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FLUORESCENCE AND RAMAN SPECTROSCOPY OF DOPED NANODIAMONDS

Abstract

Doped nanodiamonds, synthesized at high pressure and high temperature (HPHT technique) and by chemical vapor deposition from gas phase (CVD technique), were studied by the Raman and fluorescence spectroscopy techniques. For the CVD diamonds, a significant (hundredfold) increase in the fluorescence intensity of the silicon-vacancy centers, normalized to the volume of the probed material, was observed at the increase in size of the synthesized diamond particles from 150 to 300 nm. Graphitization temperature, significantly smaller than for detonation nanodiamonds, was established for the boron-doped HPHT nanodiamonds under heating in air.

About the Authors

O. S. Kudryavtsev
National Research Nuclear University MEPhI
Russian Federation


A. A. Khomich
V. A. Kotelnikov Institute of Radio Engineering and Electronics, Russian Academy of Sciences
Russian Federation


V. S. Sedov
A. M. Prokhorov General Physics Institute, Russian Academy of Sciences
Russian Federation


E. A. Ekimov
National Research Nuclear University MEPhI; L. F. Vereshchagin Institute for High Pressure Physics, Russian Academy of Sciences
Russian Federation


I. I. Vlasov
National Research Nuclear University MEPhI
Russian Federation


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Review

For citations:


Kudryavtsev O.S., Khomich A.A., Sedov V.S., Ekimov E.A., Vlasov I.I. FLUORESCENCE AND RAMAN SPECTROSCOPY OF DOPED NANODIAMONDS. Zhurnal Prikladnoii Spektroskopii. 2018;85(2):280-284. (In Russ.)

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