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Spectrophotometric Determination of Component Concentrations in a Light-Scattering Mixture
Abstract
Method for determining the concentrations of mixture components from their optical absorption spectra in the presence of Rayleigh scattering is proposed. The differential evolution method was used to calculate the concentrations of components. It was used to minimize the difference between experimental and calculated spectra. To demonstrate the performance of the method, the concentrations of the components of the model mixture were determined from its optical absorption spectrum. This model mixture included five azo dyes with significantly overlapping absorption spectra and a noticeable light scattering contribution. The influence of the absorption spectrum errors on the errors of component concentrations was evaluated. Without light scattering both the multiple linear regression method and the method of differential evolution give the results of determination of the component concentrations coinciding within the measurement accuracy. It is reasonable to use the method of differential evolution for spectrophotometric determination of the concentrations of mixture components in the presence of light scattering.
About the Authors
V. S. Kozlovsky
A.N. Belozersky Research Institute of Physico-Chemical Biology, Lomonosov Moscow State University
Russian Federation
Russian Federation
Moscow
A. P. Razjivin
A.N. Belozersky Research Institute of Physico-Chemical Biology, Lomonosov Moscow State University
Russian Federation
Russian Federation
Moscow
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Review
For citations:
Kozlovsky V.S., Razjivin A.P. Spectrophotometric Determination of Component Concentrations in a Light-Scattering Mixture. Zhurnal Prikladnoii Spektroskopii. 2025;92(3):303-310. (In Russ.)
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