Preview

Zhurnal Prikladnoii Spektroskopii

Advanced search
Open Access Open Access  Restricted Access Subscription Access

Photoluminescence Studies on Tb3+ Doped Li4Zn(PO4)2 Phosphors

Abstract

Novel Li4Zn(PO4)2:Tb3+ green-light-emitting phosphors were synthesized using the combustion process. A thorough investigation was done on the crystal phase, shape, morphology and luminescence properties, including decay curves. With the P21(4) space group, the Li4Zn(PO4)2:Tb3+ phosphors showed a monoclinic structure. It was calculated that the average crystal size was about 80 nm. Under excitation at 250 nm, a strong green emission peak at 545 nm attributed to 5D47F5 transition was observed in the present host. It was found that the emission intensity depended on the dopant concentration.

About the Authors

A. Naveen
Koneru Lakshmaiah Education Foundation (Deemed to be University); Chaitanya (Deemed to be University)
India

Akinapally Naveen - Department of Engineering Physics, Koneru Lakshmaiah Education Foundation (Deemed to be University); Department of Physics & Electronics, Chaitanya (Deemed to be University)

Guntur, A. P.; Telangana



M. Venkateswarlu
Koneru Lakshmaiah Education Foundation (Deemed to be University)
India

Department of Engineering Physics.

Guntur, A. P.



M. V.V.K. Srinivas Prasad
Koneru Lakshmaiah Education Foundation (Deemed to be University)
India

Department of Engineering Physics.

Guntur, A. P.



P. Tejeswara Rao
GITAM (Deemed to Be) University
India

Department of Physics, GITAM School of Science.

Andhra Pradesh, Visakhapatnam



N. Chandana
B.R. Ambedkar Open University
India

Department of Physics.

Hyderabad



M. Ravi
Government Polytechnic College
India

Kothagudem, Telangana



G. Giridhar
Acharya Nagarjuna University
India

Department of Nanotechnology.

A. P.



References

1. L. Li, X. Tang, Z. Wu, Y. Zheng, S. Jiang, X. Tang, G. Xiang, X. Zhou, J. Alloys and Compd., 780, 266 (2019).

2. S. Li, N. Guo, Q. Liang, Y. Ding, H. Zhou, R. Ouyang, W. Lü, Spectrochim. Acta A: Mol. and Biomolec. Spectroscopy, 190, 246 (2018).

3. K. Munirathnam, D. Prakashbabu, Optik-International J. Light and Electron Optics, 140, 32 (2017).

4. A. Naveen, M. Venkateswarlu, M. V. V. K. Srinivas Prasad, M. Syamsundar, G. Giridhar, Russ. Phys. J., 68, 142 (2025).

5. G. E. Barasch, G. H. Dieke, J. Chem. Phys., 43, 988 (1965).

6. W. T. Carnall, Handbook on the Physics and Chemistry of Rare Earths, 3, North-Holland, Netherlands, 171 (1979).

7. J. Juarez-Batalla, A. N. Meza-Rocha, U. Caldiño, Opt. Mater., 64, 33 (2017).

8. M. R. Dousti, R. J. Amjad, J. Non-Crystal. Solids, 420, 21 (2015).

9. U. Caldiño, I. Camarillo, A. Speghini, M. Bettinelli, J. Lumin., 161, 142 (2015).

10. D. Ehrt, IOP Conference Series: Materials Science and Engineering, 2 (2009).

11. K. Park, H. Kim, D. A. Hakeem, Ceram. Int., 42, 10526 (2016).

12. V. Singh, S. Watanabe, T. K. G. Rao, K. Al-Shamery, M. Haase, Y.-D. Jho, J. Lumin., 132, 2036 (2012).

13. D. Sztolberg, B. Brzostowski, P. J. Dereń, Opt. Mater., 78, 292 (2018).

14. F. Wang, H. Song, G. Pan, L. Fan, B. Dong, L. Liu, X. Bai, R. Qin, X. Ren, Z. Zheng, J. Lumin., 128, 2013 (2008).

15. G. E. Malashkevich, G. I. Semkova, O. L. Amelyanovich, T. G. Kochubeyeva, Opt. Appl., 38, 57 (2008).

16. G. E. Malashkevich, G. I. Semkova, A. P. Stupak, A. V. Sukhodolov, Phys. Solid State, 46, 1425 (2004).

17. L. H. Zhang, C. Y. Zhang, Y. B. Zhou, Y. L. Li, Q. L. Peng, J. Appl. Spectrosc., 90, 1346 (2024).

18. C. B. Palan, N. S. Bajaj, A. Soni, S. K. Omanwar, J. Lumin., 176, 106 (2016).

19. B. Yan, X. Su, K. Zhou, Mater. Res. Bull., 41, 134 (2006).

20. S. Zhang, Y. Li, Y. Lv, L. Fan, Y. Hu, M. He, Chem. Eng. J., 322, 314 (2017).

21. K. Shinde, K. N. Dhoble, S. J. Swart, H. C. Park, In: Phosphate Phosphors for Solid-State Lighting, Springer Berlin Heidelberg, Germany, 61 (2012).

22. R. John, R. Rajakumari, Nano-Micro Lett., 4, 65 (2012).

23. S. M. Suryawanshi, K. V. Chandekar, D. S. Badwaik, V. V. Warhate, N. M. Gahane, S. R. Daf, Inorg. Chem. Commun., 156, 111204 (2023).

24. P. Sana, S. Verma, M. M. Malik, Mater. Res. Express, 1, 015027 (2014).

25. A. Shyichuk, S. Lis, Mater. Chem. Phys., 140, 447 (2013).

26. C. R. Kesavulu, A. C. A. Silva, M. R. Dousti, N. O. Dantas, A. S. S. de Camargo, T. Catunda, J. Lumin., 165, 77 (2015).

27. X. Li, Y. Zhang, D. Geng, J. Lian, G. Zhang, Z. Hou, J. Lin, J. Mater. Chem., C2, 9924 (2014).

28. V. Kumar, J. Sharma, V. K. Singh, O. M. Ntwaeaborwa, H. C. Swart, J. Electron Spectroscopy and Related Phenomena, 206, 52 (2016).

29. L. Lin, X. Sun, Y. Jiang, Y. He, Nanoscale, 5, 12518 (2013).

30. N. Rakov, S. A. Vieira, R. B. Guimarães, G. S. Maciel, J. Alloys and Compd., 618, 127 (2015).

31. E. Yildiz, E. Erdoğmuş, G. Annadurai, J. Appl. Spectrosc., 91, 852 (2024).


Review

For citations:


Naveen A., Venkateswarlu M., Srinivas Prasad M.V., Tejeswara Rao P., Chandana N., Ravi M., Giridhar G. Photoluminescence Studies on Tb3+ Doped Li4Zn(PO4)2 Phosphors. Zhurnal Prikladnoii Spektroskopii. 2025;92(4):564.

Views: 66


ISSN 0514-7506 (Print)