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Changes of Thickness and Optical Constants of Boron Oxide Films During Heating on Air
Abstract
The thickness and optical constants changes of boron oxide films deposited on substrates of sapphire glass, sitall, and polycrystalline massive aluminum were studied directly during heating on air in the temperature range of 24–700°C using single-wave and spectral ellipsometry methods. The high hygroscopicity of these films was demonstrated, which decreases upon their preliminary annealing. It was shown that a continuous decrease of the film thickness occurs in the studied temperature range. In the temperature range up to 300°C, it is due to dehydration processes. At higher temperatures, the decrease in the film thickness is explained by the slow evaporation of boric acid formed in the film. It was shown that the deposition of a boron oxide film on the aluminum surface does not affect the rate of its oxidation.
About the Authors
L. A. Akashev
Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences
Russian Federation
Russian Federation
Ekaterinburg
N. A. Popov
Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences
Russian Federation
Russian Federation
Ekaterinburg
V. G. Shevchenko
Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences
Russian Federation
Russian Federation
Ekaterinburg
E. V. Spesivtsev
A.V. Rzhanov Institute of Semiconductor Physics, Siberian Branch of RAS
Russian Federation
Russian Federation
Novosibirsk
O. G. Reznitskih
Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences
Russian Federation
Russian Federation
Ekaterinburg
References
1. Г. В. Самсонов. Физико-химические свойства окислов. Справочник, Москва, Металлургия (1978)
2. Р. А. Лидин, В. А. Молочко, Л. Л. Андреева. Химические свойства неорганических веществ: уч. пособие для вузов, 3-е изд., испр., Москва, Химия (2000)
3. А. Н. Пивкина, Д. Б. Мееров, К. А. Моногаров, Ю.В. Фролов, Н.В. Муравьёв. Физика горения и взрыва, 56, № 2 (2020) 28—35, https://sibran.ru/journals/issue.php?ID=178481&ARTICLE_ID=178486
4. H. F. Rizzo. Boron Synthesis, Structure, and Properties, Springer, Boston, MA (1960) 175—189, doi: 10.1007/978-1-4899-6572-1_21
5. B. Natan, A. Gany. J. Propulsion, 7, N 1 (1991) 37—43, doi: 10.2514/3.23291
6. M. K. King. Comb. Sci. and Technology, 8, N 5-6 (1973) 255—273, doi: 10.1080/00102207308946648
7. G. Mohan, F. A. Williams. AIAA J., 10, N 6 (1972) 776—783, doi: 10.2514/3.50210
8. Y. Sun, K.-L. Chintersingh, M. Schoenitz, E. L. Dreizin. J. Phys. Chem. C, 123 (2019) 11807— 11813, doi: 10.1021/acs.jpcc.9b03363
9. B. Hussmann, M. Pfitzner. Comb. and Flame, 157 (2010) 803—821, doi: 10.1016/j.combustflame.2009.12.010
10. W. Yang, W. Ao, J. Zhou J. Liu, K. Cen, Y. Wang. J. Propulsion and Power, 29, N 5 (2013) 1207—1203, doi: 10.2514/1.B34785
11. А. П. Чижиков. СВС-экструзия оксидной керамики, дисперсно-упрочненной частицами боридов и карбидов, дис. … канд. тех. наук. ФГБУН Ин-т структурной макрокинетики и проблем материаловедения им. А. Г. Мержанова РАН, Черноголовка (2019) 87—96
12. M. Arık, C. Yıldırım, N. Solak. Solid State Sci., 146 (2023) 107367, doi: 10.1016/j.solidstatesciences.2023.107367
