
Moscow
S. V. Zlotsky
Belarusian State University
Belarus
Belarus
Minsk
V. V. Uglov
Belarusian State University
Belarus
Belarus
Minsk
E. Sotova
Moscow State Technological University “STANKIN”
Russian Federation
Russian Federation
Moscow
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Review
For citations:
Ovodok E.A., Ivanovskaya M.I., Seleznev A.E., Zlotsky S.V., Uglov V.V., Sotova E. MAX-PHASE STRUCTURE FORMATION IN COATING AND BULK MATERIAL Ti–Al–N AT HIGH-TEMPERATURE ANNEALING IN VACUUM. Zhurnal Prikladnoii Spektroskopii. 2025;92(1):70-78. (In Russ.)
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