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Phosphores- cence of In(III)Cl-Etioporphyrin-I at 298 K
Abstract
Phosphorescence of In(III)Cl-etioporphyrin-I in thin films of polyvinylbutyral was recorded at room temperature and atmospheric conditions. A series of phosphorescence spectra was obtained using the stroboscopic method, on the basis of which the glow duration τР ≈ 42 μs at 298 K was determined. A decrease in τР by almost two orders of magnitude with a change in temperature from 77 to 298 K confirms the quenching effect of atmospheric oxygen in the gas-permeable polymer matrix. With an increase in the excitation power density by ∼300 times, the quantum yield of phosphorescence at 298 K increases by ∼30 times, reaching a value of ϕР ≈ 0.74%.
About the Authors
P. P. Pershukevich
B. I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus
Belarus
Belarus
Minsk
S. M. Arabei
Belarusian State Agrarian Technical University
Belarus
Belarus
Minsk
M. V. Belkov
B. I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus
Belarus
Belarus
Minsk
E. D. Rychikhina
Ivanovo State University of Chemistry and Technology
Russian Federation
Russian Federation
Ivanovo
P. A. Stuzhin
Ivanovo State University of Chemistry and Technology
Russian Federation
Russian Federation
Ivanovo
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Review
For citations:
Pershukevich P.P., Arabei S.M., Belkov M.V., Rychikhina E.D., Stuzhin P.A. Phosphores- cence of In(III)Cl-Etioporphyrin-I at 298 K. Zhurnal Prikladnoii Spektroskopii. 2025;92(6):724-731. (In Russ.)
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