13. A. Jain, S. Anthonysamy. J. Therm. Anal. Calorim., 122 (2015) 645—652, doi: 10.1007/s10973-0154818-3
14. B. Chen, Z. Xia, L. Huang, J. Hu. Fuel Proc. Technol., 165 (2017) 34—43, doi: 10.1016/j.fuproc.2017.05.008
15. C. L. Yeh, K. K. Kuo. Prog. Energy and Comb. Science, 22 (1996) 511—541
16. Д. Майнкён. Физика горения и взрыва, 42, 2 (2006) 39—52
17. L. A. Akashev, N. A. Popov, Yu. V. Korkh, T. V. Kuznetsova, V. G. Shevchenko, L. Yu. Buldakova. Russ. J. Phys. Chem. A, 98, N 6 (2024) 181—187, https://link.springer.com/article/10.1134/S0036024424700225
18. R. A. Smith, R. B. McBoom. Kirk-Othmer Encyclopedia of Chemical Technology, 4th ed., 4, Hoboken, N. J., Wiley-Interscience (2001) 191
19. А. С. Пайвин. Матер. конф. ВНКСФ-18, Красноярск, АСФ России (2012) 356—357, http://asf.ural.ru/VNKSF/Tezis/v18/VNKSF-18-09.pdf
20. W. Zhang, S. Sun, J. Xu, Z. Chen. Asian J. Chemistry, 27, N 3 (2015) 1001—1004, doi: 10.14233/ajchem.2015.17856
21. С. Feldman. Anal. Chem., 33, N 13 (1961) 1916—1920, https://link.springer.com/chapter/10.1007/978-14684-7621-7_25
22. А. А. Немодрук, 3. К. Каралова. Аналитическая химия бора, Москва, Наука (1964) 17
23. J. Gaillardet, D. Lemarchand, C. Göpel, G. Manhès. J. Geostandarts and Geoanalysis, 25, N 1 (2001) 67—75, https://onlinelibrary.wiley.com/doi/10.1111/j.1751-908X.2001.tb00788.x
24. A. Alpatova, A. Alsaadi, N. Ghaffour. J. Hazard. Mater., 351 (2018) 224—231, https://pubmed.ncbi.nlm.nih.gov/29550556/
25. V. Brandani, G. Del Re, G. Di Giacomo. J. Sol. Chem., 17, N 5 (1988) 429—434, https://link.springer.com/article/10.1007/BF00647310
26. C. Huber, S, Setoodeh, F. Birkelbach, J. Weber, C. Jordan, M. Schreiner, M. Harasek, F. Winter. Energy Sci. and Eng., 8, N 5 (2020) 1650—1666, https://repositum.tuwien.at/bitstream/20.500.12708/20188/1/Huber-2020-Energy%20Science%20and%20Engineering-vor.pdf
27. S. Aghili, M. Panjepour, M. Meratian. J. Therm. Anal. Calorim., 131 (2018) 2443—2455
28. R. Balasubramanian, T. S. Lakshmi Narasimhan, R. Viswanathan, S. Nalini. J. Phys. Chem. B, 112 (2008) 13873—13884, doi: 10.1021/jp8058883
29. A. D. Rakić. Appl. Opt., 34 (1995) 4755—4767, https://opg.optica.org/ao/abstract.cfm?uri=ao-34-22-4755
30. Л. А. Акашев, Н. А. Попов, М. В. Кузнецов, В. Г. Шевченко. Журн. физ. химии, 89, № 5 (2015) 287—291, https://link.springer.com/article/10.1134/S0036024415050027
31. Л. А. Акашев, Н. А. Попов, Ю. М. Ярмошенко, А. В. Дружинин, В. Г. Шевченко. Журн. прикл. химии, 88, № 12 (2015) 1665—1671, https://link.springer.com/article/10.1134/S10704272150120010
32. В. Г. Шевченко, Д. А. Еселевич, Н. А. Попов, В. Н. Красильников, З. С. Винокуров, А. И. Анчаров, Б. П. Толочко. Физика горения и взрыва, 54, № 1 (2018) 65—71, https://www.sibran.ru/upload/iblock/75e/75e1b36949af80c8244fdddd9955ba+19.pdf
Review
For citations:
Akashev L.A., Popov N.A., Shevchenko V.G., Spesivtsev E.V., Reznitskih O.G. Changes of Thickness and Optical Constants of Boron Oxide Films During Heating on Air. Zhurnal Prikladnoii Spektroskopii. 2025;92(3):318-325. (In Russ.)
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