EFFECT OF VISCOSITY AND POLAR PROPERTIES OF SOLVENT ON DYNAMICS OF PHOTOINDUCED CHARGE TRANSFER IN BTA-1 CATION - DERIVATIVE OF THIOFLAVIN T
Abstract
Difference in spectral and fluorescent properties of BTA-1C cation in protic and aprotic solvents was found. It has been shown that, for the dye solutions in long-chain alcohols, viscosity is the dominant factor which determines the dynamics of intramolecular charge transfer in the excited state of BTA-1C. In the case of aprotic solvents, we found correlation of the rate of twisted intramolecular charge transfer (TICT) process with the solvent relaxation rate kTICT ~ 1/tS.
About the Authors
S. D. Gogoleva
Yanka Kupala Grodno State University
Russian Federation
Russian Federation
V. I. Stsiapura
Yanka Kupala Grodno State University
Russian Federation
Russian Federation
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Review
For citations:
Gogoleva S.D., Stsiapura V.I. EFFECT OF VISCOSITY AND POLAR PROPERTIES OF SOLVENT ON DYNAMICS OF PHOTOINDUCED CHARGE TRANSFER IN BTA-1 CATION - DERIVATIVE OF THIOFLAVIN T. Zhurnal Prikladnoii Spektroskopii. 2018;85(2):219-225. (In Russ.)
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